The method of disposal of copper-ammonium solution production of divinyl

 

(57) Abstract:

The invention relates to the production of fertilizers. The method of disposal of copper-ammonium solution production of butadiene is that the initial work concentrated copper-ammonium solution containing as a main component tetraamine copper acetate in a ratio of components, wt. %: copper complex salt of 16.7; acetic acid 23,86; ammonia 13,86; the rest is water, dilute or add to the macro fertilizers to the copper content in the final product in the range from 0.01 to 0.30 wt.% to obtain a copper-containing simple and complex micro - and macro fertilizers. The method does not require sophisticated technology for disposal of copper-ammonium solution, allows to obtain an effective copper-containing simple and complex micro - and macrodontia and to ensure environmental safety and high efficiency of utilization of hazardous storage copper-ammonium solution production of butadiene.

The invention relates to the chemical industry, namely the production of chemical fertilizers.

Known methods of processing copper-containing waste or energy-intensive material-intensive and do not provide environmental without the CSOs production. - M., 1990.- S. 46-47/. Close the entity and the results achieved by the claimed method no. All methods do not provide a complete recycling and may not be used in the proposed form for recycling copper-ammonium solution production of butadiene. Similar to composition is the composition described in A. S. the USSR, N 536803, class a 01 N 59/20 1974. N. M. Gorodni etc.

The essence of the invention is that the method of disposal of copper-ammonium solution production of butadiene is carried out by dilution of the copper-ammonium solution without pre-processing or by adding it to the microelement fertilizers to the copper content in the final product in the range from 0.01 to 0.30 wt.% to obtain a copper-containing fertilizers.

The positive effect is that proposed to use the solution contains as the main component tetraamine copper acetate in a ratio of components, wt.%:

The copper complex salt - 16,7

Acetic acid - 23,86

Ammonia - 13,86

Water - the Rest

This allows you to fully utilize copper-ammonia solution for the production of butadiene, to ensure environmental safety recycling copper-ammonium solution.di from 0.01 to 0.30 wt.% and is used for pre-impregnation of potato tubers, seeds of cereals, tomatoes, etc.

Example 2. Diluted copper-ammonia solution until the concentration of copper from 0.01 to 0.30 wt. % can be used for foliar feeding of plants.

Example 3. Copper-ammonia solution diluted to the desired concentration of copper for direct soil when there is shortage of copper.

Example 4. Copper-ammonia solution is added in the production process, for example, urea, ammeline, map, or other single or complex microelement fertilizers in quantities providing the copper content in the final product in the range of from 0.01 to 0.30 wt.%.

The proposed method solves the problem of environmentally safe disposal of copper - ammonium solution production of butadiene by preparing a copper-containing microfertilizers, as well as simple and complex microelement fertilizers.

The method of disposal of copper-ammonium solution production of butadiene, which consists in the fact that the initial work concentrated copper-ammonium solution containing as a main component tetraamine copper acetate, in a ratio of components, wt.%:

The copper complex salt - 16,7

Acetic acid is Rania copper in the final product in the range from 0.01 to to 0.30 wt.% with simple and complex micro - and macro fertilizers.

 

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SUBSTANCE: invention describes a fungicide mixture containing carbamate of the formula (Ia):

and copper-containing fungicide taken in synergistically active amount. Also, invention describes a method for control of phytopathogenic fungi and applying compounds for a synergistic mixture eliciting the fungicide properties. Fungicide mixtures provide inhibition of phytophthora infection in tomato plants.

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EFFECT: decreased protectant consumption.

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