De-icing fluid on the basis acetate
The invention relates to anti-icing fluids. Anti-icing fluid includes, g/l: sodium benzoate 2,0-8,0, a mixture of trisodium phosphate and dinatriumfosfaatti mass ratio of 1:5 10,0-15,0, sodium nitrite 0.2 to 0.8, liquid glass 2,0-10,0, glycerin, pre-treated with sulfuric acid in a ratio of 1:0,5 0,5-3,0, aqueous potassium acetate solution with a density of 1.20-1,26 and pH 9-11 - the rest. The technical result is the production of environmentally safe composition for low (not more than 0.1 g/m2h) corrosion losses. table 2. In connection with the release of the OST 54-830.4-99 have any need for significant improvement in corrosion properties of anti-icing fluids (YLL) for runways of airfields. In accordance with the above OST corrosion loss of metal in YLL should not exceed 0.1 g/m2including Weight corrosion losses in the Russian practice of standardized YLL for the first time, and foreign developments and technical literature allowable corrosion losses are significantly higher (EP 0375214, national US standard AMS 14350).Also known compositions anticorrosive additives (SU 1827382 And class With the traditional additives in acetate YLL can not provide the newly approved requirements of the Russian standards.The present invention is directed to the solution of the technical problem to ensure low (not more than 0.1 g/m2h) corrosion losses of ferrous and non-ferrous metals when exposed to YLL on acetate base.According to the invention an aqueous solution of potassium acetate is prepared by mixing at a temperature not lower than the 20oWith aqueous solutions of acetic acid, caustic potash and potash to pH 9,0 11,0...and as additives (grams per liter of an aqueous solution of potassium acetate) following components: 1. Low-modulus (M=1) liquid glass any alkali metal. obtained by conducting the reaction between aerosol and aqueous solution of alkali metal hydroxide...10,0 2,0.2. The glycerol-treated concentrated sulfur acid 0,5...3,0.3. Salts of phosphoric acid 10,0 15,0....4. Sodium benzoate...8,0 2,0.5. Sodium nitrite 0,2...0,8.The complex composition of the inhibitor additives due to the complexity of the problem: typically, the inhibitors are recommended for any one of metal, with the same inhibitor may be a stimulant corrosion of other metals (A. Altsybeeva, S. Levin. The corrosion inhibitors of metals. L.: Chemistry. 1968).In this case, it is necessary to provide the corrosion inhibition simultaneously the metal.The complexity of the task is also due to the need to ensure environmental cleanliness additives: YLL in large quantities is poured directly onto the runway of the airfield, therefore, in the soil. An additional difficulty was the need to use only materials, industrial output in the country.Using special technology and special kind of liquid glass is due to the fact that the inhibitors are introduced in the highly concentrated solution, which immediately coagulates conventional liquid glass.Sulfurized glycerin contains artificial radicals acidic. The presence of inhibitors with acidic and alkaline reaction provides a comprehensive inhibition is an extremely complex process of formation of films or passive, or waterproof, or films combined type.Salts of phosphoric acid, which makes the solution of phosphates inhibitors for ferrous and some nonferrous metals differently shift the pH in the alkaline region. So use trisodium phosphate and centripetal in the ratio of 1:5.Sodium benzoate - inhibitor metals in the environment, works well in thin disappearing from drying Yu, what is also important in the context of collapsing films YLL.Sodium nitrite is due to oxidative processes are well protects metals on iron base.Technology introduction inhibitors in an aqueous solution of potassium acetate in dry or dissolved form is simple: they are entered in any sequence in the cold or hot solution with stirring.The invention is illustrated with specific examples describing the content of the corrosion inhibitors (table 1) and the results of the corrosion tests (table 2).Corrosion tests were carried out according to the methods OST-54-830.4-99.From the above examples that the proposed additive is optimal and provides the required technical result.
ClaimsDe-icing fluid for runways of airfields on acetate base containing as anti-corrosive additives sodium benzoate, tri-sodium phosphate and glycerol, wherein the corrosion inhibitor further comprises centripetal, sodium nitrite and water glass when the following ratio of components, g/l:Sodium benzoate 2,0-8,0A mixture of trisodium phosphate and dinatriumfosfaatti in massoudy sulfuric acid in the ratio of 1:0,5 0,5-3,0Aqueous potassium acetate solution with a density of 1.20-1,26 and pH 9-11 Else
FIELD: road servicing industry.
SUBSTANCE: the invention is dealt with the road servicing industry, in particular with the methods of extirpation of ice covering on motorways, bridges, flyovers, and also aerodromes. The method of the roadway covering slipperiness prevention provides for application of a roadway ice covering suppressing reactant based on acetate, in the capacity of which use a solution with pH=7-9.5, containing components in the following ratio (in mass %): magnesium acetate 13-17, potassium acetate 8-16, potassium hydrocarbonate 5-8, potassium carbonate 2-6, water-insoluble impurities 0-6, water - the rest. The roadway ice covering suppressing reactant may additionally contain a fired limestone in amount of 3-5 mass % in terms of calcium oxide. The method of production a roadway ice cover suppressing reactant for a roadway covering slipperiness prevention provides for mixing of a component containing a magnesium compound, iced acetic acid and water, in the capacity of the component containing the magnesium compound is used brucite, the stirring is exercised in two stages: first they continuously agitate brucite with water and a part of iced acetic acid in a stoichiometric ratio at the temperature of 50-70°C within 50-80 minutes, then, not terminating mixing at the same temperature in the produced mix with pH=5-6 add the rest of ice acetic acid and then add potash in amount exceeding by 0.1 - 6 % the stoichiometric ratio and continue agitation till production of the roadway ice cover suppressing reactant - a solution with pH = 7-9.5 with the above indicated composition. The used roadway ice cover suppressing reactant has composition mentioned above. The technical result consists in - maintenance of the low temperature at the reactant usage, ensuring the passing ice covered roadways motor vehicles metal corrosion protection and at use as the airfield runways coatings - the corrosion protection of metals used in aircraft designs as well. The roadway coating treated with the reactant has a high coefficient of adhesion, that reduces the accident rate on the roadways.
EFFECT: the invention ensures, that the roadway coating treated with the reactant decreases the accident rate on the roadways.
6 cl, 2 tbl, 4 ex
FIELD: chemical industry.
SUBSTANCE: invention relates to preparations used for prevention and removal of snow-ice formations in roads. An anti-glaze of ice preparation comprises the following components, wt.-%: calcium chloride, 15-50; sodium chloride, 48.5-83.5; potassium ferricyanide, 0.2-0.5, and sodium dihydrogen phosphate, 0.3-1.0. Anti-glaze of ice preparation in granulated form is resistant against caking, inhibits corrosion of metals and reduces inhibitory effect of chloride on plants.
EFFECT: improved and valuable properties of preparation.
FIELD: special reagents.
SUBSTANCE: invention relates to substances for applying on surface to prevent or diminish adhering ice, mist or water on it, for prevention of icing, in particular, to anti-glaze of ice reagents. The composite comprises the following components, wt.-%: calcium chloride, 25-32; urea, 2-7; sodium nitrite, 0.03-1.0, and water, the balance. Invention provides preparing the composite harmless for environment that doesn't show harmful effect on environment, doesn't corrode road coatings, and inhibits corrosion of metals. Agent shows economy and high effectiveness.
EFFECT: improved and valuable properties of reagent.
2 cl, 1 tbl
FIELD: road-transport industry.
SUBSTANCE: method includes applying substance on asphalt-concrete mixture. As substance silicon-organic modifier is used, loss of which at 1 m2 of area of pre-placed on road asphalt-concrete mixture at temperature 80-100°C is no less than 0,3-0,5 kg. After applying modifier, asphalt-concrete mixture is rolled.
EFFECT: higher efficiency, no corrosive effect on metals, effective at temperature above -20°C.
2 cl, 3 tbl, 3 ex, 1 dwg
FIELD: domestic chemistry.
SUBSTANCE: invention relates to agents using against misting and icing windshields in transports, sight glasses in agent of individual protection and can be used in living conditions for prevention showcase glasses icing. The composition comprises the following components, wt.-%: polyoxyethylene glycol ester of synthetic primary higher alcohols of (C12-C14)-fraction as a surface-active substance, 6-25; urea or thiourea, or mixture of urea and thiourea, 1-20; glycerol, 5-25; ethylene glycol, 5-41; dye, 0.0005-0.02, and a solvent, the balance. Propyl alcohol as propanol-1 or propanol-2 can be used as a solvent. The composition elicits an anti-misting and anti-icing properties, provides two-sided protection of sight glasses of transport agents and agents of individual protection in cooling the protecting glass surface up to -40°C, elicits the prolonged protective effect, it doesn't solidify at the environment temperature below -40°C and doesn't require the special technical devices for its applying.
EFFECT: valuable properties of composition.
3 cl, 1 tbl, 10 ex
FIELD: Composition of an anti-icing water solution for roads surface treatment.
SUBSTANCE: the invention is pertaining to production of composition of an anti-icing water solution for roads surface treatment against a winter slipperiness (snow rolling-ups, a glaze ice, black ice) n the roads and streets in cities and settlements. The composition contains, in mass %: 20-27 calcium chloride, 5-30 ethyl alcohol, 0.3-5 corrosion inhibitors (borax or sodium nitrite or their mixture), the rest - water. The technical result is - an increase of effectiveness of the composition application, an increase of friction coefficient due to a decrease of the ice density, a raise of the composition ice melting capacity.
EFFECT: the invention ensures an increase of effectiveness of the composition application, an increased friction coefficient and a decreased ice density, a raise of the composition ice melting capacity.
1 cl, 1 ex, 2 tbl
FIELD: materials for miscellaneous applications.
SUBSTANCE: grain mixture comprise, in mass %, 15-45% of compressed first salt of alkaline or alkaline-earth metal and 85-55% of the second salt of alkaline or alkaline-earth metal. The first salt is a waterless hygroscopic salt.
EFFECT: reduced cost.
14 cl, 4 dwg
FIELD: preventive means against freezing and sticking of loose materials to walls of mining and transport equipment; prevention of dusting on interim roads, open-cut mining; protection of rolling stock against freezing and blowing-off of loose materials, coal and peat for example.
SUBSTANCE: preventive means is made in form of mixture of solvent and thickening additive of oil nature. Used as solvent are distillation residues of coke and by-product process and/or by-products of production of butadiene, isoprene, isobutylene, ethylene both independently and in mixture with distillation residues of production process of polymers, pyrolysis residues, benzene, styrene and distillation residues of production of butanol, isobutanol, 2-ethyl hexanol acid and 2-ethyl hexanol. Solvent may additionally contain gas oils of thermal and catalytic cracking and gas oils of coking process. Used as thickening additives are mineral and synthetic oils of all kinds, mixture of used oils, oil sludge, oil residues and oil fuel. Components of thickening additive and solvent are used at any combination. Novelty of invention is use of wastes of various processes of oil and petroleum chemistry products.
EFFECT: extended field of application; cut costs; enhanced ecological safety.
5 cl, 1 dwg, 2 tbl, 17 ex
FIELD: suppression or reduction of icing on surfaces by means of antiicing compounds.
SUBSTANCE: proposed anti-icing compounds contain succinic acid and/or succinic anhydride and neutralizing base, sodium hydroxide, potassium hydroxide or ammonium hydroxide in particular. When mixed with water anti-icing compounds form succinates in the course of reaction which causes fast liberation of heat sufficient for melting ice on surface. According to other versions, anti-icing compounds contain glycol which inhibits repeated icing on cleaned surface. Specification gives description of sets of compounds for melting snow and ice.
EFFECT: enhanced efficiency of melting snow and ice on aircraft and territories of their operation.
29 cl, 11 dwg, 7 tbl, 2 ex
FIELD: motor-car industry; other industries; methods of production of the anti-icing reactant.
SUBSTANCE: the invention is pertaining to the method of production of the anti-icing reactants for maintenance of roads in winter. The method of production of the anti-icing reactant based on sodium chloride and calcium chloride provides for mixing of the sodium chloride with calcium chloride and their heating and drying. Sodium chloride crystals are coated with the atomized solution of calcium chloride and dried in the "boiling bed" kiln with production of the double-layer granules, the outer layer of which is composed out of calcium chloride. Sodium chloride crystals are coated with calcium chloride in two phases. The forming small particles of calcium chloride are fed into the cyclone, whence the cyclone dust of the calcium chloride is fed into the mixer for intermixing with the wet crystals of sodium chloride. The produced anti-acing reactant has the improved physicochemical thermodynamic properties.
EFFECT: the invention ensures, that the produced anti-acing reactant has the improved physicochemical thermodynamic properties.
3 cl, 1 ex, 2 tbl