Composition for cleaning solid surfaces with component for control on unpleasant odour and methods of solid surface purification

FIELD: chemistry.

SUBSTANCE: invention relates to compositions for purification of solid surfaces, containing acidic component; one or more surfactants; surface-modifying polymer; component for control of unpleasant odour, which contains effective quantity of two or more volatile aldehydes, selected from 2-ethoxybenzylaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylfurfural, 5-methyl-thiophene-carboxaldehyde, adoxal, p-anisic aldehyde, benzylaldehyde, bourgeonal, cinnamic aldehyde, cymal, decyl aldehyde, floral super, florhydral, helional, lauryl aldehyde, ligustral, lyral, melonal, o-anisic aldehyde, linoacetaldehyde, P.T.Bucinal, thiophenecarboxaldehide, trans-4-decenal, trans trans 2,4-nonadienal, undecyl aldehyde; and water carrier ,with component for unpleasant odour control containing from 35% to 60% of volatile aldehydes with B.P. 250°C or higher and ClogP 3.0 or higher; or 25% of aldehydes which have B.P. approximately 250°C or lower and ClogP approximately 3 or lower; or 10% of aldehydes, which have B/P/ 250°C or lower and ClogP 3.0 or higher; or from 10% to 30% of aldehydes, which have B.P. 250°C or higher and ClogP 3.0 or lower.

EFFECT: invention provides neutralisation and concealing wide spectrum of unpleasant odours, including amine and sulphur unpleasant odours.

17 cl, 1 dwg, 10 tbl, 23 ex

 

The technical field to which the invention relates

The present invention relates to compositions for cleaning hard surfaces with a component to control odor and methods of cleaning hard surfaces.

The level of technology

Famous flavored compositions for cleaning hard surfaces. Typically, compositions for cleaning hard surfaces improve perfume technology that provides a pleasant scent and masks unpleasant odors associated with contaminated solid surfaces.

However, not all odors on hard surfaces effectively controlled products on the market, as with amine unpleasant odors such as the smell of fish and urine, and with sulphuric unpleasant odors, such as garlic, onion, legs and fecal odors, difficult to deal with. Additionally, the time required to ensure that the product visibly struggled with the unpleasant smell that may draw consumers ' doubts about the effectiveness of the product against unpleasant odors. For example, the user can finish cleaning a hard surface and leave the area before the product begins to visibly reduce the unpleasant smell.

Difficulties in overcoming a wide range of odors generated a diverse range of products to neitralizovat�, to mask or absorb odors. There remains a need in the composition for cleaning hard surfaces, cleans and is effective for a wide range of odors, including amine and sulfur odors, at the same time not overpowering odors strong smell of perfume.

Summary of the invention.

In one implementation provided a cleaning composition for hard surfaces containing (a) an acid component; (b) a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants; amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; and (C) polymer-modifying surface; (d) a component for controlling odor, containing an effective amount of two or more volatile aldehydes for neutralizing odor, in this case, these two or more volatile aldehydes selected from the group consisting of 2-ethoxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylfentanyl, 5-methyl-thiophene-carboxaldehyde, doxal, p-anisaldehyde, Benzylalcohol, burchenal, cinnamic aldehyde, cymal, DecimalDigit, floral super, floridal, helional, lauric aldehyde, ligustri, oral, Mellon�ü, about-anisaldehyde, pinoytutorial, R. T. butinal, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, undeclared, and mixtures thereof; and (e) aqueous carrier.

In another implementation, a provided composition for cleaning hard surfaces, containing: (a) a mixture of acids containing formic acid and citric acid; (b) a polymer that modifies the surface is selected from the group consisting of: vinylpyrrolidone homopolymer or copolymer; polysaccharide polymer, and mixtures thereof; and (C) component to control odor, containing: (i) at least one volatile aldehyde; and (ii) an acid catalyst having a vapor pressure of from about 0.01 to about 13 at 25°C.

In yet another implementation is provided a method of cleaning a hard surface or object, comprising stages on which: applied composition for treatment of solid material according to claim 1 on said hard surface or the specified object; leaving said composition on said hard surface or a specified target; optional wipe a specified solid surface or object; and then rinsed with a specified surface or the specified object.

Brief description of the drawings

Fig.1 is a graph showing recovery of butandiol the thiophene by carboxaldehyde in combination with various key�acidic catalysts.

Detailed description of the invention

The present invention relates to a composition for cleaning hard surfaces for cleaning various hard surfaces, including surfaces that are in bathrooms, garages, driveways, basements, gardens, kitchens, etc. More specifically, the compositions in accordance with the present invention provide good reduction of unpleasant odors and good characteristics descaling (i.e., removal of sediment clean of scale and/or dirt that contains the scale), while not being corrosive. The present invention also relates to methods for cleaning hard surfaces.

I. Composition for cleaning hard surfaces

The compositions according to the present invention are liquid compositions (including gels) unlike solids or gas. The compositions according to the present invention can have a pH of approximately 2.0, alternative from 2.0 to 4.0, an alternative from 2.5 to 4.0, an alternative from 3.0 to 3.9, alternative from 3.0 to 3.6, alternative from 2.0 to 3.6, alternative from 2.1 to 3.6, alternative from 2.1 to 2.9, alternative from 2.1 to 2.4, alternative from 2.2 to 2.4. Alternatively, the pH of the cleaning compositions in this application, when measured at 25°C may be at least 2.0. the pH of the cleaning compositions in this application, when measured at 25°C may be less than 3,. In one implementation, the compositions according to the present invention are acidic and have a pH above 2.0.

In one implementation of the compositions in this application can have vodopodobnogo viscosity. "Vodopodobnogo viscosity" is meant in this application a viscosity similar to water. Alternatively, the liquid acidic compositions for cleaning hard surfaces in this application have a viscosity of 50 CPS at 60 rpm, an alternative from 0 CPS to 30 CPS, alternative from 0 CPS to 20 CPS, alternative from 0 CPS to 10 CPS at 60 rpm and 20°C when measured using a digital Brookfield viscometer, model DV II, section 2.

In another implementation of the compositions in this application are thickened compositions. Thus, the compositions for cleaning hard surfaces in this alternative application have a viscosity of from 50 CPS to 5000 CPS at 20-1alternative from 50 CPS to 2000 CPS, alternative from 50 CPS to 1000 CPS and alternative from 50 CPS to 500 CPS at 20-1and 20°C when measured with a rheometer, model AR 1000 (supplied TA Instruments) with a 4 cm conic-section stainless steel, 2° angle (linear increment from 0.1 to 100-1for max 8 minutes). Alternatively, the thickened compositions in accordance with this specific osushestvlenie�m are structures with shear thinning. Gelled compositions for cleaning hard surfaces in this application contain alternative thickener, an alternative polysaccharide polymer (as described in this application below) as a thickener, another alternative resinous polysaccharide polymer thickener and alternative xanthan gum.

The compositions according to the present invention may contain from 70% to 99%, by weight of the total composition, of water, alternative from 75% to 95%, alternative from 80% to 95%, and other core and optional komponenty composition is dissolved, dispersed or suspended in water.

A. Acid component

The compositions according to the present invention may contain formic acid. Formic acid, as it has been found to provide excellent characteristics descaling. Formic acid is commercially available from Aldrich.

The compositions according to the present invention can contain from 0.01% to 5%, alternative from 0.5% to 4% alternative 1% to 3%, by weight of the total composition of formic acid.

The compositions according to the present invention may contain citric acid. Acceptable citric acid commercially available from Aldrich, ICl or BASF.

The compositions according to the present invention may contain from 0.1 to 12%, alternative from 1% to 10%, alternative from 1.5% to 8%, alternative from 15% to 5% by weight of the total composition of citric acid.

The applicant unexpectedly found that when using a composition comprising formic acid and citric acid having a pH of above 2.0, acid composition provides good cleaning without being corrosive. Indeed, a similar composition having a pH value less than 2.0 (i.e. not buffered or not buffered enough) will be corrosion. Indeed, the combination of acids along with selected pH provides the optimal combination of descaling and achieve decorationsthe.

Under "corrosion" mean in this application that the composition should be identified as the corrosion by means of appropriate text and/or pictograms in accordance with Directive 1999/45/EC of the European Parliament and of the Council of 31 may 1999 concerning the application of laws, regulations and administrative provisions of the member States concerning the classification, packaging and labelling of dangerous preparations. Under "non corrosive" or "non/is considered as corrosive", etc. mean in this application that the composition should not be labeled as corrosive by means of appropriate text and/or pictograms according to the Directive.

Indeed, it has been found that the compositions for cleaning hard surfaces, containing formic acid and citric acid and has�ing a pH of above 2.0 (alternative 2,01-3,6), provide similar or even better characteristics descaling (i.e., characteristics clean the scale deposits and characteristics of pollution control that contains the scale), compared with the characteristics of the descaling obtained for the same composition having the same pH value, as stated in this application, but containing formic acid or citric acid itself, or other compositions having a lower pH value, as stated in this application, and containing formic acid or citric acid in combination with another acid (e.g., sulfuric acid), at comparable levels of free acidity.

Additionally, the compositions for cleaning hard surfaces, having a pH of above 2.0 and containing formic acid and citric acid, as claimed in this application are not considered to be corrosive.

The present invention also encompasses the use in a liquid acidic composition for cleaning hard surfaces, formic acid, citric acid and an alkaline substance at a pH value above 2.0, with the software features descaling, without being corrosive.

The composition according to the present invention may also include other acids, alternative acetic acid and/or oxalic acid and/or lactic acid.

Was neid�but the presence of lactic acid additionally provides antimicrobial/disinfectant advantages of the compositions according to the present invention. Lactic acid commercially available from Aldrich or Purac.

The compositions according to the present invention may contain from 0.1 to 1%, preferably from 0.1% to 0.75% by weight of the composition of lactic acid.

The compositions in this application may contain acetic acid. Acceptable acetic acid commercially available from Aldrich, or ICI BASF.

The compositions according to the present invention may contain from 0.1 to 1%, alternative from 0.1% to 0.75% by weight of the composition of acetic acid.

The compositions in this application can contain oxalic acid. Acceptable oxalic acid commercially available from Aldrich or Clariant.

The compositions according to the present invention may contain from 0.1 to 1%, alternative from 0.1% to 0.75% by weight of the composition of oxalic acid.

V. Alkaline component

The compositions in this application contain an alkaline substance. Indeed, the alkaline substance may be present to balance the pH and/or maintain the pH of the compositions according to the present invention. Examples of alkaline substances are sodium hydroxide, potassium hydroxide and/or lithium hydroxide, and/or oxides of alkali metals such as sodium oxide and/or potassium and�and mixtures thereof, and/or monoethanolamine and/or triethanolamine. Other suitable bases include ammonia, ammonium carbonate, choline base, etc. In one implementation, the source of alkalinity is a sodium hydroxide or potassium hydroxide, an alternative sodium hydroxide.

Typically the amount of alkaline substance is from 0.001% to 20% by weight, alternative from 0.01% to 10% and alternative from 0.05% to 3% by weight of the composition.

Despite the presence of alkaline substances, if present, the compositions in this application can remain acid compositions.

C. Chelating agent

The compositions according to the present invention may contain a chelating agent or mixtures thereof. Chelating agents can be included in the compositions in this application in amounts ranging from 0% to 10% by weight of the total composition, alternative from 0.01% to 5.0%, alternative from 0.05% to 1%.

Acceptable phosphonate chelating agents for use in this application can include ethane 1-hydroxy diphosphonates alkali metals (HEDP), alkylene poly(alkylenediamine), as well as amino phosphonate compounds, including linolenate(methylenephosphonic acid) (ATMP), nitrilotriacetate (NTP), and (DTPMP). Phosphonate compounds may be present in widecolor, and in the form of salts of different cations on some or all of their acid functionalities.

Acceptable chelating agents for use in this application are (DTPMP) and ethane 1-hydroxyifosfamide (HEDP). In one implementation of the present invention, the chelating agent is selected as ethane 1-hydroxydiclofenac (HEDP). Such phosphonate chelating agents are commercially available from Monsanto under the trade name DEQUEST®.

Polyfunctionally-substituted aromatic chelating agents may also be useful in the compositions in this application. Cm. U.S. patent 3,812,044, issued may 21, 1974, to Connor et al. Acceptable compounds of this type in acid form are dihydroxyazobenzene, such as 1,2-dihydroxy-3,5-disulfonate.

Byroslawsky chelating agent for use in this application is Ethylenediamine N,N'-diantara acid, or its alkali metal salt or alkaline earth metal, ammonium or substituted ammonium or mixtures thereof.

Ethylenediamine N,N'-diantaranya acid, in particular (S,S)-isomer, were described in detail in U.S. patent 4,704,233, issued November 3, 1987 to Hartman and Perkins. Ethylenediamine N,N'-diantara acid, for example, commercially available under the trade name ssEDDS® from Palmer Research Laboratories.

Acceptable aminocarboxylate for use in this Zaya�ke include ethylenediaminetetraacetate, diethylenetriaminepentaacetate, diethylenetriaminepentaacetate (DTPA), N-hydroxyethylacrylate, nitrilotri-acetates, ethylendiaminetetraacetic, Triethylenetetramine-acetates, ethanolgasoline, Propylenediamine acid (PDTA) and methylpyridoxine acid (MGDA), in their acidic form or in the form of their alkali metal salts, ammonium and substituted ammonium. Particularly acceptable aminocarboxylate for use in this application are diethylenetriaminepentaacetic acid, Propylenediamine acid (PDTA) which is, for example, commercially available from BASF under the trade name Trilon FS® and methylpyridoxine acid (MGDA).

Further carboxylate chelating agents for use in this application include salicylic acid, aspartic acid, glutamate acid, glycine, malonic acid or mixtures thereof.

It has surprisingly been found that the addition of a chelating agent, alternative HEDP, in the composition according to the present invention provides an unexpected improvement in terms of descaling.

D. Surfactants

The compositions according to the present invention may contain a nonionic surfactant or a mixture and/or anionic surfactant or a mixture. In one implementation, sostaviv accordance with the present invention comprise a mixture of nonionic surfactants or mixtures thereof, and anionic surfactants or mixtures thereof. Indeed, it has surprisingly been found that such a mixture contributes to the characteristics of descaling and dirty soapy foam compositions in this application.

The compositions according to the present invention may contain a nonionic surfactant or a mixture. This class of surfactants can be desirable because it makes an additional contribution to the characteristics of cleaning compositions for cleaning hard surfaces in this application. It was found, in particular, nonionic surfactants greatly contribute to the achievement of vysokomolochnyh characteristics removal of dirty suds, a useful effect is particularly observed when the pH value is above a 3.0.

The compositions according to the present invention can contain up to 15% by weight of the total composition of non-ionic surfactants or mixtures thereof, alternative from 0.1% to 15%, alternative from 1% to 10%, even alternative from 1% to 5% and alternative from 1% to 3%.

Acceptable non-ionic surfactants for use in this application are alkoxycarbonyl alcohol nonionic surfactants that can be easily obtained by condensation processes, well known in the art. However, a great many of these alkoxysilane alcohols, in special�spine ethoxylated and/or propoxycarbonyl alcohols, traditionally commercially available. Catalogues are available surfactants, which lists a number of surfactants, including nonionic.

Accordingly, acceptable alkoxycarbonyl alcohols for use in this application are non-ionic surfactants of the formula RO(E)e(P)pH where R is a hydrocarbon chain containing from 2 to 24 carbon atoms, E represents ethylene oxide and P represents a propylene oxide, and e and p which represent the average degree of, respectively amoxilonline and propoxycarbonyl range from 0 to 24 (sum of e+p, at least, is 1). Alternatively, the hydrophobic fragment of the non-ionic compounds may be primary or secondary, straight or branched alcohol having from 8 to 24 carbon atoms.

Acceptable non-ionic surfactants for use in compositions in accordance with the present invention are the condensation products of ethylene oxide and/or propylene oxide with alcohols having a straight or branched alkyl chain having from 6 to 22 carbon atoms, where the degree of alkoxysilane (ethoxycarbonyl and/or propoxycarbonyl) is from 1 to 15, an alternative from 5 to 12. Such acceptable non-ionic surfactant commercially available from Shell, for example under Thor�new name Neodol® or from BASF under the trade name Lutensol®.

The compositions according to the present invention may contain an anionic surfactant or a mixture. The compositions according to the present invention can contain up to 15% by weight of the total composition of an anionic surfactant or mixtures thereof, alternative from 0.1% to 15%, alternative from 1% to 10%, even alternative from 1% to 5% and alternative from 1% to 3%.

Anionic surfactants can be included in this application, since they contribute to the cleaning advantages of the compositions for cleaning hard surfaces, in accordance with the present invention. Indeed, the presence of anionic surfactant contributes to the cleaning of dirty soapy foam compositions in this application. In General, the presence of anionic surfactants in the liquid acidic compositions according to the present invention allows to reduce surface tension and improve wetting of the surfaces of the treated liquid acidic compositions according to the present invention. Additionally, an anionic surfactant or a mixture contributes to solubilization of impurities in the compositions according to the present invention.

Acceptable anionic surfactants for use in this application are common�known to specialists in this field of technology. In one implementation, the anionic surfactants for use in this application include sulfonates, alkylarylsulfonates or mixtures thereof.

Acceptable linear alkyl sulphonates include C8 sulfonate, such as Witconate ® NAS 8, commercially available from Witco.

Other anionic surfactants useful in this application include salts (including, for example, salts of sodium, potassium, ammonium and substituted ammonium such as mono-, di - and triethanolamine salts) of soap, alkylsulfate, alkylarylsulfonate, alkoxysilane sulfates, C8-C24 reincorporate, sulfonated polycarboxylic acids obtained by sulfonation of the pyrolysis products of alkaline earth metal citrates, e.g., as described in the description of British patent No. 1,082,179; alkylether sulfonates, such as With 14-16 methylether sulfonates; acylglucuronide alkyl phosphates, isethionate, such as utilizationin, N-allcounty, alkylacrylate, acylcarnitine, sulfates of alkylpolyglucoside, such as sulfates of alkylpolyglucoside (nonionic desulfuromonas compounds described below), alkylpolyoxyethylene, such as those having the formula RO(CH2CH2O)kCH2COO-M+, where R represents a C8-C22 alkyl, k is an integer from 0 to 10 and M is a soluble salt-forming cation. Resin acids and gidrogenit�available resin acids are also acceptable for example rosin, gidrirovannoe rosin, and resin acids and hydrogenated resin acids present in or derived from tall oil. Other examples are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch). A variety of such surfactants are also generally described in U.S. patent 3,929,678, issued December 30, 1975, issued to Laughlin, et al. column 23, line 58 to column 29, line 23.

E. Polymer-modifying surface

The compositions according to the present invention can optionally contain vinylpyrrolidone homopolymer or copolymer, or a mixture thereof. Typically, the compositions according to the present invention can contain from 0.01% to 5% by weight of the total composition vinylpyrrolidone homopolymer or copolymer or a mixture thereof, an alternative from 0.05% to 3% and alternative from 0.05% to 1%.

Acceptable vinylpyrrolidone the homopolymers for use in this application are the homopolymers of N-vinylpyrrolidone having the following repeating monomer:

where n (degree of polymerisation) is an integer from 10 to 1000000, alternative from 20 to 100000 and alternative from 20 to 10,000.

Accordingly, acceptable vinylpyrrolidone the homopolymers ("PVP") for use in this application have an average molecular weight of from 1000 to 10,000,000, alternative from 2,000 to 10,000,000, alternative from 5,000 to 1,000,000 and alternative from 50000 to 500000.

Acceptable vinylpyrrolidone the homopolymers commercially available from ISP Corporation, New York, NY and Montreal, Canada under the product names PVP K-15® (srednevozrastnoe molecular weight of 10,000), PVP K-30® (average molecular weight of 40,000), PVP K-60® (average molecular weight of 160,000), and PVP K-90® (average molecular weight 360000). Other acceptable vinylpyrrolidone the homopolymers are commercially available from BASF Cooperation include Sokalan HP 165®, Sokalan HP 12®, Luviskol K30®, Luviskol K60®, Luviskol K80®, Luviskol K90®; vinylpyrrolidone the homopolymers known to specialists in this field of detergents (see, for example, EP-A-262,897 and EP-A-256,696).

Acceptable vinylpyrrolidone copolymers for use in this application include copolymers of N-vinylpyrrolidone and alkylene unsaturated monomers or mixtures thereof.

Alkylene unsaturated monomers of the copolymers in this application include unsaturated dicarboxylic acids such as maleic acid, hermalinda acid, fumaric acid, taconova acid, Tarakanova acid, fenilalanina acid, akonita acid, acrylic acid, N-vinylimidazole and vinyl acetate. Any of the anhydrides of unsaturated acids may be used, for example acrylate, methacrylate. Can be used aromatic monomers, such as styrene, sulphonated styrene, alpha-methylsterol, Dalwallinu, tert-butalbiral and similar well-known monomers.

For example, acceptable N-vinylimidazole N-vinylpyrrolidone polymers for use in this application have an average molecular weight in the range from 5000 to 1000000, alternative from 5000 to 500000 and alternative from 10000 to 200000. The range of the average molecular weight was determined by light scattering as described in Barth H. G. and Mays J. W. Chemical Analysis Vol 113, "Modern Methods of Polymer Characterization".

Such copolymers of N-vinylpyrrolidone and alkylene unsaturated monomers, e.g., PVP/vinyl acetate copolymers, commercially available under the trade name Luviskol® series from BASF.

In one implementation of the present invention are choosing vinylpyrrolidone the homopolymers.

The compositions according to the present invention may optionally contain a polysaccharide polymer or a mixture. Typically, the compositions according to the present invention can contain from 0.01% to 5% by weight of the total composition of a polysaccharide polymer or mixtures thereof, alternative from 0.05% to 3% and alternative from 0.05% to 1%.

Acceptable polysaccharide polymers for use in this application include substituted cellulose materials like carboxymethylcellulose, ethylcellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxymethylcellulose�, succinogenes and natural polysaccharide polymers like xanthan gum, Galanova gum, guar gum, gum carob, tragacanth gum or derivatives thereof, or mixtures thereof.

In one implementation of the compositions according to the present invention comprise a polysaccharide polymer selected from the group consisting of: carboxymethylcellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxymethylcellulose, succinogenes resin, xanthan gum, Galanova gum, guar gum, gum carob, tragacanth gum, derivatives of the foregoing, and mixtures thereof. Alternatively, the compositions in this application contain a polysaccharide polymer selected from the group consisting of: entrance succinogenes resin, xanthan gum, Galanova gum, guar gum, gum carob, tragacanth gum, derivatives of the foregoing, and mixtures thereof. Alternatively, the compositions in this application contain a polysaccharide polymer selected from the group consisting of: xanthan gum, Galanova gum, the guar gum, derivatives of the foregoing, and mixtures thereof. Alternatively, the compositions in this application contain xanthan gum, its derivatives, or mixtures thereof.

Specific polysaccharide polymers for use in this application are to xanthan�copper and its derivatives. Xanthan gum and its derivatives can be commercially available, for example, from CP Kelco under the trade name Keltrol RD®, K-elzan S® or Kelzan T®. Other suitable xanthan gums are commercially available from Rhodia under the trade name Rhodopol T® and Rhodigel X747®. Coccinellinae gum for use in this application is commercially available from Rhodia under the trade name Rheozan®.

It has surprisingly been found that polysaccharide polymers or mixtures thereof in this application are as polymers, modifying the surface (alternative combined with vinylpyrrolidones a homopolymer or copolymer, as described in this application) and/or as thickeners. Indeed, polysaccharide polymers or mixtures thereof in this application can be used to thicken compositions in accordance with the present invention. It has surprisingly been found that the use of polysaccharide polymers or mixtures thereof in this application, and alternative xanthan gum, provides excellent thickening characteristics of the compositions in this application. Additionally, it was found that the use of polysaccharide polymers or mixtures thereof in this application, and preferably xanthan gum, provides excellent thickening, not slimming or only minimally reducing characteristics descaling. Indeed, sagus�best compositions usually as a rule, show a decrease of the characteristics remove dirt/stains (which, in turn, requires a higher level of active substances to compensate for the decrease in the characteristics) due to the thickening. It was found that this is due to the fact that active substances that provide features remove dirt/stains, less freely migrate to dirt/stains. However, surprisingly been found that if the polysaccharide polymers or mixtures thereof in this application, and alternative xanthan gum, are used as thickeners for the compositions in this application, the reduction characteristics remove dirt/stains on the substance is reduced or even prevented.

Additionally, without being bound by theory, it was shown that vinylpyrrolidone the homopolymers or copolymers alternative vinylpyrrolidone homopolymer, and polysaccharide polymers, alternative xanthan gum and its derivatives, described in this application, when added to aqueous acid composition provide an increased gloss of the treated surface, as well as the advantage of a further improved cleaning of said surface, while providing a good first-time characteristics for cleaning hard surfaces, the effectiveness and good performance of the descaling. Additionally, education �single spots and/or scale deposits after drying is reduced or even eliminated.

Additionally, vinylpyrrolidone the homopolymers or copolymers and polysaccharide polymers provide long lasting protection against formation of water stains and/or scum deposits, hence, long-term preservation shiny surfaces.

An additional advantage associated with the use of vinylpyrrolidone of homopolymers or copolymers and polysaccharide polymers in the acid compositions in this application, is that they are kept on a hard surface, making it more hydrophilic, the surfaces themselves become smoother (this can be perceived by touching these surfaces), and it facilitates the transfer of the perception of surface without scaling.

These beneficial effects can be obtained at low levels vinylpyrrolidone of homopolymers or copolymers and polysaccharide polymers, alternative xanthan gum and its derivatives, described in this application.

The compositions in this application may further contain a polymer, modifying the surface, except vinylpyrrolidone Homo - and copolymers and polysaccharide polymers, described in this application above.

The composition in this application can contain up to 5%, alternative from 0.0001% to 3%, alternative from 0.001% to 2% and alternative from 0.01% to 1%, by weight of the total composition of said other polyester�ditch modifying the surface.

Other polymers which modify the surface may be optional ingredients in this application, since they are deposited on surfaces that are cleaned with a composition according to the present invention. This prevents the adhesion of dirt, soap scum, limescale and/or mineral crusts.

Acceptable other polymers, modifying the surface, can be selected from the group consisting of: zwitterionic copolymers, modifying the surface, consisting of carboxylate - and permanent cationic fragments, zwitterionic poliolefinovykh copolymers, modifying the surface; zwitterionic polimetinovymi copolymers, modifying the surface, siliconvalley polymers and their mixtures.

Zwitterionic copolymers, modifying the surface, consisting of carboxylate - and permanent cationic fragments, zwitterionic poliolefinovykh copolymers, modifying the surface, and zwitterionic polimetinovymi copolymers, modifying the surface described in WO 2004/083354, EP-A-1196523 and EP-A-1196527. Acceptable zwitterionic copolymers, modifying the surface, consisting of carboxylate - and permanent cationic fragments, zwitterionic poliolefinovykh copolymers, modifying the surface, and zwitterion�'s polimetinovymi copolymers, modifying the surface, commercially available from Rhodia in Mirapol SURF S-series polymers.

Alternative copolymers, modifying the surface described in concurrently pending European patent applications of the Applicant 07113156.9, such copolymers are sulfobetaine/vinyl pyrrolidone and their copolymers derived. Particularly acceptable sulfobetaine/vinyl pyrrolidone and derivative copolymer is a copolymer of 90% moles of vinylpyrrolidone and 10% moles of SPE (sulforhodamine methacrylate), as illustrated in Example 1.1 simultaneously pending European patent applications of the Applicant 113 07 156.9.

Acceptable siliconpirate described in concurrently pending European patent applications of the Applicant 03 447 099.7 and 03 447 098.9, in the section entitled "Siliconpirate".

Siliconvalley polymers commercially available from General electric, Dow Coming, and Witco (see European patent application 03447099.7 and 03447098.9 below for an expanded list of trade names siliconvalley polymers).

In one implementation consistent with the present invention, siliconvalley polymer in this application is a copolymer of silicones and polyethers, commercially available under the trade name SF 1288® from Momentive Performance Materials.

F. Acceptor for�Alov

The compositions according to the present invention may further comprise acceptors radicals, or mixtures thereof.

Acceptable acceptors radicals for use in this application include well-known substituted mono - and dihydroxybenzene and their analogs, alkyl and arylcarboxylic and mixtures thereof. Preferred acceptors radicals for use in this application include di-tert-stabilizer (BHT), hydroquinone, di-tert-butylhydroquinone, mono-tert-butylhydroquinone, tert-butyl-hydroxy anisole, benzoic acid, Truelove acid, catechol, tert-butylcatechol, benzylamine, 1,1,3-Tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane, n-propyl-gallate or mixtures thereof and highly preferred is di-tert-stabilizer. Such acceptors radicals, N-propyl-gallate may be commercially available from Nipa Laboratories under the trade name Nipanox S1®.

The acceptors radicals, when used, may typically be present in this application in amounts up to 10% by weight of the total composition and alternative from 0.001% to 0.5% by weight. The presence of acceptors radicals may increase the chemical stability of the compositions according to the present invention.

G. Solvent

The compositions according to the present invention may further contain a solvent or a mixture, as optional ingredients will not damage�NTA. Solvents for use in this application include all solvents for compositions for cleaning hard surfaces known to those skilled in the art. In one implementation, the compositions in this application contain alkoxycarbonyl glycol ether (for example, n-butoxypropyl (n-BPP)) or a mixture.

Typically, the compositions according to the present invention may contain from 0.1% to 5% by weight of the total composition of a solvent or mixtures thereof, alternative from 0.5% to 5% by weight of the total composition and alternative from 1% to 3% by weight of the total composition.

N. Additional surfactant

The compositions according to the present invention may contain additional surface-active substance or mixtures thereof, above in this application already described nonionic surfactant and/or anionic surfactant. Additional surfactants may be desirable in this application because they further contribute to the characteristics of the cleaning and/or useful the glitter effect of the compositions according to the present invention. Surfactants for use in this application include cationic surfactants, amphoteric surfactants, zwitterionic surfactants and and� mixture.

Accordingly, the compositions according to the present invention can contain up to 15% by weight of the total composition of another surfactant or mixtures thereof, nonionic surfactant already described above in this application, alterantive from 0.5% to 5%, even alterantive from 0.5% to 3% and alterantive from 0.5% to 2%. Various surfactants can be used in the present invention, including anionic, cationic, zwitterionic or amphoteric surfactants. It is also possible to use mixtures of such surfactants, without departing from the gist of the present invention.

Acceptable surfactants for use in this application are zwitterionic surfactants, as they provide superb ability to clean dirty soapy foam compositions in accordance with the present invention.

Acceptable zwitterionic surfactants for use in this application contain both basic and acidic groups which form an internal salt, giving both cationic and anionic hydrophilic groups in the same molecule at a relatively wide range of pH values. The typical cationic group is a Quaternary ammonium group, although can be used, etc�many positively charged groups, such as postname, imidazoline and sulfonamide group. The typical anionic hydrophilic groups are carboxylates and sulfonates, although other groups like sulfates, phosphonates, and the like.

Some common examples of zwitterionic surfactants (i.e., betaine/sulphobetaine) described in U.S. patents №№2,082,275, 2,702,279 and 2,255,082. For example, coconut dimethylbutan commercially available from Seppic under the trade name Amonyl 265®. Laurylether commercially available from Albright &Wilson under the trade name Empigen BB/L®. Further example of betaine is lauryl-imino-dipropionate commercially available from Rhodia under the trade name Mirataine H2C-HA®.

In one implementation, the composition contains sulfobetaine surfactants, because they can provide optimal benefits of cleaning soap suds. Examples of acceptable sulfobetaine surfactants include tavatuy bis(hydroxyethyl)sulphobetaine, , which are commercially available from Rhodia and Witco, under the trade name of Mirataine CBS® and Rewoteric AM CAS 15®, respectively.

Amphoteric and apoliticism detergents, which can be either cationic or anionic depending on the pH of the system, represented by detergents such as DoD�civeta-alanine, N-alkylarene, such as obtained by reaction of dodecylamine with isethionate sodium in accordance with the doctrine of U.S. patent No. 2,658,072, N-higher alkalisation acids, such as obtained in accordance with the doctrine of U.S. patent No. 2,438,091, and products sold under the trade name "Miranol" and described in U.S. patent No. 2,528,378. Additional synthetic detergents and a list of their commercial sources can be found in McCutcheon's Detergents and Emulsifiers, North American Ed. 1980.

Acceptable amphoteric surfactants include aminoxide. Examples of aminoxide for use in this application are, for example, coconut dimethylaminoacetyl, C12-C16 dimethylaminoacetyl. These aminoxide may be commercially available from Clariant, Stepan and AKZO (under the trade name Aromox®). Other suitable amphoteric surfactants for the purposes of the present invention are phosphine or sulfoxide surfactants.

Cationic surfactants suitable for use in the compositions according to the present invention, are those having long-chain hydrocarbon group. Examples of such cationic surfactants include Quaternary ammonium surfactants, such as alkyd�methylammonium halides. Other cationic surfactants useful in this application are also described in U.S. patent No. 4,228,044, Cambre, issued October 14, 1980

I. Dye

The compositions according to the present invention can be painted. Accordingly, they may include a dye or a mixture. Acceptable dyes for use in this application are acid-stable dyes. By "acid-stable" is meant in this application a compound which is chemically and physically stable in the acidic environment of the compositions in this application.

J. Component to control odor

Composition for cleaning hard surfaces contains a component for the control of odors. Component to control odor may include at least one volatile aldehyde and an acid catalyst. Component to control odor designed to provide genuine neutralize unpleasant odor and does not function only through a cover up or mask odors. Genuine neutralization of unpleasant odors delivers a sensory and analytically measurable (for example, using gas chromatography) reducing unpleasant odor. Thus, if the component to control unpleasant odors delivers an authentic neutralize unpleasant odor, �remaining will reduce odors in the steam and/or liquid phase.

1. Volatile aldehydes

Component to control odor comprises a mixture of volatile aldehydes, which neutralize unpleasant odors in the steam and/or liquid phase via chemical reactions. Volatile aldehydes are also called reactive aldehydes (RA). Volatile aldehydes can react with amine odor, along the route of formation of Schiff bases. Volatile aldehydes can also react with sulfur odors, forming thioacetal, hemicolectomy and thiol esters in the steam and/or liquid phase. It may be desirable to volatile aldehydes in the steam and/or liquid phase had a virtual negative impact on the desired character of the fragrance of the product. Aldehydes, which are partially volatile, can be considered as volatile aldehyde, as used in this application.

Acceptable volatile aldehydes may have a vapour pressure (VP) in the range from about of 0.0001 Torr to 100 Torr, alternative from about of 0.0001 Torr to about 10 Torr, an alternative from about 0,001 Torr to about 50 Torr, alternative from approximately about 0.001 Torr to about 20 Torr, alternative from about 0,001 Torr to approximately 0,100 Torr, alternative from about 0,001 Torr to 0.06 Torr, alternative from approximately about 0.001 Torr to 0.03 Torr, �lternative from approximately from 0.005 Torr to about 20 Torr, alternative from about 0.01 Torr to about 20 Torr, alternative from about 0.01 Torr to about 15 Torr, alternative from about 0.01 Torr to about 10 Torr, an alternative from about 0.05 Torr to about 10 Torr, measured at 25°C.

Volatile aldehydes may also have a certain boiling point (B. R.) and the distribution coefficient octanol/water (P). Boiling point in this application refers to measurable under normal standard pressure of 760 mm Hg.PT. The boiling points of many volatile aldehydes at standard 760 mm Hg.PT. shown in, e.g., "Perfume and Flavor Chemicals (Aroma Chemicals)," written and published by Steffen Arctander, 1969.

The distribution coefficient octanol/water volatile aldehyde is the ratio between its equilibrium concentrations in octanol and in water. The partition coefficients of volatile aldehydes used in the component to control odor, can be more conveniently represented in the form of their logarithm to the base 10, logP. Been reported logP values of many volatile aldehydes. See, for example, the database Pomona92, available from Daylight Chemical Information Systems, Inc. (Daylight CIS), Irvine, California. However, the logP values are most conveniently calculated using the program "CLOGP", also available from Daylight CIS. This program also lists experimental value�ia logP, if they are available in the database Pomona92. The "calculated logP" (ClogP) is determined by the fragmented approach of Hansch and Leo (cf., A. Leo, in Comprehensive Medicinal Chemistry, Vol.4, C. Hansch, P. G. Sammens, J. B. Taylor and C. A. Ramsden, Eds., p.295, Pergamon Press, 1990). A piecemeal approach is based on the chemical structure of each volatile aldehyde and takes into account the number and types of atoms, the bond between atoms and chemical bonding. The ClogP values, which are the most reliable and widely used, evaluate the given physico-chemical property and their alternative is used instead of the experimental logP values in the selection of volatile aldehydes for the component to control odor.

ClogP values can be defined using four groups, and volatile aldehydes can be selected from one or more of such groups. The first group comprises volatile aldehydes that have a B. R. of about 250°C or less and ClogP of about 3 or less. The second group comprises volatile aldehydes that have a B. R. 250°C or less and ClogP of 3.0 or more. The third group comprises volatile aldehydes that have a B. R. 250°C. or more and ClogP of 3.0 or less. The fourth group comprises volatile aldehydes that have a B. R. 250°C. or more and ClogP of 3.0 or more. Component to control bad breath can contain any combination of volatile aldehydes from one or more ClogP groups.

In some realizations, a component for controlled�I smell in accordance with the present invention may contain, on the total weight of the component to control odor, from about 0% to about 30% of volatile aldehydes from group 1, alternative approximately 25%; and/or from about 0% to about 10% of volatile aldehydes from group 2, alternative approximately 10%; and/or from about 10% to about 30% of volatile aldehydes from group 3, alternative approximately 30%; and/or from about 35% to about 60% of volatile aldehydes from group 4, alternative approximately 35%.

Acceptable volatile aldehydes that can be used in a component to control unpleasant odors include, but are not limited to shows, doxal (2,6,10-trimethyl-9-undecenal), bourgeonal (4-t-butylbenzaldehyde), linestyles 33 (2-methyl-4-t-butylphenyl)propanal), cinnamic aldehyde, cinnamic aldehyde (phenyl, propenal, 3-phenyl-2-propenal), citral, geranial, neral (dimethyloctadecyl, 3,7-dimethyl-2,6-octadien-1-al), zikel With (2,4-dimethyl-3-cyclohexene-1-carbaldehyde), forgital (3-(3-isopropyl-phenyl)-Butyraldehyde), and citronellal (3,7-dimethyl 6-octenal), cymal, cyclamen aldehyde, cyclosal, lemon aldehyde (alpha-methyl-p-isopropylidenediphenol aldehyde), metilnorarenalin, aldehyde 12 MNA (2-methyl-1-undecanal), hydroxycitronellal, and citronellal hydrate (7-hydroxy-3,7-dimetil�tan-1-al), geranial (alpha-methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, hydrocinnamaldehyde (3-phenylpropanal, 3-phenylpropionaldehyde), intralevel aldehyde (undec-10-EN-1-al), ligustri, Trivastal (2,4-dimethyl-3-cyclohexene-!-carboxaldehyde), asmarani, catenalogic (2-methyl-3-Tripropylamine, 4-dimethylaminopropanol), lyral (4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde), melonal (2,6-dimethyl-5-heptenal), methoxymethyl (6-methoxy-2,6-dimethylheptyl), methoxycinnamaldehyde (TRANS-4-methoxycinnamaldehyde), mirak aldehyde isohexane cyclohexenyl-carboxaldehyde, triphenyl ((3-methyl-4-phenylpropanal, 3-phenylbutyl), lilial, R. T. buzing, lysmeral, benzopyranyl (4-tert-butyl-alpha-methyl-hydrocinnamaldehyde), topical, tricyclodecane (4-tricyclo-2.6 deciliter-butanal), olaflur (1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde), methylacrylamide, aldehyde C-11 MOA (2-Merdeka-1-al), homicidal (2,6,10-trimethyl-5,9-undecadien-1-al), citronellyl oxyacetylene, Mpumalanga 50 (3,7-dimethyl-6-octenyl) oxyacetylene), phenylacetaldehyde, migranal (3-methyl-5-phenylpentane), triplel, vertical dimethyl tetrahydrobenzo aldehyde (2,4-dimethyl-3-cyclohexene-1-carboxaldehyde), 2-phenylpropionaldehyde, hydrotroilite, kuntosali, resiprocal 4-methoxy-alpha-methylbenzol�propanal (2-antiliberal), clikeman And (1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde), and precision In (1-cyclohexene-1-carboxaldehyde).

Another illustrative aldehydes include, but are not limited to shows, acetaldehyde (ethanal), pentanal, valeraldehyde, lillegal, sentinal (octahydro-5-methoxy-4,7-methano-1H-indene-2-carboxaldehyde), Propionaldehyde (propanal), cyclocitral, beta-cyclocitral, (2,6,6-trimethyl-1-cyclohexene-1-acetaldehyde), sziklarol (2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde), Isobutyraldehyde, Butyraldehyde, isovaleraldehyde (3-methylbutyraldehyde), methylbutyraldehyde (2-methylbutyraldehyde, 2-methylbutanal), digitaldreamer (3,7-dimethyloctan-1-al), 2-ethylbutyraldehyde, 3-methyl-2-butenal, 2-methylpentanol, 2-methylvaleraldehyde, hexenal (2-hexenal, TRANS-2-hexenal), heptanal, octanal, nonanal, decanal, lauryl aldehyde, tridecanal, 2-dodecanal, methylthiomethyl, glutaraldehyde, pentanedial, glutaraldehyde, heptanal, CIS or TRANS-heptenal, undecenal(2-, 10-), 2,4-octadienal, nonenal (2-, 6-), decanal(2-, 4-), 2,4-hexadienal, 2,4-decadienal, 2,6-nonadienal, octenal, 2,6-dimethyl 5-heptenal, 2-isopropyl-5-methyl-2-hexenal, traversal, betamethasoni, 2,6,6-trimethyl-1-cyclohexene-1-acetaldehyde, phenyl, butenyl (2-phenyl 2-butanol), 2-methyl-3(p-isopropylphenyl)-propionamide�d, 3-(p-isopropylphenyl)-Propionaldehyde, p-collateralised (4-methylphenylacetonitrile), anisaldehyde (p-methoxybenzoyl aldehyde), benzaldehyde, vernalized (1-methyl-4-(4-methylpentyl)-3-cyclohexenecarboxaldehyde), heliotropin (piperonal) 3,4-methylenedioxybenzene, alpha imilarity aldehyde, 2-pentyl-3-phenylpropenoic aldehyde, vanillin (4-methoxy 3-hydroxybenzaldehyde), ethylvanillin (3-ethoxy 4-hydroxybenzaldehyde), hexylcaine aldehyde, ammonal N (alpha-n-hexyl-cinnamaldehyde), floraison, (para-ethyl-alpha,alpha-dimethyl hydrocinnamaldehyde), Acalea (n-methyl-alpha-interconnected), methylcinnamaldehyde, alpha methylcinnamaldehyde (2-methyl 3-phenylpropenal), alpha hexylcinnamaldehyde (2-hexyl 3-phenyl, propenyl), salicylic aldehyde (2-hydroxy benzaldehyde), 4-ethylbenzaldehyde, semenovii aldehyde (4-isopropylbenzaldehyde), ethoxybenzaldehyde, 2,4-dimethylbenzaldehyde, veratraldehyde (3,4-dimethoxybenzaldehyde), syring aldehyde (3,5-dimethoxy 4-hydroxybenzaldehyde), categroy aldehyde (3,4-dihydroxybenzaldehyde), safranal (2,6,6-trimethyl-1,3-diene methanal), myrtenal (pin-2-ene-1-carbaldehyde), perillaldehyde L-4(1-methylethenyl)-1-cyclohexene-1-carboxaldehyde), 2,4-dimethyl-3-cyclohexene carboxaldehyde, 2-methyl-2-pentenal, 2-methylpentanol, grape aldehyde, formyl, tricyclodecane, tangerine al�of digid, cyclemax, Pino acetaldehyde, Corps Iris, Mazal Corps and 4322.

In one implementation, a component to control odor includes a mixture of two or more volatile aldehydes selected from the group consisting of 2-ethoxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylpyrrole, 5-methyl-thiophene-carboxaldehyde, alaxala, p-anisic aldehyde, benzyl aldehyde, burgens, cinnamic aldehyde, chimala, decyl aldehyde, florala super, floridale, gelinas, lauryl aldehyde, ligustrina, liras, melons, o-anisic aldehyde, pinealectomized, R. T. bocinas, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, odesilaneho aldehyde and mixtures thereof.

In some realizations, a component to control odor includes responsive volatile aldehydes. "Responsive volatile aldehydes" refers to volatile aldehydes, which are either (1) reduce the smell of ammonia at 20% or more in less than 40 seconds; or (2) reduce thiol odors of 20% or more in less than 30 minutes.

In one implementation, a component to control odor comprises a mixture of volatile aldehydes listed in Table 1, which in this application is the name of the Note A.

Table 1 - Note A
SubstanceWt.%CAS numberClogP groupVP (Torr) @ 25°C
Intralevel aldehyde5,000112-45-830,060
Forgital10,000125109-85-540,008
Floral super25,00071077-31-13-0,030
Sentenal10,00086803-90-920,010
Cemal25,000103-95-740,007
O-anisaldehyde25,000135-02-410,032

In another implementation, a component to control odor comprises a mixture of volatile Aldagi�s, listed in Table 2, which in this application is called a Hint V.

Table 2 - Note
SubstanceWt.%CAS numberClogP groupVP (Torr) @ 25°C
Intralevel aldehyde2,000112-45-830,060
Forgital20,000125109-85-540,008
Floral super10,00071077-31-130,030
Sentenal5,00086803-90-920,010
Cemal25,000103-95-740,007
Floraison10,00067634-14-4 40,005
Doxal1,000141-13-940,007
Metilnorarenalin1,000110-41-830,030
Melonal1,000106-72-930,670
O-anisaldehyde25,000135-02-410,032

In another implementation, a component to control odor comprises a mixture of approximately 71.2 percent volatile aldehydes, the remainder is another ester and alcohol raw materials fragrances. This mixture are listed in table 3, which in this application is the name of the Note C.

4
Table 3 - a Note From
Substance Wt.%CAS numberClogP groupVP (Torr) @ 25°C
Intralevel aldehyde2,000112-45-830,060
Forgital10,000125109-85-540,008
Floral super5,00071077-31-130,030
Sentenal2,00086803-90-920,010
Cemal15,000103-95-740,007
Floraison12,00067634-14-440,005
Doxal1,000141-13-90,007
Metilnorarenalin1,000110-41-830,030
Melonal1,000106-72-930,670
Floricet11,8005413-60-510,060
Froten7,00017511-60-340,020
Helional5,0001205-17-020,0005
Bourgeonal2,00018127-01-040,004
Linalool10,00078-70-630,050
0,200100-52-711,110
O-anisaldehyde15,000135-02-410,320

Notes A, b or C can be formulated in a composition with other raw materials for fragrances in amounts, for example, approximately 10% by weight of the component to control odor. Additionally, individual volatile aldehydes or various combinations of volatile aldehydes can be delivered in a composition in a component to control odor. In certain implementation, the volatile aldehydes may be present in an amount up to 100%, by weight of the component to control odor, alternative from 1% to about 100%, alternative from approximately 2% to approximately 100%, an alternative from approximately 3% to approximately 100%, an alternative from approximately 50% to approximately 100%, an alternative from approximately 70% to approximately 100%, an alternative from about 80% to about 100%, alternative from about 1% to about 20%, alternative from about 1% to about 10%alternative from about 1% doprinosilo 5%, alternative from about 1% to about 3%, alternative from approximately 2% to approximately 20%, alternative from approximately 3% to approximately 20%, alternative from approximately 4% to approximately 20%, and alternative from approximately 5% to approximately 20%, by weight of the composition.

In some realizations, where the volatility is not important to neutralize the unpleasant odors, the present invention may include polyallelic, for example di-, tri-, Tetra-aldehydes. Such implementation may include detergents for washing, additives, etc., to remove by washing and vypolaskivat, various types of precipitated substances.

2. Acid catalyst

Component to control odor in accordance with the present invention may contain an effective amount of acid catalyst to neutralize unpleasant sulfur smells. It was found that certain soft acids have an impact on the reactivity of aldehydes and thiols in liquid and vapor phase. It was found that the reaction between the thiol and aldehyde is a catalytic reaction that goes on the mechanism of the route of formation of hemiacetal and acetal. If this component to control odor contains an acid catalyst and in contact with an unpleasant� sulfur smell, the volatile aldehyde reacts with a thiol. This reaction can form tiletamine connection, thus neutralizing the sulfuric smell. Without acid catalyst, is formed only Hemi-tially acetal.

Acceptable acid catalysts have a VP, as reported Scifinder, in the range of from about 0,001 Torr to about 38 Torr, measured at 25°C, alternative from about 0,001 Torr yeah about 14 Torr, alternative from approximately 0.001 to approximately 1, alternative from about 0.001 to about 0.020 in., alternative from about 0.005 to about 0.020 in., alternative from approximately to approximately 0,010 0,020.

The acid catalyst may be a weak acid. A weak acid is characterized by an acid dissociation constant, Ka, which is the equilibrium constant for dissociation of a weak acid; pKa is equal to minus the decimal logarithm of Ka. The acid catalyst may have a pKa from about 4.0 to about 6,0, alternative from about 4.3 to 5.7, alternative from about 4.5 to about 5, an alternative from approximately 4.7 to 4.9. Acceptable acid catalyst includes acidic catalysate given in Table 4.

Table 4
SubstanceVP (Torr) @ 25°C
Formic acid36,5
Acetic acid13,9
Pivalic acid0,907
Phenol (alkaline in liquid phase and is slightly acidic in vapor phase)0,610
Tihonova acid0,152
Caprylic acid0,0222
5-methylthiofentanyl acidIs 0.019
Succinic acidX 0.0165
Benzoic acid0,014
Mestrenova acid0,00211

Depending on the desired usage of the component to control odor, it is possible to consider the nature of the flavor or the effect of the fragrance component control odor in the choice of acid catalyst. In some realizations of the component to control odor, it may be desirable to choose acid� catalyst, providing neutral or pleasant aroma. Such acid catalysts may have a VP from about 0,001 Torr to about 0.020 in Torr, measured at 25°C, alternative from approximately from 0.005 Torr to about 0.020 in Torr, alternative from about 0,010 Torr to about 0.020 in Thor. Non-limiting examples of such acid catalyst include 5-methylthiotetrazole mixed with carbonic acid, succinic acid or benzoic acid.

Component to control odor may contain from about 0.05% to about 5%, alternative from approximately 0.1% to approximately 1.0%, alternative from about 0.1% to about 0.5%, alternative from about 0.1% to about 0.4%, alternative from about 0.4% to about 1.5%, alternative about 0.4% of acid catalyst by weight of the component to control odor.

In acetic acid system, the component for controlling odor may contain about 0.4% of acetic acid (50:50 TQDPM and 0.4% acetic acid).

Table 5
Made sampleActual % acetic acid in DPM % recovery of butandiol 30 minutes
50:50 TQDPM 0% acetic acid0,0012,00
50:50 TQDPM of 0.05% acetic acid0,0414,65
50:50 TQDPM of 0.1% acetic acid0,1025,66
50:50 TQDPM of 0.2% acetic acid0,4234,68
50:50 TQDPM of 0.5% acetic acid1,0024,79
50:50 TQDPM of 1.0% acetic acid2,007,26

If an acid catalyst is present with a volatile aldehyde (or RA), the acid catalyst can improve the efficiency of volatile aldehyde against unpleasant odors in comparison with the efficiency of volatile aldehyde against unpleasant odors in itself. For example, 1% volatile aldehyde and 1.5% benzoic acid ensure the useful effect of removing unpleasant odors, equal to or greater than 5% volatile aldehyde itself.

Component to control bad breath can have a pH of about 3 to about 8, and�lternative from approximately 4 to approximately 7, alternative from approximately 4 to approximately 6.

3. Optional ingredients

Component to control odor can, optionally, include agents that mask the smell, agents that block the smell, and/or diluents. For example, a component to control bad breath can include a mixture of volatile aldehydes for neutralizing odor, Ivanovich fragrances and diluent. Alternative component to control odor may contain 100% of volatile aldehydes.

"Agents, masking the smell" refer to known compounds (for example, raw materials, fragrances) that disguise or hide an unpleasant-smelling compound. The masking scent may include a connection to Aprotinin or pleasant smell, which is metered in such a way that it limits the ability to feel unpleasant-smelling compound. The masking scent may include a variety of compounds that are coordinated with the predicted odor to change the General perception of aroma provided by the combination of aromatic compounds.

"Agents that block the smell" are known compounds, which blunts the sense of smell of a person.

Illustrative diluents include dipropyleneglycol methyl ester and 3-methoxy-3-methyl - 1-butanol, and mixtures thereof.

Component to to�of odor control may also, not necessarily, contain raw materials of perfumes, which provides the advantage of hedonistic (i.e., not neutralizes odors and provides a pleasant fragrance). Acceptable odorants described in US 6,248,135, which is included in this application by reference.

II. The method of cleaning a hard surface or object

The present invention additionally encompasses a method for cleaning a hard surface or object, alternative descaling specified solid surface or a specified object.

The method according to the present invention includes a stage on which: put the liquid acidic composition for cleaning hard surfaces, containing formic acid, citric acid and alkali substance and having a pH value above 2.0; and mixtures thereof, on said hard surface or the specified object; leaving said composition on said hard surface or a specified target; optional wipe a specified solid surface or object and/or provide mechanical stirring and then rinsed specified solid surface or the specified object.

By "hard surface" is understood in this application any kind of surfaces typically found in houses and around them, for example bathrooms, kitchens, basements and garages, e.g., floors, walls, tiles, OK�and, gutters, showers, plastic shower curtains, wash basins, toilet cubicles, plates, valves and fittings, etc. made of various materials such as ceramics, enamel, painted and unpainted cement, plaster, bricks, vinyl, no wax vinyl, linoleum, melamine, Formica®, glass, any plastics, metals, chrome surfaces, etc. the Term surface as used in this application, also include household appliances including, but not limited to shows, washing machines, automatic dryers, refrigerators, freezers, cookers, microwave ovens, dishwashers and so on. Some solid surfaces that clean liquid aqueous acidic composition for cleaning hard surfaces in this application are those that are located in the bathroom, in the toilet or in the kitchen, basements, garages, and outdoors, such as garden furniture, garden equipment, driveways, etc.

The objects in this application are objects, susceptible to limescale on them. Such objects can be taps or parts, water valves, metal objects, objects made of stainless steel, Cutlery, etc.

One method of cleaning a hard surface or object (alternative descaling with �shown a solid surface or a specified object) includes the phase, on which is applied a composition in accordance with the present invention on said hard surface or object, leaving said composition on said hard surface or object for exposure, an alternative for an effective period of time, an alternative within a period of from 1 to 10 minutes, alternate during the period of 2 to 4 minutes; optionally wiping the specified solid surface or object with a corresponding tool, such as a sponge, and then preferably rinsed specified surface water.

Despite the fact that this hard surface or object can optionally be dried and/or mixed during the method in this application, it has surprisingly been found that the method in accordance with the present invention allows good features descaling without additional mechanical wiping and/or mixing. No need for wiping and/or mechanical agitation provides additional convenience for the user of the compositions in this application.

In another embodiment in accordance with the present invention provides the purification method of the object, alternative descaling object that includes a stage on which the specified object is immersed in a bath containing the composition in �accordance with the present invention, leave the specified object in said bath to the action of the composition, an alternative for an effective period of time, an alternative within a period of from 1 to 10 minutes, alternate during the period of 2 to 4 minutes, and then alternative rinsed specified object is water.

The compositions according to the present invention may be contacted with a surface or object to be processed in its pure form or in diluted form. Preferably, the composition is applied in its purest form.

By "diluted form" mean in this application that the specified composition is diluted by the user, typically water. The composition is diluted before use to a typical dilution level of 10 to 400 times the weight of water, preferably from 10 to 200 and more preferably from 10 to 100. Usually the recommended dilution level is 1.2% dilution of the composition with water.

The compositions according to the present invention are particularly acceptable for cutting hard surfaces, located in the house and around it, such as in bathrooms, toilets, garages, driveways, basements, gardens, kitchens, etc., and preferably in the bathrooms. However, it is known that such a surface (especially the surface in the bathroom) can be contaminated� so-called "pollution, containing scum". Under "pollution containing scum" in this application involve any contaminants that contain not only mineral deposits such as calcium carbonate and/or magnesium, but also soap scum (e.g., calcium stearate) and other fats (e.g., body fat). Under "scale deposits" mean in this application any contamination of pure scale, i.e. any dirt or spots, consisting mainly of mineral deposits, such as calcium carbonate and/or magnesium.

The compositions in this application can be packaged in any suitable container, such as bottles, alternative plastic bottles, equipped with optional electric or manual spray head.

EXAMPLES

The examples in this application are intended to illustrate the present invention, but not necessarily used to limit or otherwise define the scope of the present invention. All numerical values in the examples below are given in wt.%, of the total weight of the composition, unless otherwise indicated.

-
ExamplesIIIIIIIVVVIVII VIIIIX
Acid
Formic acid3,01,52,52,01,82,53,01,03,0
Citric acid1,56,04,54,07,02,01,04,02,0
Alkaline substance/td>
NaOH until pH2,12,42,23,83,0
CON to pH2,42,92,22,8
WaterTo 100%
ExamplesXXIXIIXIIIXIVXVXVIXVIIXVIII
Acid
Formic acid2,02,72,51,81,52,02,81,84,0
Acetic acid--0,75-0,5----
Citric acid3,54,64,08,01,53,02,0--
Lactic acid---1,02,01,0-1,5
Sulfuric acid-------3,03,0

XXI
Surface-active
substances
Neodol91-8®0,52,22,22,22,50,452,5--
Sulphated Safol 23®2,0
H-LAS-----0,80-0,901,30
NaCS-----1,80-2,202,50
Polymers
Kelzan T®0,400,250,250,250,300,100,400,450,60
PVP0,250,05-0,250,05-0,25--
SF 1288®-----0,60-0,901,80
Solvent
n-CDF1,0--1,5-----
Different
WNT0,030,030,030,030,05-0,03 0,150,15
Component to control odor0,050,500,200,500,300,500,250,400,35
Dye0,010,0050,0050,010,010,010,010,010,005
Alkaline
substance
�HE is to pH2,3---2,8----
NaOH until pH-2,22,33,6-2,52,3--
pH (wt./about. added alkaline substance)0,50,5
WaterTo 100%
ExamplesXIXXXXXIIXXIII
Acid
Ant2,52,82,71,02,0
acid
Citric acid3,61,02,03,01,0
Oxalic acid1,0-- --
Surfactants
Neodol91-8®2,50,52,21,52,0
Sulphated Safol 23®0,8
Sodium lauryl sulfate3,02,01,5
Kelzan T®0,280,100,350,250,40
PVP0,05-0,250,050,25
n-CDF-3,52,51,62,5
WNT 0,04----
Component to control odor0,250,600,400,200,35
Dye0,0050,0050,010,0050,01
CON to pH-3,6---
NaOH until pH2,3 -3,03,33,6
pH (wt./about. added alkaline substance)
WaterTo 100%

Formic acid, citric acid, lactic acid, acetic acid, oxalic acid and sulphuric acid commercially available from Aldrich.

Neodol 91-8® is a C9-C11EO8 nonionic surfactant, commercially available from SHELL.

Sulphated Safol 23® is a branched C12-13sulfate surfactant based on Safol 23®, alcohol commercially available from Sasol, which was sulfated.

Sodium lauryl sulfate is a linear C12-14sulfate, commercially available from Aldrich.

n-BPP is an n-butoxy propoxy propanol.

Kelzan T® is a xanthan gum that comes Kelco.

PVP is vinylpyrrolidone homopolymer, commercially available from ISP Corporation.

p> SF 1288® is a silicone-polyether copolymer, commercially available from Momentive Performance Materials.

BHT is a butylated hydroxytoluene.

Analytical test - Effect of volatile aldehydes on amine and sulfur odors

Standards of unpleasant odors receive a selection of pipettes 1 ml of butylamine (amine odor) and butanethiol (sulfur odor) in 1.2 liters of packet sampling gas. The package is then filled to volume with nitrogen and allow to precipitate for at least 12 hours to establish equilibrium.

1 μl sample of each volatile aldehyde listed in Table 6, and each of the notes (A, b and C), are presented in Tables 1-3, pipetted into separate milanesiana vials with an air layer in 10 ml vials sealed and allow you to be balanced for at least 12 hours. Repeat 4 times for each sample (2 to butylamino analysis and 2 for potentialnew analysis).

After the period of establishment of equilibrium 1.5 ml target standard odor injected into each vial of 10 ml. For Colnago analysis vials contain samples + standard odor and incubated at room temperature for 30 minutes. Then 1 ml syringe with an air layer is then used for injection of 250 µl of each sample/smell in GC/M� entrance with cleavage and no cleavage. For amine analysis 1 ml syringe with an air layer is used for the injection of 500 µl of each sample/odor immediately in GC/MS entrance with cleavage and no cleavage. GC layer used for amine analysis to reduce the time of transmission.

The sample is then analysed using GC/MS with a DB-5, 20 mm, column 1 μm film thickness with MPS-2 equipment with automatic sampler with a static function of the air layer. Data analyze ion extraction at each total ion current (56 for thiol and for 30 amine) and the area used to calculate the percent reduction standard odor for each sample.

Table 6 shows the influence of certain volatile aldehydes for neutralizing amine and sulfur odors in 40 seconds and 30 minutes, respectively.

tr>
Table 6
Raw odorants (R-CHO)At least 20% butylamine in 40 seconds?At least 20% recovery potential in 30 minutes?
2,4,5 trimethoxybenzaldehydeNoNo
2,4,6 trimethoxybenzaldehyde NoNo
2-ethoxybenzaldehydeYesYes
2-isopropyl-5-methyl-2-hexenalYesYes
2-methyl-3-(2-furyl)-propenalNoNo
3,4,5-trimethoxybenzaldehydeNoNo
3,4-trimethoxybenzaldehydeNoNo
4-tertbutylbenzeneYesNo
5-methylfentanylYesYes
5-methyl-thiophene-carboxaldehydeNoYes
DoxalYesNo
Imilarity aldehydeNoNo
BenzylalcoholYesNo
BurgenerNoYes
Cinnamic aldehydeYesYes
Citronellyl oxyacetyleneNoNo
CemalYesNo
DecimalDigitYesNo
Floral superYesYes
ForgitalYesYes
FloraisonNoNo
HelionalYesNo
HydroxycitronellalNoNo
Lauryl aldehydeYesNo
LigustriYesNo
Lire�l YesNo
MelonalYesNo
MetilnorarenalinNoNo
o-anisaldehydeYesYes
p-anisaldehydeYesNo
PinoytutorialYesYes
R. T. ButinalYesNo
ThiophenecarboxaldehydeYesNo
TRANS-4-decenalYesYes
TRANS TRANS 2,4-nonadienalYesNo
Undecylenic aldehydeYesNo

Table 7 shows the percentage recovery of butylamine and butanethiol in 40 seconds and 30 minutes, respectively, for notes A, b and C.

Table 7
Note% recovery of butylamine in 40 seconds% recovery of potential in 30 minutes
Note A76,5825,22
Note In51,5435,38
Note65,3424,98

An analytical test the Effect of acid catalysts on sulfur odors

The above analytical test is repeated using samples containing an acid catalyst to analyze their impact on sulfur odors. Specifically, 1 μl aliquot of each of the following controls and samples acid catalyst selected a pipette in a separate milanesiana vials with an air layer of 10 ml in the dual number: thiophenecarboxaldehyde as a control; 50/50 mixture of thiophenecarboxaldehyde and each of the following acid catalysts when 0,04%, 0,10%, and 0.43% in DPM, 1.02% in DPM and 2.04% in DPM: phenol, mesotheleoma acid, Caprylic acid, succinic acid, iwalewa acid, Tihonova acid and benzoic acid.

�IG.1 shows that acid catalysts with low vapor pressure to provide 3 times more reducing sulfur odors compared to control.

Analytical test - Effect of volatile aldehydes and acid catalyst to amine and sulfur odors

The above analytical test is repeated using the compositions of samples containing volatile aldehydes (or RA) and an acid catalyst, as shown in Tables 8 and 9.

Tables 8 and 9 show that the blend of fragrances that contains at least 1% volatile aldehyde together with 1.5% acid catalyst, functions better when restoring butylamine and butanethiol than the same mixture of fragrances containing 5% volatile aldehyde.

Table 8
Composition% recovery of butylamine in 40 seconds% recovery of potential in 30 minutes
The mixture of fragrances m/5% RA (control)34,21-2,40-
The mixture of fragrances m/1% RA and m/a 1.5% benzoic acid41,63+Of 7.42 11,95+Of 9.55
The mixture of fragrances m/3% of RA and m/a 1.5% benzoic acid36,19+1,9813.56 MHz+11,16
A mixture of odorants And m/5% RA and m/a 1.5% benzoic acid41,26+7,05To 9.56+5,02

Table 9
Composition% recovery of butylamine in 40 seconds% recovery of potential in 30 minutes
The mixture of fragrances m/5% RA (control)4,94-10,52-
The mixture of fragrances m/1% RA and m/a 1.5% benzoic acid11,61+6,6718,82+8,30
The mixture of fragrances m/3% of RA and m/a 1.5% benzoic acid26,89+21,9514,85+4,33
The mixture of fragrances m/5% RA and m/a 1.5% benzoic acid20,27+15,3316,84+6.32 per

The dimensions and values described in this application should not be construed as strictly limited to the exact shown by numerical values. Instead, unless otherwise indicated, each such amount is intended to indicate how the present value and a functionally equivalent range around this value. For example, the size is described as "40 mm" is intended to mean "about 40 mm".

Each document cited in this application, including any related patent or application, is cited as a cross-reference, fully incorporated into this application by reference, unless specifically excluded or otherwise limited. The citation of any document is not an admission that it constitutes prior art with respect to any inventions described or claimed in this application, or that it, taken separately or in any combination with any other reference or references, doctrines, suggests or describes any such invention. Additionally, to the extent that any meaning or definition of the term in Danno� the document contradicts any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document will govern.

While illustrated and described a specific implementation of the present invention, specialists in the art it will be obvious that various other changes and modifications will be made, without departing from the essence and scope of the present invention. It is therefore intended to cover in the attached claims all such changes and modifications that fall within the scope of the present invention.

1. Composition for cleaning hard surfaces, containing:
(a) an acid component;
(b) a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants; amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; and
(c) a polymer that modifies the surface;
(d) a component for controlling odor, containing an effective amount of two or more volatile aldehydes for neutralizing odor, but said two or more volatile aldehydes selected from the group consisting of 2-ethoxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylpyrrole, 5-methyl-year - �Hairdryer-carboxaldehyde, alaxala, p-anisic aldehyde, Benzylalcohol, burgens, cinnamic aldehyde, chimala, decyl aldehyde, florala super, floridale, gelinas, lauryl aldehyde, ligustrina, liras, melons, o-anisic aldehyde, pinealectomized, R. T. bocinas, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, odesilaneho aldehyde, and mixtures thereof; and
(e) aqueous carrier,
the technology component to control odor contains from 35% to 60% of volatile aldehydes that have a B. R. 250°C or more and ClogP of 3.0 or more, by weight of the specified component for the control of odors.

2. The composition according to claim 1, characterized in that said two or more volatile contain aldehyde, floral super and o-anisaldehyde.

3. Composition according to any one of claims.1-2, characterized in that said two or more volatile aldehyde contain 25% of aldehydes having an R. V. of about 250°C or less and ClogP of about 3 or less, by weight of the specified component for the control of odors.

4. Composition according to any one of claims.1-2, characterized in that said mixture of two or more volatile aldehydes containing 10% aldehydes that have a B. R. 250°C or less and ClogP of 3.0 or more, by weight of the specified component for the control of odors.

5. Composition according to any one of claims.1-2, characterized in that said mixture of two or more volatile al�of Egido contains from 10% to 30% of aldehydes, with V. R. 250°C or more and ClogP of 3.0 or less, by weight of the specified component for the control of odors.

6. Composition according to any one of claims.1-2, characterized in that said two or more volatile aldehydes have a VP from 0.001 to 0.100 Torr tor.

7. Composition according to any one of claims.1-2, characterized in that said two or more volatile aldehydes are present in an amount of from 0,015% to 1%, by weight of the specified composition for cleaning hard surfaces.

8. Composition according to any one of claims.1-2, characterized in that the specified component to control odor further comprises an acid catalyst having a vapor pressure of from 0.01 to 13 at 25°C.

9. The composition according to any one of the preceding claims, characterized in that the acid component is from 0.01% to 5%, by weight of the total composition, of formic acid.

10. Composition according to any one of claims.1-2, characterized in that the acid component is from 0.1 to 12%, by weight of the total composition, citric acid.

11. Composition according to any one of claims.1-2, characterized in that said composition further comprises an alkaline substance selected from the group consisting of: sodium hydroxide, potassium hydroxide, lithium hydroxide, alkaline metal, monoethanolamine, triethanolamine, ammonia, ammonium carbonate, choline bases and mixtures thereof.

12. Composition according to any one of claims.1-2, characterized in that�asandy composition additionally contains unrelated to the cyclodextrin complex.

13. Composition according to any one of claims.1-2, characterized in that said composition further comprises a water-soluble salt of a metal selected from the group consisting of zinc salts, copper salts, and mixtures thereof.

14. The method of cleaning a hard surface or object, comprising stages on which:
(a) applied composition for cleaning hard surfaces according to claim 1 on said hard surface or the specified object;
(b) leaving said composition on said hard surface or a specified target; optional wipe a specified solid surface or object; and
(c) rinse the specified solid surface or the specified object.

15. Composition for cleaning hard surfaces, containing:
(a) an acid component;
(b) a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants; amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; and
(c) a polymer that modifies the surface;
(d) a component for controlling odor, containing an effective amount of two or more volatile aldehydes for neutralizing odor, but said two or more volatile aldehydes selected from the group consisting of 2-�of oxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylpyrrole, 5-methyl-thiophene-carboxaldehyde, alaxala, p-anisic aldehyde, Benzylalcohol, burgens, cinnamic aldehyde, chimala, decyl aldehyde, florala super, floridale, gelinas, lauryl aldehyde, ligustrina, liras, melons, o-anisic aldehyde, pinealectomized, R. T. bocinas, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, odesilaneho aldehyde, and mixtures thereof; and
(e) aqueous carrier,
the technology component to control odor contains 25% of aldehydes having an R. V. of about 250°C or less and ClogP of about 3 or less, by weight of the specified component for the control of odors.

16. Composition for cleaning hard surfaces, containing:
(a) an acid component;
(b) a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants; amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; and
(c) a polymer that modifies the surface;
(d) a component for controlling odor, containing an effective amount of two or more volatile aldehydes for neutralizing odor, wherein the two or more fly�their aldehyde selected from the group consisting of 2-ethoxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylpyrrole, 5-methyl-thiophene-carboxaldehyde, alaxala, p-anisic aldehyde, Benzylalcohol, burgens, cinnamic aldehyde, chimala, decyl aldehyde, florala super, floridale, gelinas, lauryl aldehyde, ligustrina, liras, melons, o-anisic aldehyde, pinealectomized, R. T. bocinas, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, odesilaneho aldehyde, and mixtures thereof; and
(e) aqueous carrier,
the technology component to control odor contains 10% of aldehydes with V. R. 250°C or less and ClogP of 3.0 or more, by weight of the specified component for the control of odors.

17. Composition for cleaning hard surfaces, containing:
(a) an acid component;
(b) a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants; amphoteric surfactants, zwitterionic surfactants, and mixtures thereof; and
(c) a polymer that modifies the surface;
(d) a component for controlling odor, containing an effective amount of two or more volatile aldehydes for neutralizing odor, wherein the two or bol�e volatile aldehyde is selected from the group consisting of 2-ethoxybenzaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylpyrrole, 5-methyl-thiophene-carboxaldehyde, alaxala, p-anisic aldehyde, Benzylalcohol, burgens, cinnamic aldehyde, chimala, decyl aldehyde, florala super, floridale, gelinas, lauryl aldehyde, ligustrina, liras, melons, o-anisic aldehyde, pinealectomized, R. T. bocinas, thiophenecarboxaldehyde, TRANS-4-decenal, TRANS TRANS 2,4-nonadienal, odesilaneho aldehyde, and mixtures thereof; and
(e) aqueous carrier,
the technology component to control odor contains from 10% to 30% of aldehydes with V. R. 250°C or more and ClogP of 3.0 or less, by weight of the specified component for the control of odors.



 

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15 cl, 2 tbl, 19 ex

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