Solid pesticide composition based bensultap

 

(57) Abstract:

The composition according to the invention comprises as active substances known insecticide - S,S and the stabilizer is zinc oxide, or boron, or magnesium, or titanium dioxide in the amount of 0.5-to 45.5 wt.h. stabilizer 1 wt.h. the active substance. The composition may additionally contain an insecticide and/or fungicide - phtalic, tricyclazole, etofenprox, validamycin - 0,027-2 wt.h. 1 wt.h. bensultap while maintaining its stability. The composition may contain conventional solid preparative forms of supplements. 1 C.p. f-crystals, 9 PL.

The invention relates to stabilised solid compositions containing S, S' - [2-(dimethylamino)trimethylene]bis-benzothiazolone(bensultap), more precisely to a stabilised solid compositions containing S, S'-[2-(dimethylamino)trimethylene] bis-benzothiazolone and at least one connection oxides, selected from the class consisting of titanium dioxide, zinc oxide, magnesium oxide and boron oxide.

The composition of the present invention is used as an insecticide in agriculture.

S,S'-[2-(dimethylamino)trimethylene]bis - benzothiazolone is typical for this type name: company code is/BR> N - and represents an insecticide for use in agriculture.

This insecticide is showing excellent activity against pests, has low toxicity to humans, animals, fish and natural enemies of these pests.

Still bensultap used in the form of known solid preparations, for example Farrukh Dustov, granules or wettable powders obtained by mixing with carriers or diluents such as mineral powders.

However bensultap is unstable in the composition of such well-known solid products obtained by mixing bensultap with a carrier or diluent, such as mineral powders by known methods. If solid preparations containing bensultap, store at room temperature, then bensultap gradually decompose, deteriorate, change color and destroyed. This leads to reduction in the content of bensultap in drugs.

Therefore, in the solid composition obtained by blending bensultap with one or more chemical products used in agriculture with the aim of obtaining the effects of a wider and better range of actions, as well as saving time and trudoustroistvo collapse and decompose faster than solid formulations containing only one bensultap as an active ingredient.

The present inventors have unexpectedly found that among various metal oxides, titanium dioxide (TiO2), calcium oxide (Cao), zinc oxide (ZnO), magnesium oxide (MgO) and boron oxide (2ABOUT3) are stabilising action in relation to the solid composition. However, other oxides such as aluminum oxide or silicon dioxide, are stabilizing action.

In addition, the authors were unexpectedly found that a composition of the present invention can be applied to prevent damage to plant pests, without phyto-toxic action. Also found that the destruction bensultap in the composition of this song is slowed down, i.e. bensultap stabilized for a longer period of storage. Further, in the composition, it becomes possible to introduce chemical products for agricultural purposes, for example, etofenprox, validamycin And, tricyclazole or phtalic that it was impossible to combine previously bensultap. In addition, in the solid compositions of the present invention, the active components have a lasting effect after application or priscian the ionic solid composition according to this invention essentially has no phytotoxicity and does not cause harm to humans and animals. When applying or spraying and after them there is no fear of unpleasant consequences.

The solid composition of the present invention can be obtained by mixing or connection bensultap at least one connection oxides, selected from among titanium dioxide, calcium oxide, zinc oxide, magnesium oxide and boron oxide and, if necessary, a suitable solid carrier or diluent, or adsorption bensultap and the above-mentioned compound oxide with the solid carrier or diluent. The solid composition according to this invention is used in such preparations, as dusty, the stagnant dusty (in the following referred to as dusty DL), skachivanie powders, granules and microspheres (in the following referred to as microspheres (F).

These drugs can be obtained using known methods.

The composition of this invention can optionally include other active ingredients and auxiliary ingredients such as dispersing means, means to support the distribution of the drug on the treated surface, means to support spreading, wetting means, thickeners, caking inhibitors, coagulants, the binder is applied in the range of 0.1 to 90 wt.% in terms of the weight of the total composition. More specifically, the content bensultap preferably is in the range of approximately 0.1-10 wt.% in the case of Farrukh Dustov and Farrukh Dustov DL, about 0.1-10 wt.% in the case of granules and microgranules F and about 10 to 90 wt.% in the case of wettable powders.

The compositions according to this invention, stabilizers, titanium dioxide, zinc oxide, magnesium oxide and boron oxide can be used either separately or in mixtures of two or more species in the proper proportions. Stabilizers can be used in number (in case of using two or more modes, the total number) about 0.5-50 wt. including 1 wt.h. bensultap.

Titanium dioxide, zinc oxide, magnesium oxide and boron oxide are usually taken in the form of a powder, preferably having a particle size not more than 10 μm.

Preferred examples of the solid carrier or diluent are mineral powders such as clays (e.g. kaolin, bentonite, activated acid clay, clay in the state of fine grinding, also white carbon black, talc different species (e.g., talc), crushed to a state of fine powder or powder pyrophyllite), or various kinds of silicon dioxide (for example, hard-shelled ground or powdered mica), powders is a, calcium carbonate, powdered sulfur and charcoal. All these products can be used separately or as mixtures of two or more kinds.

Surfactants can be used as a dispersing means, promoting uniform distribution of the treated surface, or tools to facilitate spreading. Examples of surfactants include non-ionic substances and ionic materials, such as soap, ethers, alkyl-aristolochiaceae, polyoxyethyleneglycol ethers, polietilenglikolya ethers and esters of polyhydric alcohols.

As inhibitors caking use white carbon, talc, hard-shelled land and magnesium stearate. As coagulants used, for example, liquid paraffin, ethylene glycol, diethylene glycol, and triethylene glycol. Used binding agents are sodium carboxymethyl cellulose, dextrin, starch and polyvinyl alcohol.

Examples of antioxidants include dibutylaminoethanol; 4,4-thio-bis-6-tert-butyl-3-METHYLPHENOL, butylacetamide, p-op, mono (or di-or tri-) ( -IU - Livenza)phenol; 2,6-di-tert-butyl-4-METHYLPHENOL, pentaerythrityl-t is a part, in addition to bensultap, one or more effective ingredients.

Among them, preferred are the following. Common name or abbreviation given in parentheses following the chemical name.

Common name or abbreviation may be used in the next statement depending on the circumstances.

Fungicides organic chlorine compounds:

4,5,6,7-tetrachlorophthalic(phtalic).

Other fungicides:

5-methyl-1,2,4-triazolo /3,4-b/benzothiazole (tricyclazole), 3-allyloxy-1,2-benzothiazole-1,1-Dixit (probanza).

Antibiotics: blasticidin S, kasugamycin, polyoxin, oxytetracycline, validamycin And etc.

Other insecticides:

S, S'-[2-(dimethylamino) trimethylene] mistakebut (cartap), 2-(4-ethoxyphenyl)-2-methylpropyl-3-phenoxybenzyl simple ether (etofenprox), (RS) - a-cyano-3-phenoxybenzyl (S)-2-(4-deformational)-3-methylbutyrate (flucythrinate).

Specific examples of the mixed composition of the present invention include a mixture bensultap and etofenprox, the mixture bensultap, etofenprox and tricyclazole (or phthalide, or validamycin A).

Other effective ingredients, other than bensultap, Costabella version of 0.05-10 wt.% in terms of the total weight of the composition in the case when you take one look, and about 0.01 to 20 wt. % , preferably about 0.05-15 wt.%, in terms of total weight, relative to the weight of the entire composition, if used two or more kinds.

When the effective ingredient (for example, etofenprox) is liquid or melts near room temperature, this effective ingredient can be used in the form of solution or dispersion in a solvent with a high boiling point. Examples are phenylxylylethane, di-2-ethylhexyladipate or 2-ethylhexylphthalate.

The composition of the present invention may further comprise a means of combating mites, nematodes, herbicides, plant hormones, plant growth regulators, synergistic agents, attracting substances, repulsive (repellents), coloring matter or fertilizer.

The compositions according to this invention wettable powders before use, dilute with water to the proper extent, about 30-4000 times, in the preferred embodiment, approximately 300 to 3000 times, and then apply. Wettable powders are preferably used after dilution to a concentration of bensultap about 50-1000 h/million

When the composition according to izaberete the ü in number within 30-500 g per 10 Ares (1 ar - 0.4 ha). The composition of this invention is treated directly stems and leaves or applied to the plant roots. Thus, processing can be performed by known methods. If you make timely spraying or coating on the rice plants, vegetable crops (such as cabbage, Chinese cabbage, Japanese radish, cucumbers or potatoes, fruit trees (e.g., Mandarin, orange or pear), plants, tea and tobacco, the composition of the present invention can realize the struggle or the destruction they are on different pests, such as lepidopteran pests, such as Ognevka tortrix, Tolstoganova rice, corn borer, borer, cabbage butterflies, moth cabbage, Ognevka cabbage, worm legumes, cabbage caterpillar, scoop Eastern or tea tortrix, Coleoptera pests, such as rice bug or watermelon beetle, a pest of the Hemipterous family, Cicada green, such as kobylecki green rice or pests of the family thysanopterous, such as thrips, yellow tea, pests of the family of Diptera, such as mol-miner rice. Further, it is possible to prevent the spread of pests for a long time through open be prepared using known methods, such as have been described above and in detail in the following examples.

Examples to serve for references, examples and sample tests below explain the invention in more detail. In the examples, the part or parts means the part or parts in mass terms.

P R I m e R references 1. Dusty DL.

To 96,5 including micronized clay add 2,2 including bensultap; 1.0 hours white carbon black and 0.3 PM of liquid paraffin (Gorillas WITHR, further referred to as Gorillas C) followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives containing bensultap dusty DL.

After storage at 60aboutWith in 1 week bensultap destroyed by 13.1%.

P R I m m e R 2 links. Dusty DL.

To 94,1 including micronized clay add 2,2 including bensultap; 1.2 x 50% (by weight) solution of etofenprox in phenylxylylethane (in the following referred to as solvent); 2,2 including white carbon black and 0.3 hours of Gorillas With, followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives dusty DL bensultap-etofenprox.

P R I m e a; 1.0 hours of white carbon black and 0.3 hours of Gorillas With, followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives dusty DL bensultap-tricyclazole.

After storage at 60aboutWith in 1 week bensultap destroyed by 24.6%.

P R I m e R references 4. Dusty DL.

To 93,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including white carbon black and 0.3 hours of Gorillas With, followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R references 5. Dusty DL.

To 93,8 including micronized clay add 2,2 including bensultap; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 0,3 including validamycin A; 2,2 including white carbon black and 0.3 hours of Gorillas With, followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives dusty DL bensultap-etofenprox-validamycin.

P R I m e R references 6. Granules.

The mixture weighing 100 hours get smeshanovalentnogo-active substance), clay (balance). After thorough mixing the mixture with water followed by mixing. The mixture after stirring granularit on the extruder-granulator (hole diameter nozzles 1.0 mm). The obtained wet granules are dried and sieved that gives granules ranging in size from 10 to 32 mesh (2.0-0,59 mm).

P R I m e R references 7. Wettable powders.

To 69,5 including clay for wetting powders add to 10.5 hours bensultap; 11,0 including a 50% aqueous solution of etofenprox in the solvent; 5,0 including white soot and 4.0 hours surfactants followed by thorough mixing in a mixer-grinder. Then the resulting mixture was pulverized in microproccesor the shredder that gives wettable powders bensultap-etofenprox.

P R I m e R references 8. Dusty DL.

To 78,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 15.0 including powdered aluminum oxide. followed by thorough mixing in a mixer-grinder. The resulting mixture is then treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R references 9. Dusty DL. is inproxy and 5 wt.% pentaerythrol-tetrakis[3-(3,5-di-tert-butyl-4 oksifenil)] -propionate in a solvent; 2,2 including white carbon black and 0.3 hours of Gorillas With followed by thorough mixing in a rapid mixer that gives dusty DL bensultap-etofenprox.

P R I m e R references 10. Dusty DL.

To 78,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h solution containing etofenprox at a concentration of 50 wt.% and Penta-erythritol-tetrakis [3-(3,5-di-tert-butyl-4 oksifenil)]propionate at a concentration of 5 wt.% in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 15.0 hours of powdery silicon dioxide, followed by thorough mixing in a mixer-grinder. The resulting mixture is treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 1. Dusty DL.

To 78,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 15.0 hours of powdered magnesium oxide (particle size less than 45 microns) followed by thorough mixing in a mixer-grinder. The resulting mixture is then treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m m e R 2. Dusty DL.

To 78,0 o'clock is storytale; 2,2 including carbon white; 0,3 hours of Gorillas With and 15.0 hours of powdery boron oxide (particle size less than 45 microns), then carefully blend are mixed in a mixer-grinder. The resulting mixture is treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 3. Dusty DL.

To 78,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 H. white soot; 0,3 hours of Gorillas With and 15.0 hours of powdery zinc oxide (particle size less than 45 microns), and then thoroughly mixed in a mixer-grinder. The resulting mixture is treated in an online mixer that gives Douste DL bensultap-tricyclazole-etofenprox.

P R I m e R 4. Dusty DL.

To 78,0 including micronized clay add 2,2 including bensultap. 1,1 including tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 15.0 hours of powdered calcium oxide (particle size less than 45 microns), followed by thorough mixing in a mixer-grinder. The resulting mixture was further treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 5. Dusty DL.

To 83,0 including fine clay to the 0,3 PM Gorillas With and 10.0 hours of powdered calcium oxide (particle size less than 45 microns) followed by thorough mixing in a rapid mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 6. Dusty DL.

To 88,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 5.0 hours of powdered calcium oxide (particle size less than 45 microns) followed by thorough mixing in a mixer-grinder. Next, the resulting mixture is treated in an online mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 7. Dusty DL.

To 90,8 including micronized clay add 2,2 including bensultap; 1,1 h tricyclazole; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 2.2 hours of powdered calcium oxide (particle size less than 45 microns), and then thoroughly mixed in a mixer-grinder. The resulting mixture was further treated in a rapid mixer that gives dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 8. Dusty DL.

To 84,1 including micronized clay add 2,2 including bensultap; 1,2 is Yes zinc (particle size less than 45 microns) followed by thorough mixing in a mixer-grinder. Then the resulting mixture is treated in an online mixer that gives dusty DL bensultap-etofenprox.

P R I m e R 9. Dusty DL.

It is 83.8 including micronized clay add 2,2 including bensultap; 1,2 h of a 50% aqueous solution of etofenprox in the solvent; 0,3 including validamycin A; 2,2 including white soot, 0,3 hours of Gorillas With and 10.0 hours of powdered magnesium oxide (particle size less than 45 microns) and thoroughly mixed in a mixer-grinder. Then the mixture is processed in thin-layer mixer that gives dusty DL bensultap-etofenprox-validamycin A.

P R I m e R 10. Granules.

The mixture weighing 100 hours receive a mixture of 4 hours bensultap, 6 hours dextrin, 2 hours surfactants, 25 hours of powdery titanium dioxide (particle size less than 45 μm) and clay (to balance). After thorough mixing add 12 tsp of water to the mixture, then knead. The mixture after stirring granularit on the extruder-granulator (the diameter of the holes in the perforated disk 1.0 mm). Thus obtained wet granules are dried and sieved, which gives the mass of granules with the size 10-32 mesh (0,59-2.0 mm).

P R I m e R 12. Wettable powders.

To 54,6 including clay for wettable powder is surface-active substances; 15,0 including powdered zinc oxide (particle size less than 45 microns), followed by thorough mixing in a mixer-grinder. The resulting mixture was additionally crushed in micropulverized that gives wettable powders containing bensultap-etofenprox.

P R I m e p 13. Dusty DL.

To 31,4 including micronized clay add 2,2 including bensultap; 1,2 h of a solution containing 50 wt.% etofenprox and a 5% aqueous solution of pentaerythrityl-tetrakis[3-(3,5-di-tert-butyl)-4 oksifenil)]propiona - one in the solvent; 2,7 hours of phthalide; 2,2 including carbon white; 0,3 hours of Gorillas With and 10.0 hours of powdery zinc oxide (particle size less than 45 microns), and then thoroughly mixed in a mixer-grinder. Next, the resulting mixture is treated at the operational mixer that gives dusty DL containing bensultap-etofenprox-phtalic.

P R I m e R 14. Dusty DL.

It is 83.8 including micronized clay add 2,2 including bensultap; 1,2 h of a solution containing 50 wt. % etofenprox and 5% solution of pentaerythrol-tetrakis[3-(3,5-di-tert-butyl-4 oksifenil)] propionate in the solvent; 0,3 including validamycin A; 2,2 including carbon white; 0,3 hours of Gorillas With and 10.0 hours of powdery zinc oxide (particle size less than 45 microns) with subsequent thorough paragraph is about is giving dusty DL, containing bensultap-etofenprox-validamycin A.

P R I m e R 15. Dusty DL.

To 84,1 including micronized clay add 2,2 including bensultap; h 1,2 solution etofenprox concentration of 50 wt.% and the solution of pentaerythrityl-tetrakis [3-(3,5-di-tert-butyl-4 oksifenil)]propionate 5,0% concentration in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 10.0 hours of powdery zinc oxide (particle size less than 45 microns), followed by thorough mixing in a mixer-grinder. The resulting mixture is then treated in an online mixer that gives dusty DL containing bensultap-etofenprox.

P R I m e R 16. Dusty DL.

To 83,0 including micronized clay add 2,2 including bensultap; 1,1 including tricyclazole; 1,2 h of a solution containing 50 wt.% etofenprox and 5 wt.% pentaerythrol-tetrakis [3-(3,5-di-tert-butyl-4 oksifenil)]propionate in the solvent; 2,7 hours of phthalide; 2,2 including carbon white; 0,3 hours of Gorillas With and 10.0 hours of powdery zinc oxide (particle size less than 45 microns), followed by thorough mixing in a mixer-grinder. The resulting mixture is treated in an online mixer that gives dusty DL containing bensultap-tricyclazole-etofenprox.

The example tests.


The obtained test results are shown in table.1-9.

The above results show that bensultap can be significantly stabilised by mixing solid compositions containing bensultap with titanium dioxide, zinc oxide, magnesium or boron.

P R I m e R s 17-24.

Mix 4 wt.h. bensultap, 6 hours dextrin, 2 hours surfactants; 50,25 or 4 hours of metal oxide shown in table.7, in the form of a powder (particle size less than 45 μm) and clay to 100 (the rest).

After thorough mixing, add 12 hours and water mixture, followed by stirring. The stirred mixture granularit on the extruder is sutured and sift, that gives a lot of granules, size passing through a sieve 10-32 mesh.

Comparative examples 11-13.

A mixture of 100 wt.h. get a mixture of 4 hours bensultap, 6 hours dextrin, 2 hours surfactants. 50, 25, or 4 tsp powdered calcium oxide (particle size less than 45 μm) and clay (the rest).

After thorough mixing to the mixture 12 o'clock water, followed by stirring. The stirred mixture granularit on the extruder-granulator (the diameter of the hole in granulating grid 1.0 mm). The obtained wet granules are dried and sieved that gives a lot of granules, size passing through a sieve 10-32 mesh.

P R I m e R 25. To 45,2 including finely ground clay was added 1,1 including bensultap, 1,2 including a 50% aqueous solution of etofenprox in the solvent; 2,2 including carbon white; 0,3 hours of Gorillas With and 50.0 tsp powdered zinc oxide (particle size less than 45 microns) and then mixed in a grinding mixer. The resulting mixture is processed in the evaporation mixer with getting Farrukh Dustov DL bensultap-ECOFIN - Prox.

P R I m e R 26. To 94,7 including finely ground clay was added 1,1 including bensultap; 1,2 h of a 50% aqueous solution of etofenprox in the solvent, 2,2 including white soot, 0,3 including Dor is Musicale. The resulting mixture was then processed in the evaporation mixer and get dusty DL bensultap-etofenprox.

P R I m e R 27. To 44.1kHz including finely ground clay was added 1,1 including bensultap, 1,1 including tricyclazole, 1,2 including a 50% aqueous solution of etofenprox in the solvent, 2,2 including white soot, 0,3 hours of Gorillas With and 50.0 tsp powdered zinc oxide (particle size less than 45 microns) and then mixed in a grinding mixer. Thereafter, the resulting mixture is processed in the evaporation mixer and get dusty DL bensultap-tricyclazole-ECOFIN-Prox.

P R I m e R 28. To 93,6 including finely ground clay was added 1,1 including bensultap, 1,1 including tricyclazole, 1,2 including a 50% aqueous solution of etofenprox in the solvent, 2,2 including white soot, 0,3 hours of Gorillas With 0.5 tsp powdered zinc oxide (particle size less than 45 microns) and then thoroughly mixed in a grinding mixer. Thereafter, the resulting mixture is processed in the evaporation mixer and get dusty DL bensultap-tricyclazole-etofenprox.

P R I m e R 29. To 85,18 including finely ground clay is added to 2.2 hours bensultap, 0,12 including a 50% aqueous solution of etofenprox in the solvent, 2,2 including white soot, 0,3 hours of Gorillas With and 10.0 hours of powdery zinc oxide (size charbatia in the evaporation mixer with getting Farrukh Dustov DL bensultap-etofenprox.

P R I m e R 30. To 54,5 including clay for wettable powders are added to 10.5 hours bensultap, 11,0 hours of tricyclazole, 5,0 including carbon white, 4,0 including surfactants and 15.0 hours of powdery zinc oxide (particle size less than 45 microns), then thoroughly mix in the chopping mixer. Then the resulting mixture is ground in micropulverized and get wettable powders bensultap-etofenprox.

1. SOLID PESTICIDE COMPOSITION BASED BENSULTAP (S, S'-[2-(dimethylamino)-trimethylene]bis-benzothiazolone), characterized in that, to improve stability bensultap, it includes the additional stabilizer is a metal oxide selected from the group comprising: titanium dioxide, boron oxide, magnesium oxide, zinc oxide, in amounts of from 0.5 to 45.5 wt.h. 1 wt.h. bensultap.

2. The composition according to p. 1, characterized in that it further comprises tricyclazole, or etofenprox, or their mixture, or a mixture of etofenprox with validamycin or Taldom, or a mixture of tricyclazole, etofenprox and phthalide in the number 0,027 - 2 wt.h. 1 wt.h. bensultap.

 

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5 cl, 15 ex

FIELD: agriculture.

SUBSTANCE: described is attractant composition for male elaters Crimean Agriotes tauricus (Coleoptera, Elateridae). Common attaractant composition used in agriculture for vermin protection of plants containing mixed 3,7-dimethyl-trans-2,6-octadiene-1-ol-3-methylbutanoate (40-68.0%), 2,6- dimethyl-trans-2, trans-6-octadiene-1,8-diol-di-(3-methylbutanoate) (18-55.5%), 3,7,11-trimethyl-trans-2, trans-6,10-dodecatrien-1-ol-3-methylbutanoate (4-10%), 3,7-dimethyl-cys-2,6- octadiene-1-ol-3-methylbutanoate (0.5-4.0%)) is added with ceresin at following component ratio, wt %: ceresin - 10.0-99.0; specified mix - 1.0-90.0.

EFFECT: production of attractant composition of long attractant activity.

3 tbl

FIELD: agriculture.

SUBSTANCE: herbicidal composition is made on the bases of 3.6-dichlorpyridine-2-carboxylic acid and substituted arylsulfonylheterylcarbamide. As a derivative of 3.6-dichlorpyridine-2-carboxylic acid it contains alcohol esters of C7-C10 356- dichlorpyridine-2-carboxylic acid or their mixtures, at the following components ratio, wt %: C7-C10 alcohol esters; 3,6-dichlorpyridine-2-carboxylic acid or their mixture - 40-75; substituted arylsulfonylheterylcarbamide - 1-5; surface -active agent 15-35; carrying agent - the remaining.

EFFECT: increases consistency of composition.

3 cl, 2 tbl, 12 ex

FIELD: agriculture.

SUBSTANCE: invention contains micro-particles each including matrix and chemical substance distributed thereinto. The matrix corresponds to liposomes or nano-particles of silicon dioxide; also the surface of the matrix contains natural hydrocarbon containing compounds able specifically to bind with root surface. Liposomes are obtained out of egg phosphatidylcholine and their surface contains lipopolysaccharides of the outer membrane of bacteria Azospirillum brasilense Sp245. The surface of the matrix out of silicon dioxide contains polysaccharides of wheat roots Triticum aestivum L of Saratovskaya 29 breed. Micro-particles are of 0.01-0.2 mcm size.

EFFECT: diminishing anthropogenic load to arable land and environment.

3 cl, 6 ex, 6 tbl

FIELD: agriculture, herbicides.

SUBSTANCE: invention relates to herbicide composition based on derivative of sulfonylurea that comprises non-ionogenic surface-active substance, lignosulfonates as anion-active surface-active substance and highly dispersed amorphous silica as a carrier. Composition comprises chlorsulfuron as derivative of sulfonylurea and triethanolamine or diethanolamine additionally, and potassium dihydrogen phosphate as a stabilizing agent in the following ratio of components, wt.-%: chlorsulfuron, 18-22; non-ionogenic surface-active substance, 3-5; potassium dihydrogen phosphate, 9-12; triethanolamine or diethanolamine, 9-11; lignosulfonates, 3-10, and highly dispersed amorphous silica, the balance. Method involves mixing components in indicated ratios by steps for 3 stages. At the 1-st stage triethanolamine or diethanolamine is applied on surface of highly dispersed amorphous silica, at the 2-d stage - chlorsulfuron, and at 3-d stage - potassium dihydrogen phosphate, lignosulfonates and non-ionogenic surface-active substance. After keeping for 24 h at the room temperature mixing products from all three stages are combined. Invention provides enhancing stability of chlorsulfuron and biological activity of preparation based on thereof. Invention is designated for applying in agriculture.

EFFECT: valuable properties of herbicide composition.

4 cl, 2 tbl, 9 ex

FIELD: agriculture, in particular chemical agents for plant protection.

SUBSTANCE: sulfonylaminourea and phenoxyacetic acid derivatives-based herbicidal composition contains nonionic surfactant, anion-active surfactant sulfonol, kaolin as carrier, and carbon white. As sulfonylaminourea and phenoxyacetic acid derivatives it contains 3-(6-methyl-4-methoxy-1,3,5-triazinyl-2-)-1-(2-chlorophenylsulphonyl)urea and 2-methyl-4-chlorophenoxyacetic acid sodium salt, respectively. Additionally composition contains triethanolamine or diethanolamine, disubstituted potassium phosphate as stabilizer in the component ratio of (mass %): 2-methyl-4-chlorophenoxyacetic acid sodium salt 55-72; 3-(6-methyl-4-methoxy-1,3,5-triazinyl-2-)-1-(2-chlorophenylsulphonyl)urea 0.3-0.4; nonionnic surfactant 0.05-0.15; sulfonol 0.05-0.15; triethanolamine or diethanolamine 0.15-0.2; carbon white 0.37-1.5; disubstituted potassium phosphate 1.0-2.0; and balance: kaolin. Composition components are separately applied on carrier surface. More specifically triethanolamine or diethanolamine is separately mixed with kaolin; 3-(6-methyl-4-methoxy-1,3,5-triazinyl-2-)-1-(2-chlorophenylsulphonyl)urea, and carbon white are separately mixed with kaolin; disubstituted potassium phosphate, nonionic surfactant, and sulfonol are separately mixed with kaolin; and 2-methyl-4-chlorophenoxyacetic acid sodium salt also is separately mixed with kaolin. Mixtures are conditioned for 24 h at room temperature and then are blended to provide mentioned above component ratio in product.

EFFECT: herbicidal composition of increased activity and deferred hydrolysis in wetted powder.

3 cl, 6 ex, 2 tbl

FIELD: agriculture.

SUBSTANCE: invention relates to composition for seed pickling in form of water suspension concentrate containing thebuconazole and thiabendazole in ratio from 20:1 to 1:20 as active ingredients, nonionic and anionic surfactants, thickener, antifreeze, antifoaming agent, conserving agent, pigment, mineral or vegetable oil, lubricating agent, and water. Preparation of present invention has long shelf-life, freeze resistance, heat aging stability, beneficial effect on plant germination and harvest, and high biological activity. Method for controlling of plant diseases also is disclosed.

EFFECT: seed pickling composition of improved quality.

6 cl, 6 tbl, 5 ex

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to herbicidal composition in form of aqueous emulsion containing a) as organic phase: 5-25 mass % of herbicidally effective amount of 2-(4-(3-chloro-5-fluoro-2-pyridyloxy)-phenoxypropionic acid propargyl eater (component A); 1-6 mass % of 2-(5-chloroquinoline-8-yl-oxy)-acetic acid 1-methylhexyl ester (component B) in amount effective to counteract to herbicide; 10-60 mass % of hydrophobic solvent; 0.5-25 mass % of essentially water insoluble hydrolysis-resistant emulsion stabilizer; and b) as aqueous phase: 0.5-5 mass % of at least one surfactant and/or dispersant, and balance: water buffered with acid and salt mixture in amount of 0.1-1 mol adjusting pH value 4-6. Also disclosed is method for controlling of undesirable plants by application of composition in herbicidally effective amount on plant or growth region thereof.

EFFECT: increased herbicidal activity of component A; stable drop emulsion; high cold stability.

2 cl, 1 tbl, 4 ex

FIELD: agriculture.

SUBSTANCE: liquid herbicide active preparative form contains 0.1-80 mass.% of one or several compounds from group of amphiphilic surfactants with equal advance parties and/or sulfosuccinates, as an active material 0.000-50 mass.% of one or several biologically active materials from group of inhibitors acetolactate synthase (ALS-inhibitors) in the dissolved form, to 60% surface-inactive material, to 90% of organic dissolvent, to 50 % of agricultural chemicals, to 50% of water. The liquid form is gained by mixing of components. The liquid form if necessary diluted with water, is put on seeds, plants, parts of plants or at the cultivated area.

EFFECT: increasing of the form stability.

11 cl, 2 tbl

FIELD: chemistry.

SUBSTANCE: invention relates to field of water neutralisation and relates to biocidal brome-containing composition in solid state, which is obtained by removal of water from water solution or suspension of product obtained in water from (A) (i) brome chloride, (ii) mixture of brome chloride and brome, (iii) brome and chlorine with molar ratio Br2 to Cl2, equal at least 1, or (iv) brome chloride, brome and chlorine in such ratio, that total molar ratio Br2 to Cl2 is equal at least 1; and (B) (i) alkali metal salt of sulfamic acid and/or sulfamic acid and (ii) alkali metal hydroxide, where pH value of said water solution or suspension is equal at least 7 and atom ratio of nitrogen to active brome from (A) and (B) constitutes more than 0.93, and where said composition is obtained by dispersion drying of water solution or suspension, said composition being in form of powder or finely crashed particles. Also described is method of biocidal brome-containing composition in solid state.

EFFECT: increased stability; long preservation of biocidal properties.

10 cl, 6 tbl, 19 ex.

FIELD: medicine.

SUBSTANCE: present invention concerns medicine and describes the liquid antimicrobial composition containing (1) admixture of iodide anions and thiocyanide anions, thereat weight ratio of iodide anions to thiocyanide anions makes from 0.2:1 to 20:1; (2) periodide acid or its salt; and (3) at least, one polymer or a copolymer containing in quality of monomeric units (a) 5-100 wt %, of at least one monoethenoid saturated monomer containing nitrogen - and-or phosphorus-containing groups, (b) 0-95 wt %, of at least, one monoethenoid saturated comonomer, containing acid groups, (c) 0-75 wt %, of at least, one additional comonomer, chosen from the group including monoethenoid saturated monomers, distinct from (a) and (b), and monomers, free from ethylene saturated groups, suitable for formation of polyaethers, and (d) 0-5 wt % of cross-linking comonomers, containing, at least, two ethylene saturated groups.

EFFECT: rising of term of stability and long-term system effectiveness due to including of synthetic polymers and copolymers.

1 tbl, 1 ex, 6 ex

FIELD: chemistry.

SUBSTANCE: invention refers to the field of disinfection; particularly to the preparation of disinfectant composition which can be used in different sectors of national economy. The kit for preparation of disinfectant composition includes: a) individual container with complexing agent - water-soluble sodium ethylendiaminotetraacetates (complexon -II, - III, - IV) or sodium diaminocyclohexanetetraacetates having undergone the mechanical activation and surfactant with complexing agent/surfactant mass ratio being equal 10:(0.2-5); (b) individual container with hydrogen peroxide and the solvent (water and/or alcohol) with hydrogen peroxide/solvent mass ratio being equal 1:(0.3-33.0). At mixing of the containers' components the biologically active nanoparticles are formed in the solution containing complexing agent and hydrogen peroxide in mole ratio 1:(50-200). The containers (a) or (b) contains also the aromatising agent and/or colorant.

EFFECT: invention provides the preparation of disinfectant composition directly at the place of application enhances the shelf life and simplifies the disposal process.

2 ex

FIELD: chemistry.

SUBSTANCE: invention refers to the field of disinfection; particularly to the disinfectants, and can be used in different sectors of national economy. The disinfectant composition includes hydrogen peroxide, complexing agent-sodium ethylendiaminotetraacetates (complexon -II, - III, - IV) or sodium diaminocyclohexanetetraacetates and the solvent (water and/or alcohol). The complexing agent undergoes the mechanical activation providing the forming of biologically active nanoparticles after hydrogen peroxide mixing with complexing agent. The mole ratio of complexing agent and hydrogen peroxide in nanoparticles is 1:(50-200); hydrogen peroxide/complexing agent/solvent mass ratio is 1:(0.001-5):(0.3-33.0). The composition contains also the surfactant with mass ratio hydrogen peroxide/surfactant 1:(0.0001-0.4) and the aromatising agent with mass ratio hydrogen peroxide/aromatizing agent 1:(0.00001-0.5).

EFFECT: invention provides the preparation of disinfectant composition with enhanced scope of antimicrobic effect and decreased corrosion effect.

3 ex

FIELD: medicine.

SUBSTANCE: biocidal composition contains benzalkonium chloride with chain length C12-C16 as a quaternary ammonium compound and also a polyguanidine - polyhexamethyleneguanidine phosphate compound, or poly-(4,9-dioxadodecaneguanidine) chloride, or poly-(4,9-dioxadodecaneguanidine) phosphate, or polyhexamethyleneguanidine succinate, or poly-(4,9-dioxadodecaneguanidine) succinate, oxyethylated sorbitan laurate, polyethylene glycol-7 - glycerol cocoate, camomile extract, great stonecrop aqueous extract, lactic acid and allantoin in defined ratio of components in wt %.

EFFECT: increased biocidal effectiveness, soothing effect on skin and anti-inflammatory properties.

3 tbl, 5 ex

FIELD: agriculture, herbicides.

SUBSTANCE: invention relates to herbicide composition based on derivative of sulfonylurea that comprises non-ionogenic surface-active substance, lignosulfonates as anion-active surface-active substance and highly dispersed amorphous silica as a carrier. Composition comprises chlorsulfuron as derivative of sulfonylurea and triethanolamine or diethanolamine additionally, and potassium dihydrogen phosphate as a stabilizing agent in the following ratio of components, wt.-%: chlorsulfuron, 18-22; non-ionogenic surface-active substance, 3-5; potassium dihydrogen phosphate, 9-12; triethanolamine or diethanolamine, 9-11; lignosulfonates, 3-10, and highly dispersed amorphous silica, the balance. Method involves mixing components in indicated ratios by steps for 3 stages. At the 1-st stage triethanolamine or diethanolamine is applied on surface of highly dispersed amorphous silica, at the 2-d stage - chlorsulfuron, and at 3-d stage - potassium dihydrogen phosphate, lignosulfonates and non-ionogenic surface-active substance. After keeping for 24 h at the room temperature mixing products from all three stages are combined. Invention provides enhancing stability of chlorsulfuron and biological activity of preparation based on thereof. Invention is designated for applying in agriculture.

EFFECT: valuable properties of herbicide composition.

4 cl, 2 tbl, 9 ex

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