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Ferroelectric liquid crystal display cell

Ferroelectric liquid crystal display cell
IPC classes for russian patent Ferroelectric liquid crystal display cell (RU 2092883):
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(57) Abstract:

The invention relates to electro-optical devices and can be used to create information displays, imaging devices, Svetozarov. The cell contains two transparent plate with a transparent conductive coating connected to a source of alternating electrical voltage. In the space between the plates is a ferroelectric liquid crystal (FLC), which change their optical anisotropy when changing the sign of the voltage source. Due to this, the cell changes the state of its transmission and simulates passing through her light. After turning off the voltage of the cell depending on the molecular structure of FLC preserves or state maximum or minimum transmittance (bistability), or storing any intermediate state of light transmission (multistability). These conditions are reached, regardless of chemical composition and structure of conductive coatings and without special electrical training cell due to the fact that the FLC layer has a thickness more than 10 μm, is optically active with the helix pitch distance of more than 1 μm and FFA state is outow, and chiral additive comprising optically active derivatives trifenilmetanovogo acid, the choice of components and the weight ratio cause as bistability and lack herringbone deformation of the FLC layer, if provided, the value of spontaneous polarization of the FLC at least 10 NC/cm2and multistability, if this value exceeds 50 NC/cm2. 2 C.p. f-crystals, 2 tab., 5 Il.

The invention relates to electro-optical devices and can be used to create information displays, Svetozarov, imaging devices.

Known ferroelectric liquid crystal display cell.

In Fig. 1 is illustrated the General principle of its construction and structure; the figures and letters on the drawings and hereinafter designated: 1 flat transparent plate, 2 transparent conductive layers on the surface of which is formed the allocation of R, which ensures uniform orientation of liquid crystal molecules, 3 the plane of the smectic layers of the liquid crystal perpendicular to the surface of the wafer 1, 4 source of alternating voltage connected to the layer 2, E is the vector electric field, located in the square is x layers of ferroelectric liquid crystal (FLC), Pwiththe vector of the spontaneous polarization of the FLC, L normal to the smectic layers, the z coordinate axis coinciding with the direction vector L, x coordinate axis parallel to the plates 1,othe angle of the long axes of the molecules with respect to the vector L (the angle between the vectors N and L ), the angle in the XY plane between the normal to the plates 1 and the vector Rwith, P, And the direction of the axes of the polarizer and analyzer, applied to the outer surface of the plates 1, b is the angle between the axes of the polarizer and analyzer, I0the intensity incident on the cell light, I is intensity modulated by the cell light.

In Fig.2 illustrates a fundamental property of FLC at E 0: the periodic dependence of the azimuthal angle v from z, which is called a helicoid twist; in the drawing and hereinafter: P0- step spiral helical twist. The value of P0this is the distance along z between the plane of the smectic layers, in which the vector of the Pwithhas the same orientation, and the angle v to the same value. Depending on the chemical structure of FLC value of P0varies from 0.16 μm to infinity. If Po(z) const, that is, the orientation value, for example, 0,16 10 micrometers, then v f (z) is a periodic function with period Pabout. If E 0 and E > Fwithwhere Ewiththe critical value of the electric field, depending on the structure and thickness of the FLC layer, the helix is unwound by an electric field, that is achieved, the situation v (z) const, corresponding to Fig. 1.

Light modulation cell is as follows. The cell falls natural unpolarized light, the intensity of which Iabout(Fig. 1). Passing through the polarizer P, the light becomes polarized in the direction of the axis of transmission of Polaroid and passing through layers 1 and 2, goes to the FLC layer. Propagation of polarized light through FLC depends on the relative position of the vector N and the axis of the polarizer P. the direction of the vector N in the cell depends on the sign of the voltage source 4, that is, from the direction of the field E. the angle between the vectors N(+E) and N(-E) is 2o(Fig. 1). If SJK is +E, and Polaroid is applied so that its axis is parallel to the vector N(+E), the light propagates along the main optical axis of FLC and therefore not having birefringence, and at = /2 cell does not transmit light. If the direction field will be changed to-E, the light will spread prizzia light converted from linear to elliptical. In this case, when = /2 cell transmits light. The change of transmittance of the cell is due to changes in the anisotropy of the FLC when the direction vector of the electric field. The intensity of the transmitted light I is determined by the ratio:
< / BR>
where
n the magnitude of the birefringence layer FFA;
d its thickness;
the wavelength of the light,
the angle between the vectors N and L. the Maximum transmittance of the cell T (I/Iabout1 is achieved, according to (1), if:
< / BR>
Thus, when the polarity of the electric voltage source is changing the direction of the electric field in the sample FLC from +E to-E, which leads to a change of transmittance of the cell from minimum to maximum value, and when changing from-E to +E light transmittance is changed from the maximum value. The described process is, if E > Fwith.

After the change of polarity of the electric voltage source 4 and then off, i.e. when E 0 it is possible to save on time from 10-3with up to 106with called time memory, two States of the optical transmission of the cell is minimal (opaque state) and the maximum. This phenomenon is called bistabil is an antiferroelectric display cells [3] the Essence of it is, when E 0 it is possible to save not only the two States of the optical transmission of the cell maximum, but also any intermediate state. This effect can be used to obtain the dullness in information displays. However, in zhidkokristallicheskikh ferroelectric display cells the effect of multistability so far not been observed.

It is known that up to the present time bistability is achieved through the interaction of FFA with surfaces 2. Bistable ferroelectric liquid crystal display cells of this type are called surface-stabilized structures. They are characterized by the following ratio between the pitch of the helix of the helix and the thickness of the FLC layer: Raboutd. These patterns have significant disadvantages. First, the stability of bistability depends on the homogeneity of the surfaces 2 and their identity, it is difficult to achieve technologically. Secondly, to obtain bistability of surface-stabilized structure must be subjected to special electrical effects [2] called electric training sample. After some time after electrical training education is working with the FLC layer thickness d of 1.5 to 2 micrometers, it is difficult to ensure when producing samples of cells. Fourthly, in the smectic layers are observed faults, called herringbone defects or chevrons (Fig. 3A). The presence of chevrons limit memory and leads to scattering in the cell that degrades its quality and lowers the contrast of light transmission.

Closest to the claimed invention ( prototype) is a bistable liquid crystal display cell, stable helix. This type of cell is called helicoidal-stable structures and is characterized by the fact that Raboutd. Helicoidal-stable structures do not need the training sample. However, as in the case of surface-stabilized structures, there is a dependence of the stability of bistability of surface parameters, although significantly weaker than for the surface-stabilizirovannykh structures. In addition, glycodelin-stable structure, and surface-stabilizirovannye in d 1.5 2 micrometer.

This invention solves the problem of creating a liquid crystal display cell in which there are no V-defects and which has bistability, that the chemical composition and structure of surfaces 2.

This is achieved by selecting combinations of chemical structures of molecules, members of the FFA. To achieve the goal you want in the FLC composition were simultaneously included chemical compounds belonging to the following chemical classes:
substituted phenylpyrimidine:
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phenylbutane:
< / BR>
< / BR>
optically active derivatives trifenilmetanovogo acid:
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or like this:
< / BR>
or R*1, R*2the same radicals as in the structure VI.

The combination of these structures in a certain ratio, namely, the weight ratio of phenylpyrimidine I, III and phenylbenzoate IV-V can vary from 4 1 to 1 4, optically active derivatives trifenilmetanovogo acid VI and VII are 10 to 40% by weight of FLC, provides the appearance of bistability in the FLC layer thickness more than 10 μm, if the structures VI and VII are selected in such a way that Rabout> 1 μm. Bistability in this case is a consequence of intermolecular interactions in the FLC, and not the result of the interaction of FFA with the surface, as in surface-stabilized structures, so there is no dependence of the resistance of bistability time and memory parameters with whom b), since the bending of the smectic layers is not allowed hard terminalname cores of the molecules of the optically active derivatives trifenilmetanovogo acid. At this time, the memory reaches 108sec or more when the thickness of the FLC layer 10 to 100 micrometers.

If the structures VI and VII, the concentration of which in the FLC composition exceeds 25 wt. chosen so that Pabout> 1 μm, Pwith> 50 NC/cm2and the weight ratio of phenylpyrimidine I, III and phenylbenzoate IV V range from 1 to 4 1 to 4, the ferroelectric liquid crystal display cell is multistable when d > 10 μm. Optical manifestations of multistability are illustrated by the micrograph of Fig. 4B, which is visible to a periodic sequence of white and black stripes. The period specified patterns 14 micrometers.

It is known that ferroelectrics, both solid and liquid, characterized by the presence of the hysteresis loop. Characteristic appearance of the hysteresis loop of the intensity of the light transmitted through the multistable liquid crystal display cell shown in Fig. 4A. At point a of the curve (Fig. 4A), the voltage source was turned on, the cell will remember the sequence of white (transparent) and che is the Reeve of the hysteresis loop, in which switches off the voltage source 4. When the amount of light transmission of the cell is determined by the ratio of the squares of white and black stripes.

The physical reason for the appearance of the considered periodic structure - singleelectron domains in the FLC. These domains occur when Rwith> 50 NC/cm2. The period D is inversely proportional to the square of the spontaneous polarization of the FLC: D Rwith-2. The presence of domains is manifested in periodic modulation angle along the coordinate z (Fig. 5) and is associated only with the material parameters of the FLC. When you change the value of the voltage source 4 switches the first cell region, in which v is the maximum, while other areas do not switch.

This leads to a periodic modulation of the transmittance of the cell (Fig. 4B), and the memorization of a periodic lattice at any point of the hysteresis loop is provided by a combination of the above chemical structures. Multistability, as bistability, is characterized by a time of remembrance, a time to remember the periodic lattice. Stereochemically conditions polucheniya of bistability and multistability largely the same, and all multistable cells is th display cell in statistics is fully described by the schema, shown in Fig. 1. Constructive contrast to previously proposed solutions is that the thickness of the layer of liquid crystal is more than 10 micrometers and not 1.5 to 2 micrometers.

Modulation of light offered by the cell is exactly the same as known. However, to obtain bistability and multistability there is no need for the selection of chemical composition and structure of surfaces 2 and advanced electrical training sample.

Bistable mode ferroelectric liquid crystal display cells and the presence of chevrons depending on the molecular structure of the FLC is illustrated by the examples in the table. 1 and multistable table. 2.

1. Ferroelectric liquid crystal display cell containing two flat transparent plates arranged in parallel one above the other on one side which caused Polaroid, and another transparent conductive coating connected to a source of alternating electric voltage, the surface of which is set to the selected direction to provide a uniform orientation of the molecules of the liquid crystal, ferroelectric W is managing its optical anisotropy under the influence of an electric field, consisting of the organization of the achiral smectic liquid crystal mixture comprising 60 to 90% of the total weight of FLC, and chiral additive, containing 10 to 40% of the total weight alcohols having spontaneous polarization Pwithmore than 10 NC/cm2and smectic tilt angle of more than 10o, characterized in that the conductive coating flat transparent plates spaced from each other at a distance of more than 10 μm, and organization of the achiral smectic liquid crystal mixture includes a combination of substituted phenylpyrimidine and phenylbenzoate in a ratio of from 1 to 4 1 to 4, and as phenylpyrimidine
< / BR>
< / BR>
< / BR>
is one of the structures I, III, or all together, or in any combination, and as phenylbenzoate
< / BR>
< / BR>
is either one of structures IV, V, or all together, or in any combination, and as chiral additives in the composition of FLC is either one of structures VI VII
< / BR>
where
< / BR>
or
< / BR>
< / BR>
where
or R*1, R*2the same radicals as in the structure VI or structures, or any combination, provided that the induction step of the spiral Raboutthe helix FLC than 1 μm.

2. Cell under item 1, wherein n is 25 to 40% of the total weight of FLC.

3. The cell on the PP. 1 and 2, characterized in that the chiral additive is chosen so that Rwithmore than 50 NC/cm2.

 

 

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