Stable sustainable hand dish-washing detergents

FIELD: chemistry.

SUBSTANCE: invention relates to stable liquid hand dish-washing detergent compositions. Described is a liquid detergent composition which contains: a) about 2% to about 70 wt % of a composition of an ethoxylated anionic surfactant obtained from a fatty alcohol, wherein: (i) at least about 80 wt % of said fatty alcohol is linear, and (ii) said fatty alcohol has an average degree of ethoxylation of about 0.8 to about 4; and b) about 0.1 to about 5 wt % of the composition of an alkoxylated branched nonionic surfactant, having an average degree of alkoxylation of about 1 to about 40; wherein the total amount of surfactant ranges from about 10 to about 85 wt % of the liquid detergent composition.

EFFECT: stability at low temperatures, good cleaning and sustainable foam.

20 cl, 2 tbl, 11 ex

 

The technical field to which the invention relates

The present invention relates to stable liquid detergent compositions for washing dishes containing anionic surfactants with slight branching of the branched nonionic surfactants that are effective in cleaning grease, forming a solid foam.

The level of technology

Consumers wish to have products for washing dishes by hand, that provide long lasting clean from grease and sustainable for a long time foam. Additionally, more and more consumers are looking for products that contain most of the ingredients derived from natural, renewable sources. They include liquid compositions of detergents for washing dishes by hand, containing higher levels of surfactants derived from renewable sources, and having a smaller number of surface-active substances obtained from crude oil. However, as natural surfactants have little branching or not branching, such compositions produce lower levels of foam. Worse, such detergent compositions are low foaming. That is, the strength of the foam is less than that �otori would like to have the majority of consumers.

Additionally, high levels of linear anionic surfactants, for example, obtained from renewable natural sources, and linear synthetic surface-active substances, lead to worse stability of the resulting composition at a low temperature.

Therefore, there remains a need for liquid detergent composition for washing dishes by hand, providing a good cleaning and sustainable for a long time, the foam having superior stability at low temperatures, which uses an anionic surfactant with little branching or non-branching.

It has been surprisingly found that small amounts of branched alkoxyimino nonionic surfactants in combination with ethoxylated anionic surfactants having a small branching or non-branching, provide excellent cleaning of grease, and sustainable for a long time foam. Even more unexpectedly, by using branched alkoxyimino nonionic surfactants in combination with anionic surface-active substance with a minimum degree of amoxilonline and insignificant isn�to the implementation or non-branching, can be structured liquid detergent composition for washing dishes by hand, having superior stability at low temperatures.

WO 9533025, US 5968888, US 2007/0123447 A1, US 2005/0170990 A1, WO 2006/041740 A1 and US 6,008,181 describe liquid compositions of detergents for washing dishes by hand, containing branched surfactants.

Summary of the invention

In accordance with the present invention provided a liquid detergent composition for washing dishes by hand, containing from 2% to 70% by weight ethoxylated anionic surfactants derived from fatty alcohol, wherein: at least 80% by weight of the specified fatty alcohol is linear and specified fatty alcohol has an average degree of amoxilonline from 0.8 to 4; and from 0.1 to 5% by weight alkoxysilane branched nonionic surfactant, having an average degree of alkoxysilane from 1 to 40; moreover, the total amount of surfactant is from 10 to 85% by weight of the liquid detergent composition. The present invention additionally encompasses a method of washing dishes by hand, using the said composition, wherein the method comprises a stage on which is injected into contact a specified composition in undiluted form with the dishes.

On�detailed description of the invention

As used in this application "liquid detergent composition for washing dishes by hand" refers to those compositions that are used in manually (i.e. by hand) cleaning of utensils. Such compositions in General have a high foaming or foam by nature. As used in this application, "cleaning" means the application of a liquid detergent composition for washing dishes by hand on the surface to remove unwanted residue, such as dirt, grease, stains and/or for disinfection.

As used in this application "tableware" means a surface such as dishes, glasses, pots, pans, kitchenware, bakeware and Cutlery, made of ceramic, porcelain, metal, glass, plastic (polyethylene, polypropylene, polystyrene, etc.) and wood.

As used in this application "grease" means materials containing at least partially (e.g., at least 0.5 wt.% by weight of the grease) saturated and unsaturated fats and oils, preferably oils and fats derived from animal sources such as beef and/or chicken.

As used in this application "profile foam" means a foam (high or low) and duration of flushing (how sustainable or long-term is foam) during the proce�sa wash, resulting from the use of liquid detergent compositions. As used in this application, "high foaming" or "stable for a long time foam" refers to liquid detergent compositions for washing dishes by hand, which generates high levels of foam (i.e., the level of foaming is considered acceptable to the consumer) and where the level of stable foam during the operation of washing dishes. This is particularly important in relation to liquid detergent compositions for washing dishes, because the consumer perceives high foaming in the performance of the detergent composition. Additionally, the user also uses the profile of foaming, as an indication that the cleaning solution still contains active ingredients of detergents. The consumer typically causes additional liquid detergent composition for washing dishes by hand, when the foam subsides. Thus, the detergent composition for washing dishes low foaming will tend to be used by the user more than necessary.

The term "in its neat form", in this application mean that the specified composition is applied directly onto the surface, or a device or deterge�in cleaning, such as a towel, sponge or brush for dishes, without any significant dilution by the user (immediately) before applying. "In its undiluted form, also includes a small breeding, for example, arising from the presence of water in the cleaning device, or the addition of water to the consumer to remove the remaining amount of the composition from the bottle. Therefore, the composition in its neat form includes a mixture comprising the composition and water in ratios ranging from 50:50 to 100:0, preferably from 70:30 to 100:0, more preferably from 80:20 to 100:0, even more preferably from 90:10 to 100:0 depending on user habits and clean-up tasks. For the avoidance of doubt, a ratio of 100:0 is the most preferred.

The term "diluted form", in this application mean that the specified composition is diluted by the user, typically water. The term "rinsing", in this application involve contacting the tableware, which is purified composition with a substantial amount of water after the step of applying a liquid composition on a specified dishes.

The term "substantial amounts" mean usually from 1 to 20 liters.

All percentages, ratios and proportions used in this application, is given as a mass percentage of liquid detergent compositions �the means for washing dishes by hand. All average values are calculated "by weight" liquid detergent composition for washing dishes by hand, unless specifically stated otherwise.

Liquid detergent composition for washing dishes by hand method

Liquid detergent compositions for washing dishes by hand in accordance with the present invention are designed to provide cleaning grease, sustained over a long period of time foam and optional useful effects that are often desired by the consumer. Optional benefits include the removal of dirt, glitter and hand care.

Compositions in accordance with the present invention contain at least one ethoxylated anionic surfactant with little branching or non-branching, and at least one branched non-ionic, alkoxysilane surfactant.

The compositions in this application may additionally contain from 30% to 80% by weight of the aqueous liquid medium containing water, in which the other essential and optional ingredients are dissolved, dispersed or suspended. More preferably, the compositions according to the present invention contain from 45% to 70%, more preferably from 45% to 65% aqueous liquid carrier. Acceptable neoblast�further additional ingredients include a surfactant, selected from other anionic surfactants, other nonionic surfactants, amphoteric/zwitterionic surfactants, cationic surfactants and mixtures thereof; cleaning polymers; cationic polymers; enzymes; humidifiers; salts; solvents; hidroterapia substances; polymer foam stabilizers; diamines; carboxylic acid; pearlescent agent; chelators; pH buffering agents; perfume, dyes, cloud emulsions, and mixtures thereof.

Aqueous liquid carrier, however, may contain other materials which are liquid, or which dissolve in the liquid carrier, at room temperature (20°C-25°C) and which can also perform some other functions, except the function of an inert filler.

The liquid detergent composition can have any acceptable pH. Preferably the pH of the composition adjust from 4 to 14. More preferably the composition has a pH from 6 to 13, most preferably 6 to 10. the pH of the composition may be adjusted using pH modifying ingredients known in the art.

Liquid detergent composition in accordance with the present invention is preferably transparent or translucent. That is, the liquid detergent composition has a turbidity of 5 NTU to less than 3000 NTU, preferably� less than 1000 NTU, more preferably less than 500 NTU and most preferably less than 100 NTU.

Ethoxylated anionic surfactant

Liquid detergent composition for washing dishes by hand in accordance with the present invention comprises from 2% to 70%, preferably from 5% to 30%, more preferably from 10% to 25% by weight anionic surfactant having an average degree of amoxilonline from 0.8 to 4, preferably from 1 to 2. The average degree of amoxilonline is defined as the average number of moles of ethylene oxide per mole of ethoxylated anionic surfactants in accordance with the present invention. Ethoxylated anionic surfactant derived from fatty alcohol, where at least 80%, preferably at least 82%, more preferably at least 85%, most preferably at least 90% by weight of the specified fatty alcohol are linear. The term "linear" means that the fatty alcohol contains one skeleton carbon atoms with no branching. Preferably, the specified ethoxylated anionic surfactant is ethoxylated alkylsulfate surface-active substance of the formula:

R1-(OCH2CH2)n-O-SO3 M+where:

R1represents a saturated or unsaturated C8-C16preferably C12-C14alkyl chain; preferably, R1represents a saturated C8-C16more preferably a saturated C12-C14alkyl chain;

n is a number from 0.8 to 4, preferably from 1 to 2;

M+is a acceptable cation which provides charge neutrality, preferably sodium, calcium, potassium or magnesium, more preferably a sodium cation.

Acceptable ethoxylated alkylsulfate surfactants include saturated C8-C16alkylalkoxysilane, preferably a saturated C12-C14alkylalkoxysilane.

The ratio R1which is linear, is such that at least 80% by weight of the original fatty alcohol are linear. Saturated alkyl chain is preferred, as the presence of double bonds may lead to chemical reactions with other ingredients, such as some of the ingredients of fragrances, or even with UV radiation. Such reactions can lead to instability of the phases, change in color and odor.

The required distribution of carbon chain length can be obtained by using alcohols with the corresponding distribution �Lina chain obtained synthetically or from natural raw materials or the respective pure compounds. Preferably, the anionic surfactant according to the present invention is obtained from the alcohol of natural origin. Natural sources such as plant or animal esters (waxes), can be obtained by obtaining linear alcohols with terminal primary hydroxyl group, along with varying degrees of unsaturation. Such fatty alcohols containing alkyl chain in the range of C8to C16can be obtained by any known commercial process, such as obtaining fatty alcohols from fatty acids or methyl esters, and sometimes triglycerides. For example, the addition of hydrogen in the carboxyl group of the fatty acid to obtain fatty alcohol, when treated with hydrogen at high pressure and in the presence of acceptable metal catalysts. For similar reactions, fatty alcohols can be obtained by hydrogenation of glycerides or methyl esters. The recovery of methyl esters is an acceptable means of providing saturated fatty alcohols, and selective hydrogenation with the use of special catalysts such as the oxides of copper or cadmium, may be used to produce OLE�lovoy alcohol. Synthetic processes or processes petroleum-based, such as the Ziegler process, are useful for obtaining an acceptable unbranched, containing even number of atoms, saturated alcohols. Oxidation of paraffins is an acceptable method to obtain the mixed primary alcohols. Fatty alcohol can react with the ethylene oxide with obtaining ethoxylated fatty alcohols. Ethoxylated alkylsulfate surface-active substance(substances) of the formula R1-(OCH2CH2)n-O-SO3-M+can then be obtained by sulfonation of the corresponding ethoxylated fatty alcohol(alcohols).

Ethoxylated alkylsulfate surface-active substance(substances) of the formula R1-(OCH2CH2)n-O-SO3-M+can be obtained from coconut oil. Coconut oil typically contains triglycerides that can be chemically processed to produce a mixture of C12-C18alcohols. A mixture of alkyl sulfates containing a high proportion of C12-C14alkylsulfates may be obtained by separation of the corresponding alcohols in front of the stage amoxilonline or sulfation, or obtained by separating the ethoxylated alcohol or ethoxylated alkylsulfate surfactant(�of exist).

Preferred ethoxylated anionic surfactants in this application are ethoxylated alkylsulfate containing from 8 to 18, preferably from 10 to 16, more preferably 12 to 14 carbon atoms in the alkyl chain, and are at 80% to 100% linear. Such surfactants may be obtained by any known means, using acceptable material. For example, from linear fatty alcohols that preferably have a natural origin, such as n-dodecanol, n-tetradecanol and mixtures thereof. If desired, such surfactants may include linear alkyl fragments derived from synthetic sources, or may contain a mixture of ethoxylated linear of alkylsulfates with slightly branched, e.g. methyl branched counterparts. Ethoxylated alkylsulfate can be in the form of their salts of sodium, potassium, ammonium or alkanolamine salts. Acceptable alcohol precursors for ethoxylated anionic surfactants include obtained by the Ziegler process linear alcohols, the alcohols obtained by the hydrogenation of Oleochemicals, and 80% or more of linear alcohols obtained by the enrichment of the linear component oxo derived alcohols, such as Neodol® or Dobanol® from Shell. Other examples of acceptable�x primary alcohols include those obtained from: the natural linear fatty alcohols, such as commercially available from Procter & Gamble Co.; and by the oxidation of paraffins stages (a) oxidation of paraffin with the formation of fatty carboxylic acids, and (b) recovering the carboxylic acid to the corresponding primary alcohol. Other preferred ethoxylated anionic surfactants are substances from Sasol, which are sold under the trademarks: Alfol®, Nacol®, Nalfol®, Alchem®. Alkoxysilane branched non-ionic surfactant Liquid compositions of detergents for washing dishes by hand in accordance with the present invention contain from 0.1% to 5%, preferably from 0.2% to 3%, more preferably from 0.5% to 2% by weight alkoxysilane branched nonionic surfactant. Specified alkoxysilane branched non-ionic surfactant has an average degree of alkoxysilane from 1 to 40, preferably from 3 to 20, more preferably from 7 to 12. The average degree of alkoxysilane is defined as the average number of moles of alkylated per mole alkoxysilanes branched non-ionic surfactant in accordance with the present invention. Preferably the branched non-ionic substance is an ethoxylated and/or propoxide�baths more preferably ethoxylated.

Not ethoxylated branched non-ionic surfactant in combination with ethoxylated anionic surface-active substance in these compositions, it has been found that limiting characteristic of the foaming liquid detergent composition. Therefore, the composition preferably contains less than 10%, more preferably less than 5%, most preferably less than 2 mass% is not alkoxysilanes branched alcohol. To surfactant was acceptable surfactant, branched nonionic surfactant preferably contains from 8 to 24, more preferably from 9 to 18, most preferably 10 to 14 carbon atoms. Alkoxysilane branched nonionic alcohols selected from: formula I, formula II, and mixtures thereof, are particularly preferred:

Formula I:

,

where, in the formula I:

R1 is a C5-C16 linear or branched, preferably linear, alkyl chain;

R2 represents a C1-C8 linear or branched, preferably linear, alkyl chain;

R3 represents H or C1-C4 alkyl, preferably H or methyl;

b denotes a number from 1 to 40, preferably from 5 to 20, more preferably from 7 to 1;

Formula II:

,

where, in the formula II:

R1 represents a C6-C16 linear or branched, preferably linear, alkyl chain;

R2 represents a C1-C8 linear or branched, preferably linear, alkyl chain;

R3 represents H or C1-C4 alkyl, preferably H or methyl;

b denotes a number from 1 to 40, preferably from 5 to 20, more preferably from 7 to 12.

The degree of alkoxysilane specified branched nonionic substance is preferably greater than the degree of amoxilonline specified ethoxylated anionic surfactant. With increase in the degree of amoxilonline anionic surfactant increases the viscosity of the liquid detergent composition for washing dishes by hand. Believe that this is because the hydrophilicity of the overall system of the surfactant increases. Additionally, liquid compositions of detergents for washing dishes by hand in General is obtained using premix of surfactants. With increase in the degree of amoxilonline anionic surfactants, the probability of such gelation of the premix of surfactants during processing increases. However, it has been discovered that by incorporating a small amount of�the number of branched non-ionic surfactant, having a higher degree of alkoxysilane than the degree of amoxilonline anionic surfactants, the viscosity of the premix surfactant and the resulting composition can be controlled.

Alkoxysilane branched nonionic surfactants can be classified as relatively water-insoluble or relatively water-soluble. While certain alkoxysilane branched nonionic surfactants can be considered insoluble in water, they can be formulated into liquid compositions of detergents for washing dishes by hand in accordance with the present invention with an appropriate additional surfactants, in particular anionic or nonionic surfactants.

Preferred branched nonionic surfactants in accordance with formula I are the Guerbet C10 alcohol ethoxylate with 7 or 8 EO, such as Ethylan® 1007 &1008, and Guerbet C10 alcohol alkoxysilane nonionic surfactants (which are ethoxylated and/or propoxycarbonyl), for example, commercially available from series Lutensol® XL (X150, XL70, etc.). Other illustrative alkoxysilane branched nonionic surfactant and�tive substances include available under the trademarks: Lutensol® XP30, Lutensol® XP-50 and Lutensol® XP-80, available from BASF Corporation. In General, Lutensol® XP-30 can be considered as having 3 duplicate ethoxypropan, Lutensol® XP-50 can be considered as having 5 repeating ethoxy and Lutensol® XP-80 can be considered as having 8 of ethoxy repeating. Other suitable branched nonionic surfactants include oxo branched nonionic surfactants, such as Lutensol® ON 50 (5 EO) and Lutensol® ON70 (7 EO). Also acceptable are: ethoxylated fatty alcohols obtained by the reaction of the Fischer-Tropsch and containing up to 50% branching (40% methyl (mono or bi), 10% cyclohexyl) such as derived from alcohols Safol® from Sasol; ethoxylated fatty alcohols obtained by the oxo reaction, where at least 50% by weight of the alcohol is a C2isomer (bromide or Pentium), such as obtained from Isalchem® alcohols or Lial® alcohols from Sasol.

Preferred branched nonionic ethoxylate in accordance with formula II are available under the trademarks Tergitol® 15-S, with the degree of alkoxysilane from 3 to 40. For example, Tergitol® 15-S-20, which has an average degree of alkoxysilane 20. Other suitable commercially available compounds in accordance with formula II are available under the trademark Softanol® M and EP series.

Additional over�OSTO-active substances

The composition according to the present invention may contain an additional surfactant selected from other anionic and other nonionic, amphoteric/zwitterionic, cationic surfactants and mixtures thereof. Liquid composition for washing dishes by hand in accordance with the present invention contain a total amount of surfactant: 10% to 85% by weight, preferably from 12.5% to 65% by mass, more preferably from 15% to 40% by weight of the composition. The total amount of surfactants is the sum of all the present of surfactants, including ethoxylated anionic surfactant, alkoxysilane branched nonionic surfactant and any other anionic, other nonionic, amphoteric/zwitterionic and cationic surfactants that may be present.

1) Other anionic surfactants:

The composition according to the present invention will typically contain from 2% to 70%, preferably from 5% to 30%, more preferably from 7.5% to 25% and most preferably from 10% to 20% by weight anionic surfactant.

Acceptable anionic surfactants, which are used to form composite�ies and methods in accordance with the present invention, are sulfates, sulfosuccinates, sulfonates and/or sulfoacetate, preferably alkylsulfate.

Acceptable sulphate or sulphonate surfactants for use in compositions in this application include water soluble salts or acids of the C10-14alkyl or hydroxyalkyl, sulphate or sulphonates. Acceptable counterions include hydrogen, alkali metal cation or ammonium or substituted ammonium, but preferably sodium. If the hydrocarbon chain is branched, it preferably contains C1-4alkyl-chain branching.

Sulphate or sulphonate surfactants may be selected from C11-C18alkyl benzene sulphonates (LAS), C8-C20primary, branched or random alkyl sulfates (AS); C10-C18secondary (2,3) alkyl sulfates; branched in the middle of the chain alkyl sulfates as discussed in US 6,020,303 and US 6,060,443; modified alkylbenzene sulphonate (MLAS) as discussed in WO 99/05243, WO 99/05242, WO 99/05244, WO 99/05082, WO 99/05084, WO 99/05241, WO 99/07656, WO 00/23549 and WO 00/23548; methyl sulfonate esters (MES); and alpha-olefin sulfonate (AOS).

The paraffin sulfonates may be monosulfonated or disulfonate and usually are mixtures thereof, obtained by sulfonation of paraffins with 10 to 20 carbon atoms. Preferred �sulfonate are containing C12-18 carbon atoms in the chain and more preferably a C14-17 chains. Paraffin sulfonates that have the sulfonate group(s) distributed along the paraffin chain are described in US 2,503,280; US 2,507,088; US 3,260,744; US 3,372 188 and DE 735 096.

Also acceptable are alkylglycerol sulfonate surfactant and/or alkyl glycerol sulfate surfactants, which are described in the patent application WO 06/014740 Procter & Gamble: a Mixture of oligomeric alkyl glycerol sulfonate and/or sulfate surfactant selected from dimers, trimers, tetramer, pentamer, hexamers, heptamers and their mixtures, where the mass percentage of monomers is from 0 wt% to 60 wt% by weight of a mixture of alkyl glycerol sulfonate and/or sulfate surfactants.

Other suitable anionic surfactants are alkyl, preferably dialkyl the sulfosuccinates and/or sulfoacetate. Dialkyl the sulfosuccinates may be C6-15linear or branched dialkyl the sulfosuccinates. Alkyl fragments can be symmetrical (i.e., the same alkyl moieties) or asymmetrical (i.e., different alkyl moieties). Preferably, the alkyl fragment is symmetrical.

2) Other non-ionic surfactants

Liquid detergent compositions for washing dishes by hand method can neoblast�flax contain additional non-ionic surfactant. The composition preferably contains from 2% to 40%, more preferably from 3% to 30% by weight nonionic surfactant.

Acceptable additional nonionic surfactants include the condensation products of aliphatic alcohols containing from 1 to 25 mol of ethylene oxide. The alkyl chain of the aliphatic alcohol in General contains from 8 to 22 carbon atoms. Particularly preferred are the condensation products of alcohols having an alkyl group containing from 8 to 18 carbon atoms, more preferably from 9 to 15 carbon atoms, with from 2 to 18 mol, more preferably from 2 to 15 mol, most preferably from 5 to 12 mol of ethylene oxide per mole of alcohol.

Also acceptable are alkylpolyglycoside having the formula, R2O(CnH2nO)t(glycoside)x(formula (I)), where R2in the formula (I) selected from the group consisting of alkyl, alkyl-phenyl, hydroxyalkyl, hydroxyalkyloxy and mixtures thereof in which alkyl groups contain from 10 to 18, preferably from 12 to 14 carbon atoms; n in formula (I) is 2 or 3, preferably 2; t in the formula (I) is from 0 to 10, preferably 0; and x in the formula (I) is from 1.3 to 10, preferably from 1.3 to 3, most preferably from 1.3 to 2.7. The glycoside is preferably derived from glucose. Also acceptable are alkyl of glitz�Rin esters and sorbitane esters.

Also acceptable are surface-active substances on the basis of amides of fatty acids having formula (II):

where R6in the formula (II) represents an alkyl group containing from 7 to 21, preferably from 9 to 17, carbon atoms and each R7in the formula (II) selected from the group consisting of hydrogen, C1-C4alkyl, C1-C4hydroxyalkyl and -(C2H4O)xH, where x in the formula (II) ranges from 1 to 3. Preferred amides are C8-C20the amide ammonium, monoethanolamine, diethanolamine and isopropanolamide.

Preferred nonionic surfactants for use in the present invention are the condensation products of aliphatic alcohols with ethylene oxide, for example a mixture nonjabulo (C9), decyl (C10) and odesilaneho (C11) alcohols modified with on average 5 ethylene oxide units (EO), for example, commercially available Neodol 91-5 or Neodol 91-8, we have modified an average of 8 EO units. Also acceptable are ethoxylated nonionic surfactants with longer alkyl chain, for example, C12, C13, modified 5 EO (Neodol 23-5). Neodol is a trademark of Shell. Also acceptable is a C12, C14 alkyl chain with 7 EO, commercially available under the trademark Novel 1412-7 (Sasol) or Lutenso A 7 N (BASF).

3) Amphoteric/zwitterionic surfactants

It has been found that amphoteric/zwitterionic surfactants additionally raise the profile of foaming, while providing superior cleaning and softness to hands. Amphoteric and zwitterionic surfactant may be contained at a level of from 0.01% to 20%, preferably from 0.2% to 15%, more preferably from 0.5% to 10% by weight of the liquid detergent compositions for washing dishes by hand. Preferred amphoteric and zwitterionic surfactants are aminoxide surfactants, betamovie surfactants and mixtures thereof.

Most preferred are aminoxide, especially kokodigital aminoxide or cocamidopropylbetaine. Aminoxide may be linear or branched in the middle of the chain of the alkyl fragment.Typical linear amine oxides include water-soluble aminoxide formula, R1-N(R2)(R3)→O, where R1is C8-18alkyl fragment; R2and R3independently selected from the group consisting of C1-3alkyl groups and C1-3hydroxyalkyl groups and preferably include methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl and 3-hydroxypropyl. LINEST�e aminoxide surfactants, in particular, can include linear C10-C18alkyl dimethyl aminoxide and linear C8-C12alkoxy ethyl dihydroxy ethyl aminoxide. Preferred aminoxide include linear C10linear C10-C12and linear C12-C14alkyl dimethyl aminoxide. As used in this application "branched in the middle of the chain" means that aminoxide has one alkyl fragment with n1carbon atoms with one alkyl branch on the alkyl fragment with n2carbon atoms. Alkyl branching is located on the α carbon from the nitrogen in the alkyl fragment. This type of branching for aminoxide also known in the art as internal aminoxide. The total n1and n2ranges from 10 to 24 carbon atoms, preferably from 12 to 20 and more preferably from 10 to 16. The number of carbon atoms for the one alkyl fragment (n1) should be approximately equal to the number of carbon atoms in the alkyl chain branching (n2), so one alkyl fragment and one alkyl branching are symmetrical. As used in this application "symmetric" means that |n1-n2| is smaller or equal to 5, preferably less than 4 carbon atoms in at least 50 wt.%, more preferred�Thelen, at least 75 wt.% to 100 wt.% branched in the middle of the chain aminoxide for use in this application.

Aminoxide additionally contains two fragments, independently selected from C1-3alkyl, C1-3hydroxyalkyloxy group, or polyethylenoxide group containing on average from 1 to 3 ethylene oxide groups. Preferably two fragments selected from C1-3the alkyl and more preferably both are selected as C1alkyl.

Other suitable surfactants include betaine, for example: an alkyl betaine, alkylamidoamines, imidazoline betaine, sulfobetaine (INCI Sultani) and phosphatidy, which preferably correspond to formula (III):

R1-[CO-X(CH2)n]x-N+(R2)(R3)-(CH2)m-[CH(OH)-CH2]y-Y-(III), where

R1represents a saturated or unsaturated C6-22alkyl chain, preferably C8-18alkyl chain, more preferably a saturated C10-16alkyl chain, most preferably a saturated C12-14alkyl chain;

X is selected from the group consisting of: NH, NR4, O, and S; where R4represents C1-4alkyl chain;

n means an integer from 1 to 10, preferably from 2 to 5, more preferably 3;

x is 0 or 1, preferably 1;

R2, R3not�avisio selected from C 1-4alkyl chains, preferably methyl chain; R2, R3there may also be replacement, for example hydroxyethylene or hydroxymethyl chain;

m means an integer from 1 to 4, preferably 1, 2 or 3;

y means 0 or 1; and

Y is selected from the group consisting of: COO, SO3, OPO(OR5)O and P(O)(OR5)O; where R5represents H or C1-4the alkyl chain.

Preferred betaine are the alkyl betaine of formula (IIIa), alkylamides of formula (IIIb), sulfobetaine of formula (IIIc) and the amido sulfobetaine of formula (IIId);

where R1has the same meaning as in formula III. Particularly preferred betaine are carbbean [where Y-=COO-], in particular carbonation of formula (IIIa) and (IIIb), more preferred are alkylamidoamines of formula (IIIb).

Examples of acceptable betinov and sulfobetaine are [notation given in accordance with INCI]: almond amidopropyl betaine, apricot amidopropyl betaine, avocado amidopropyl betaine, the babassu amidopropyl betaine, behenamidopropyl betaine, behenyl betaine, betaine, canalipalpata betaine, capryl/Carmichael betaine, carnitine, cetyl betaine, cocoamide betaine, cocoa�izopropil betaine, cocoamidopropyl hydroxysultaine, Coco betaine, Coco hydroxysultaine, Coco/oleamide betaine, Coco Sultan, a decyl betaine, dihydroxyethyl oleyl glycinate, dihydroxyethyl soy glycinate, dihydroxyethyl stearyl glycinate, dihydroxyethyl tallow glycinate, Dimethicone propyl PG-betaine, erucamide hydroxysultaine, hydrogenated tallow betaine, isostearamide betaine, lauramidopropyl betaine, lauryl betaine, lauryl hydroxysultaine, lauryl Sultan, milk amidopropyl betaine, minamidai betaine, myristamide betaine, myristyl betaine, oleamide betaine, oleamide hydroxysultaine, the oleyl betaine, oligomineral betaine, palmamide betaine, palmitoleate betaine, palmitoylcarnitine, palm kernel amidopropyl betaine, the polytetrafluoroethylene acetoxypropionyl betaine, ricinodendron betaine, sesame izopropil betaine, soy amidopropyl betaine, stearamidopropyl betaine, stearyl betaine, tallowamine betaine, allowedrolesandusers, the tallow betaine, the tallow dihydroxyethyl betaine, underenumerated betaine and wheat germ amidopropyl betaine.

A preferred betaine is, for example, cocamidopropylbetaine (cocamidopropylbetaine).

A preferred system of surface-active substances is a mixture and�ionic surfactants and amphoteric or zwitterionic surfactant in a ratio in the range from 1:1 to 5:1, preferably from 1:1 to 3.5:1.

4) Cationic surfactants

Cationic surfactants, when present in the compositions, present in an effective amount, more preferably from 0.1% to 20% by weight of the composition. Acceptable cationic surfactants are Quaternary ammonium surfactants, preferably selected from mono C6-C16, more preferably C6-C10N-alkyl or alkenyl ammonium surfactants, where the remaining N position is substituted with methyl, hydroxyethylene or hydroxypropylamino groups. Other preferred cationic surface-active substance is C6-C18alkyl or alkenyl ester Quaternary ammonium alcohol, such as Quaternary chlorine esters. More preferably, the cationic surfactants have the formula (V):

where R1in the formula (V) is a C8-C18substituted hydrocarbyl and mixtures thereof, preferably C8-14alkyl, more preferably C8, C10or C12alkyl, and X-in the formula (V) is an anion, preferably chlorine or bromine.

Cleaning polymers

Liquid composition for washing pic�dy manual method in this application may optionally further comprise one or more alkoxysilane polyethylenimine polymers. The composition may contain from 0.01% to 10%, preferably from 0.01% to 2%, more preferably from 0.1% to 1.5%, even more preferably from 0.2% to 1.5% by weight of the whole composition alkoxysilanes polyethylenimine polymer, as described on page 2, line 33 - page 5, line 5 and illustrated in examples 1-4 on pages 5-7 WO 2007/135645 The Procter & Gamble Company.

Preferred alkoxycarbonyl polyethylenimine polymer has polyethylenimine frame, having a weighted average molecular weight of from 400 to 10,000, preferably from 600 to 7000 mass, more preferably from 3000 to 6000.

Modification polyethylenimine frame includes: (1) one or two modifications of alkoxysilane on the nitrogen atom, depending on whether the modification on the internal nitrogen atom or a terminal nitrogen atom, in polyethylenimine frame, modification of alkoxysilane consists of the replacement of the hydrogen atom in polyacetylene chain containing on average from 1 to 40 alkoxy fragments in a modification, the end where the alkoxy fragment modification alkoxysilane will be terminated by hydrogen, C1-C4the alkyl or mixtures thereof; (2) substitution of one C1-C4alkyl fragment and one or two modifications of alkoxysilane on the nitrogen atom, depending on whether the substitution at the internal nitrogen atom or end �volume of nitrogen, in polyethylenimine frame, the modification of alkoxysilane consisting of substitution of the hydrogen atom in polyacetylene chain having an average of from 1 to 40 alkoxy fragments in a modification, the end where the alkoxy fragment ends hydrogen, C1-C4the alkyl or mixtures thereof; or (3) a combination of both. The composition may also contain amphiphilic graft polymers based on water-soluble polyalkyleneglycol (A) as the grafted base and side chains formed by polymerization of a vinyl ester component (B), these polymers have an average of≤1 vaccination sites 50 alkalinising units and mean molar mass Mw of from 3000 to 100000, as described in BASF patent application WO 2007/138053 on page 2, line 14 to page 10, line 34 and is illustrated on pages 15-18. Cationic polymers

In a preferred implementation, the liquid composition for washing dishes by hand in this application may contain at least one cationic polymer. Without wanting to be bound by theory, believe that the interaction of cationic polymer with anionic surface-active substance leads to the phenomenon of the separation of phases, known as coacervate where the polymer-enriched koatservatnyh phase is separated from the bulk phase composition. Koatservatsija increases the deposition of cationic polymer on the skin and contribute to efficiency�t deposition of other active agents, such as hydrophobic emollient materials who can get into such koatservatnyh phase and as such jointly deposited on the skin. This koatservatnyh phase can exist in a liquid detergent for washing dishes by hand, or alternatively may be formed after dilution or rinsing the cleaning composition.

The cationic polymer will typically be present at a level from 0.001% to 10%, preferably from 0.01% to 5%, more preferably from 0.05% to 1% by weight of the whole composition.

Acceptable cationic polymers for use in the present invention contain fragments containing a cationic nitrogen atom, for example, Quaternary ammonium or cationic protonated Minerageny. The average molecular weight of cationic polymer is from 5,000 to 10 million, preferably at least 100000, more preferably at least 200,000 but preferably not more than 3000000. The cationic polymer preferably has a cationic charge density of from 0.1 mEq/g to 5 mEq/g, more preferably at least about 0.2 mEq/g, more preferably at least about 0.3 mEq/g, at pH targeted use of the composition. The charge density is calculated by dividing the total number of charges in a recurring segment on the molecular weight povtoreaiusi�Osya link. Positive charges can be located on the frame of the polymers and/or side chains of polymers. In General, regulation of ratios of amine fragments or fragments of Quaternary ammonium in the polymer depending on the pH of the liquid composition for washing dishes in the case of amines, will affect the charge density. Any anionic counterions can be used in combination with a cationic deposition polymers as long as the polymer remains soluble in water and in the composition according to the present invention, and while the counterion is physically and chemically stable with essential components of the composition, or not too impair product performance, stability or aesthetic quality. Non-limiting examples of such counterions include halides (e.g., chlorine, fluorine, bromine, iodine), sulfate and methylsulfate.

Specific examples of water-soluble cationizing polymers include cationic polysaccharides, such as cationization cellulose derivatives, cationizing starch and cationization derivatives of guar gum powder. Also included synthetically derived copolymers, such as the homopolymers diallyl Quaternary ammonium salts, copolymers of diallyl Quaternary ammonium salts/acrylamide, derivatives quaternionic polyvinylpyrrolidone, condensates �polyglycol polyamine, copolymers of vinylimidazole chloride/vinyl pyrrole and the don, copolymers of dimethyldiallylammonium chloride, copolymers of vinylpyrrolidone/quaternionic dimethylaminoethyl methacrylate, copolymers of polyvinylpyrrolidone/acylaminoacyl, copolymers of polyvinylpyrrolidone/acylaminoacyl/vinylcaprolactam, copolymers of vinylpyrrolidone/methacrylamide trimethylammonium chloride, copolymers of alkylacrylate/acrylate/alkylaminomethylated/polyethylene glycol methacrylate, a copolymer of adipic acid/dimethylaminoisopropyl ethylendiamine ("Cartaretin" is a product of Sandoz/USA), and optional quaternion/protonated condensation polymers having at least one heterocyclic end group connected to the polymer skeleton via the link received from alkylamide, link contains optionally substituted ethylene group (as described in WO 2007098889, page 2-19).

Specific non-limiting commercial examples of water-soluble cationizing polymers described in General in this application above, include: "Merquat 550" (a copolymer of acrylamide and salts of diallyl dimethyl ammonium CTFA name: polyquaternium-7, product of ONDEO-NALCO), "Luviquat FC370" (a copolymer of 1-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazolium salt - CTFA name: polyquaternium-16, product of BASF), "Gafquat 755N" (a copolymer of 1-vinyl-2-Pirro�idea and dimethylaminoethyl methacrylate - CTFA name: polyquaternium-11, product ex. ISP), "polymer KG, "polymer JR series" and "polymer LR series" (salt of a reaction product between trimethyl ammonium substituted epoxide and hydroxyethyl cellulose - CTFA name: polyquaternium-10, product of Amerchol) and "Jaguar series" (guar hydroxypropyl of trimoni chloride, a product of Rhodia) or N-hance series" (guar hydroxypropyl of trimoni chloride, a product of Aqualon).

Preferred cationic polymers are cationic polysaccharides, more preferably cationic cellulose derivatives, for example, salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) polyquaternium-10, for example UCARE LR400, or UCARE JR-400 form. Dow Amerchol, even more preferred are cationic derivatives of the guar gums, such as guar of hydroxypropyltrimonium chloride, for example, Jaguar series form. Rhodia, and N-Hance polymer series available from Aqualon.

Enzymes

Enzymes can be included in compositions according to the present invention at a level from 0.00001% to 1% of enzyme protein by weight of the whole composition, preferably at a level from 0.0001% to 0.5% of enzyme protein by weight of the entire composition, more preferably at a level from 0.0001% to 0.1% of enzyme protein by weight of the whole composition.

In a preferred implementation of the composition according � the present invention may contain an enzyme, preferably, the protease and/or amylase.

Protease of microbial origin is preferred. Chemically or genetically modified mutants are included. The protease may be a serine protease, preferably an alkaline microbial protease or a trypsin-like protease.

A preferred protease for use in this application include polypeptides demonstrating at least 90%, preferably at least 95%, more preferably at least 98%, even more preferably at least 99% and especially 100% identity with the wild-type enzyme from Bacillus lentus or the wild-type enzyme from Bacillus amyloliquefaciens.

Preferred commercially available protease enzymes include those sold under the trade names Alcalase®, Savinase®, Primase®, Durazym®, Polarzyme®, Kannase®, Liquanase®, Ovozyme®, Neutrase®, Everlase® and Esperase® by Novozymes A/S (Denmark), those sold under the trademarks Maxatase®, Maxacal®, Maxapem®, Properase®, Purafect®, Purafect Prime®, Purafect Ox®, FN3®, FN4®, Excellase® and Purafect PU® from Genencor International, and those sold under the trade names Opticlean® and Optimase® by Solvay Enzymes. In one aspect, the preferred protease is subtilisin BPN' protease derived from Bacillus amyloliquefaciens, preferably containing Y217L mutation, which is sold under the brand name Purafect Prime® from Genencor International.

Acceptable�s alpha-amylase include amylase of bacterial or fungal origin. Chemically or genetically modified mutants (variants) are included. Preferred alkaline alpha-amylase derived from a strain of Bacillus, such as Bacillus Bacillus licheniformis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus subtilis, or other Bacillus sp. for example, Bacillus sp.NCIB 12289, NCIB 12512, NCIB 12513 and DSM 9375 (USP 7,153,818) DSM 12368, DSMZ no. 12649, KSM API378 (WO 97/00324), KSM K36 or KSM K38 (EP 1,022,334).

Preferred amylases include:

(a) the variants described in WO 94/02597, WO 94/18314, WO 96/23874 and WO 97/43424, especially the variants with substitutions in one or more of the following positions versus the enzyme listed in SEQ ID No. 2 in WO 96/23874: 15, 23, 105, 106, 124, 128, 133, 154, 156, 181, 188, 190, 197, 202, 208, 209, 243, 264, 304, 305, 391, 408 and 444.

(b) the variants described in USP 5,856,164 and WO 99/23211, WO 96/23873, WO 00/60060 and WO 06/002643, especially the variants with one or more substitutions in the following positions versus the AA560 enzyme listed as SEQ ID No. 12 in WO 06/002643: 26, 30, 33, 82, 37, 106, 118, 128, 133, 149, 150, 160, 178, 182, 186, 193, 203, 214, 231, 256, 257, 258, 269, 270, 272, 283, 295, 296, 298, 299, 303, 304, 305, 311, 314, 315, 318, 319, 339, 345, 361, 378, 383, 419, 421, 437, 441, 444, 445, 446, 447, 450, 461, 471, 482, 484, preferably also contain the deletions of D183* and G184*.

(c) variants exhibiting at least 90% identity with SEQ ID No. 4 in WO 06/002643, the wild-type enzyme from Bacillus SP722, especially variants with deletions in the 183 and 184 positions and variants described in WO 00/60060, which is incorporated into this application by reference.

(d) variants exhibiting, at least, 95% identity with the wild-type enzyme from Bacillus sp.707 (SEQ ID NO:7 in US 6,093,562), especially variants containing one or more of the following mutations M202, M208, S255, R172, and/or M261. Preferably the said amylase comprises one or more of M202L, M202V, M202S, M202T, M202I, M202Q, M202W, S255N and/or R172Q. Particularly preferred are variants containing M202L or M202T mutations.

Acceptable commercially available alpha-amylases include DURAMYL®, LIQUEZYME®, TERMAMYL®, TERMAMYL ULTRA®, NATALASE®, SUPRAMYL®, STAINZYME®, STAINZYME PLUS®, FUNGAMYL® and BAN® (Novozymes A/S, Bagsvaerd, Denmark), KEMZYM® AT 9000 Biozym Biotech Trading GmbH Wehlistrasse 27b A-1200 Wien Austria, RAPIDASE®, PURASTAR®, ENZYSIZE®, OPTISIZE HT PLUS® and PURASTAR OXAM® (Genencor International Inc., Palo Alto, California) and KAM® (Kao, 14-10 Nihonbashi Kayabacho, 1-chome, Chuo-ku Tokyo 103-8210, Japan). In one aspect, acceptable amylases include NATALASE®, STAINZYME® or STAINZYME PLUS®, and mixtures thereof.

Humidifiers

In a preferred implementation of the composition according to the present invention may contain one or more moisturizers. It was discovered that such a composition containing a humidifier, will provide additional useful effects of softness to skin.

If present, the humidifier will typically be present in the compositions in accordance with the present invention at a level of from 0.1% to 50%, preferably from 1% to 20%, more preferably from 1% to 10%, even more preferably from 1% to 6%, and most preferably from 2% to 5% by weight of the entire composition.�I.

Moisturizers that can be used in accordance with the present invention include those substances that have an affinity to water and help to improve the absorption of water by the substrate, preferably leather. Specific non-limiting examples of particularly acceptable humectants include glycerin, diglycerin alcohol, polyethylene glycol (PEG-4), propylene glycol, hexyleneglycol, butylene glycol, (di)-propylene glycol, glyceryltrinitrate, polyalkylene glycols, and mixtures thereof. Others may be a polyethylene glycol ether methylglucose, pyrrolidone carboxylic acid (PCA) and its salts, pilolevu acids and salts, such as pidolate sodium, polyols, such as sorbitol, xylitol and maltitol, or polymeric polyols such as Polydextrose or natural extracts like Quillaia, or lactic acid or urea. Also included are the alkyl polyglycoside, polyeten polysiloxane and mixtures thereof. Additional acceptable moisturizers are polymeric moisturizers of the family of water soluble and/or swellable polysaccharides, such as hyaluronic acid, chitosan and/or enriched fructose polysaccharide which is e.g. available as Fucogel®1000 (CAS-Nr 178463-23-5) from SOLABIA S. Electrolytes and chelators

It is preferable to limit the electrolytes or chelators to less than 5%, preferably to 0.015% to 3%, more preferred�Stateline from 0.025% to 2.0% by weight of the liquid detergent composition.

Electrolytes are water-soluble mono-or polyvalent is not surface active (i.e. non-surfactants) salts that can affect the phase behavior of aqueous surfactants. Such electrolytes include chloride, sulfate, nitrate, acetate and citrate salts of sodium, potassium and ammonium.

The chelators used for binding or complexometry with metal ions, including ions of transition metals, which can have a negative impact on the productivity and stability of surface-active substances, for example, leading to the formation of deposits or scales. By sequestration of ions, such as ions of calcium and magnesium, they also inhibit the growth of crystals which can lead to the staining of the bands during drying. However, the chelators are also able to affect the phase behavior of aqueous surfactants.

The chelators include aminocarboxylate, aminophosphonate, polyfunctional substituted aromatic chelating agents and mixtures thereof. Examples of chelators include: MEA citrate, citric acid, aminoalkylindole(alkylene phosphonates), ethane 1-hydroxy diphosphonates, alkali metal and nitrilotriethanol, phosphonates, diethylen triamine Penta (methylene fosfonovoi acid) (DTPMP), ethylenediaminetetra(methylene fosfonovoi acid (DDTMP), hexamethylenediamine Tetra(methylene fosfonovoi acid), hydroxy-ethylene 1,1 diphosphonic acid (HEDP), hydroxyethane dimethylene fosfonovoi acid, ethylene di-amine di-succinic acid (EDDS), Ethylenediamine vs acid (EDTA), hydroxyethylammonium triacetate (HEDTA), nitrilotriacetic (NTA), methylpyridazin (MGDA), iminodisuccinate (IDS), hydroxyethylmethacrylate (HIDS), hydroxyethylaminomethyl (HEIDA), glycine diacetate (GLDA), diethylen triamine pantusso acid (DTP), and mixtures thereof. Solvents

Acceptable solvents include C4-14esters and dietary, glycols, alkoxysilane glycols, C6-C16glycol ethers, alkoxysilane aromatic alcohols, aromatic alcohols, aliphatic branched alcohols, alkoxysilane aliphatic branched alcohols, alkoxysilane linear C1-C5alcohols, linear C1-C5alcohols, amines, C8-C14alkyl and cycloalkyl hydrocarbons and halogenated and mixtures thereof. If present, the liquid detergent composition will contain from 0.01% to 20%, preferably from 0.5% to 20%, more preferably from 1% to 10% by weight of the liquid detergent composition of a solvent. These solvents can be used in conjunction with an aqueous liquid carrier, e.g. water, or they can be used �ithout any the presence of aqueous liquid carrier.

Hidroterapia substances

Liquid detergent compositions according to the present invention can optionally contain hydrotropes substance in an effective amount, so that the liquid detergent compositions are appropriately compatible with water. Acceptable hidroterapia substances for use in this application include hidroterapia substances anionic type, in particular xylene sulfonate sodium, potassium and ammonium toluene sulfonate, sodium potassium and ammonium salts, cumene sulfonate sodium, potassium and ammonium, and mixtures thereof, and related compounds as described in U.S. patent 3,915,903. Liquid detergent compositions in accordance with the present invention typically contain from 0% to 15% by weight of the entire liquid detergent compositions hydrotropes substances, or mixtures thereof, preferably from 1% to 10%, most preferably from 3% to 10% by weight of the entire liquid composition for washing dishes by hand.

Polymeric foam stabilizers

Compositions in accordance with the present invention may optionally contain a polymeric foam stabilizer. Such polymeric foam stabilizers provide increased foam and durable foam liquid detergent compositions. Such polymeric foam stabilizers can be selected from homopolymers of (N,N-dialkylamino) alkalinising esters and (N,N-dialkylamino) alkyl acrylate esters. The weighted average molecular weight of the polymer amplifiers foaming, certain traditional gel permeation chromatography, ranges from 1000 to 2000000, preferably from 5000 to 1000000, more preferably from 10,000 to 750,000, more preferably from 20,000 to 500,000, even more preferably from about 35,000 to 200,000. Polymeric foam stabilizer can optionally be present as salts, inorganic or organic salts.

One preferred polymeric foam stabilizer is (N,N-dimethylamino)alkyl acrylate esters. Other preferred polymers that enhance foaming, are copolymers of hydroxypropylmethacrylate/dimethyl of aminoethylethanolamine (copolymer of HPA/DMAM).

If present in the compositions, the polymeric amplifier foaming/stabilizer may be present in an amount of from 0.01% to 15%, preferably from 0.05% to 10%, more preferably from 0.1% to 5%, by weight of the liquid detergent composition.

Another preferred class of polymeric enhancers foam are hydrophobically modified cellulose polymers, having a weighted average molecular weight (Mw) of less than 45000; preferably from 10,000 to 40,000; more preferably from 13,000 to 25,000. Hydrophobically modified cellulose polymers include water-soluble derivatives of allyl�EIT esters, such as non-ionic and cationic cellulose derivatives. Preferred cellulose derivatives include methylcellulose, hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, and mixtures thereof.

Diamines

Another optional ingredient of the compositions in accordance with the present invention is a diamine. Since the habits and practices of the users of liquid detergent compositions show considerable variation, the composition may contain from 0% to 15%, preferably from 0.1% to 15%, preferably from 0.2% to 10%, more preferably from 0.25% to 6%, more preferably from 0.5% to 1.5% by weight of the specified composition, at least one diamine.

Preferred organic diamines are those in which pK1 and pK2 are in the range of from 8.0 to 11.5, preferably in the range from 8.4 to 11, even more preferably from 8.6 to 10.75. Preferred materials include 1,3-bis(methylamine)-cyclohexane (pKa=10 to 10.5), 1,3 propanediamine (pK1=10,5; pK2=to 8.8), 1,6 hexane diamine (pK1=11; pK2=10), 1,3 pentane diamine (DYTEK EP®) (MT1=10,5; MT2=8,9), 2-methyl 1,5 pentane diamine (DYTEK A®) (pK1=11,2; pK2=10,0). Other preferred materials include primary/primary diamines with alkilirovanny spacers in the range of C4to C8. Carboxylic acid

Liquid detergent compositions according to the present invention may contain linear�Yu or cyclic carboxylic acid or its salt to improve the feel of the rinse composition. The presence of anionic surfactants, especially when present in higher amounts in the range of 15-35% by weight of the composition causes the composition is a sticky feeling to the hands of the user and the dishware. A feeling of stickiness is reduced when using carboxylic acids as defined in this application, i.e., the feeling of rinsing becomes the stickiness.

Carboxylic acids useful in this application include C1-6linear, or at least containing 3 carbon atoms of the cyclic acid. Linear or cyclic carbon-containing chain of the carboxylic acid or its salts can be substituted by a group of Deputy selected from the group consisting of hydroxyl, ester, ether, aliphatic groups containing from 1 to 6, more preferably from 1 to 4 carbon atoms, and mixtures thereof.

Preferred carboxylic acids are selected from the group consisting of salicylic acid, maleic acid, acetyl salicylic acid, 3 methyl salicylic acid, 4 hydroxy isophthalic acid, dihydroxyfumaric acid, 1,2,4 benzene tricarboxylic acid, pentanoic acids and their salts and mixtures thereof. If the carboxylic acid exists in the salt form, the cation of the salt is preferably chosen from alkali metal, alkaline earth metal�, monoethanolamine, diethanolamine or triethanolamine and mixtures thereof.

Carboxylic acid or its salt, if present, is preferably present at a level of from 0.1% to 5%, more preferably from 0.2% to 1% and most preferably from 0.25% to 0.5%, by weight of the whole composition.

Viscosity

Compositions in accordance with the present invention preferably have viscosity from 50 to 4000 CPS (50 to 4000 MPa*s), more preferably from 100 to 2000 CPS (100 to 2000 MPa*s), and most preferably from 500 to 1500 CPS (500 to 1500 MPa*s) at 20-1and 20°C. Viscosity in accordance with the present invention is measured using an AR 550 rheometer Ott instruments using a flat steel spindle at 40 mm diameter with the size of the lumen 500 μm. The high shear viscosity at 20-1and low shear viscosity at 0.05 s-1can be obtained from a logarithmic sweep degree shift from 0.1 s-1to 25-13 minutes at 20°C. the Preferred rheology described in this application can be achieved using internal existing structuring with detergent ingredients or by applying an external rheology modifier. Therefore, in a preferred implementation, in accordance with the present invention, the composition further comprises a rheology modifier. Turbidity measurement(NTU)

Turbidity (measured in NTU: nephelometric turbidity units) was measured using the turbidimeter Hach 21 OOP, calibrated in accordance with the procedure provided by the manufacturer. The vials with samples were filled with 15 ml of a representative sample and closed and cleared in accordance with the operating instructions. If necessary, the sample is degassed to remove any bubbles by applying a vacuum or using an ultrasonic bath (see manual for procedure). Turbidity was measured using automatic range selection.

The ways to wash dishes by hand method

Liquid detergent compositions for washing dishes by hand in accordance with the present invention can be used for washing dishes in a variety of ways, depending on the level and type of contamination or grease, and user preferences.

One typical method is the application of undiluted composition that includes a phase when brought into contact this composition, in its undiluted form, with utensils. Said composition can be poured directly onto the plate from the container. Alternatively, the composition may be applied to the apparatus or means for cleaning, e.g., a sponge, a woven material or nonwoven material. The apparatus or means of purification, and therefore W�DCA composition for washing dishes in its undiluted form, then in direct contact with each contaminated surface of the dish to remove specified impurities. The device or the cleaning tool is typically in contact with each surface of the dish during the time period in the range from 1 to 10 seconds, although the actual time of application will depend on such factors as the degree of soiling of the dish. Contacting the device or cleaning means with the surface of the dish is preferably accompanied by simultaneous scraped. Alternatively, the device can be immersed in a liquid detergent composition for washing dishes by hand in its undiluted form, in a small container that can hold a cleaning device.

Before applying the specified song, contaminated glassware can be immersed in a water bath, or hold it under running water, for wetting the surface of the dish.

The method may include an optional rinsing stage, after the step of contacting a liquid detergent composition with the dishes.

EXAMPLES

The composition of example 1 is a reference. Reference composition does not contain ethoxylated anionic surfactant according to the present invention (wt.% the linearity of less than 80% and an average degree of amoxilonline less than 0.8), and contains alkoxysilane �OSVETLENIE non-ionic surface-active agent.

- Example 2 not included in the scope of the present invention. Example 2 contains an anionic surfactant in accordance with the present invention, but does not contain alkoxysilane branched nonionic surfactant. As indicated in the table below, the composition provides enhanced cleaning of grease, improving the profile of foaming, but with lower stability at low temperature.

- Example 3 are also not included in the scope of the present invention because it does not contain the specified anionic surfactant. However, the composition of example 3 contains alkoxysilane non-ionic surfactant in accordance with the present invention. As demonstrated in the table below, the composition provides only a limited improvement in cleaning grease and lasting foam.

Example 4 illustrates an arrangement in accordance with the present invention. This composition shows a synergistic improvement as cleaning grease and sustainability of foam, also having superior stability at low temperatures.

TABLE 1
Wt. %PR.1 (rapper) PR.2PR.3PR.4
Alkyl (C10-14amoxicullin26,926,926,926,9
- wt.% linear Alsina chain76827682
- molar Ms. the degree of amoxilonline0,610,61
C12-14 dimethylamine6,16,16,16,1
Branched nonionic substance: 3-propyl heptanol EO81,01,0
PEI600-EO10-PO7 block polymer0,8 0,80,80,8
Ethanol3,03,02,52,5
Propylene glycol MW 20001,11,11,11,1
Sodium chloride1,31,31,31,3
Minor additives* waterTo balance to 100%
Features:(rap.)
Index cleaning grease0+12+3+20
The foaming index 00+1+8
Stability at low temperaturesPassed the testNot testedPassed the testPassed the test
* Dyes, cloud emulsions, fragrances, preservatives, means for processing, stabilizers, etc.

Test methods:

1) Purification from fat:

The feature of cleaning grease was evaluated by measuring the relative removal of the average consumer beef fat (CABF), applied in excess to the substrate removed after immersion for 90 minutes in a 0.1% by weight solution of the composition in water at 35°C and a water hardness of 15 ° dH. It was compared with the removal of beef fat (CABF), obtained using a reference detergent under the same conditions.

2) foam Stability:

Foam stability was measured by counting the number of plates contaminated secondary consumer levels of beef fat (CABF), which can be washed away, and 0.1% by weight solution of the composition in water at 35°C and a water hardness of 15 dH, before the foam has completely disappeared from the surface of the sink. It was compared with the number�Twomey, plates, which can be washed reference detergent under the same conditions.

3) Stability at low temperatures:

The stability of the compositions was evaluated by storing 50 ml of the composition in 100 ml PET bottles at a constant temperature of -3°C for 3 days. The composition was visually examined for visible deposition and/or section of phases. The presence of visible debris and/or visually distinct phases were recorded as an Unsuccessful test, while visually transparent composition was recorded as the Last test.

TABLE 2: Examples 5-11 are additional implementation of the compositions according to the present invention.

PR. 5PR. 6PR. 7PR. 8PR. 9PR. 10PR. 11
ALKYL (C10-14ethoxy sulfate26,918,726,925,718,726,926,9
- wt.% linear alkyl chain82 928292828392
- molar Ms. the degree of amoxilonline1112111
Sodium alkyl benzene sulfonate-8,0-----
Sodium paraffin sulfonate----8,0--
C12-14 dimethylamine6,1--4,1--6,1
Cocamide propyl betaine-4,5 6,83,26,0--
C12-13 EO7 nonionic substance-----6,0-
Branched nonionic substance: 3-propyl heptanol 8 EO 3-propyl heptanol EO3 C11-15 secondary alcohol EO20
3,0-1,0--1,0-
-2,0-3,0--2,0
----2,0--
PEI600-EO10-PO7 block polymer0,80,80,8
Ethanol4,05,03,03,02,03,03,0
Propylene glycol1,10,81,11,11,11,11,1

0,8
MW 2000
Sodium chloride1,31,30,50,81,31,3
Minor additives* waterTo balance to 100%

The dimensions and values described in this application should not be construed as strictly limited to the exact shown by numerical values. Instead, unless otherwise indicated, each such amount is intended to refer to both the specified value and a functionally equivalent range surrounding that value. For example, the size is described as "40 mm" is intended to mean "about 40 mm".

1. Liquid detergent composition for washing dishes by hand, containing:
a) from about 2% to about 70% by weight of the composition ethoxylated anionic surfactants derived from fatty alcohol, thus:
(i) at least about 82% by weight of the specified fatty alcohol is linear and
ii) the fatty alcohol has an average degree of amoxilonline from about 0.8 to about 4; and
(b) from about 0.1 to about 5% by weight of the composition alkoxysilanes branched non-ionic surface-active ve�society, having an average degree of alkoxysilane from about 1 to about 40;
moreover, the total amount of surfactant is from about 10 to about 85% by weight of the liquid detergent composition.

2. A composition according to claim 1, characterized in that the degree of alkoxysilane specified branched non-ionic substances exceeds the degree of amoxilonline specified ethoxylated anionic surfactant.

3. A composition according to claim 1, characterized in that said ethoxylated anionic surfactant is present at a level of from about 5% to about 30% by weight of the composition.

4. A composition according to claim 1, characterized in that it further comprises from about 0.01% to about 20% by weight amphoteric/zwitterionic surfactants.

5. A composition according to claim 1, characterized in that said ethoxylated anionic surfactant is a saturated C8-C16alkylalkoxysilane.

6. A composition according to claim 1, characterized in that said ethoxylated anionic surfactant derived from the alcohol of natural origin.

7. A composition according to claim 1, characterized in that said nonionic surfactant is present�attempt at a level of from about 0.2% to about 3% by weight of the composition.

8. A composition according to claim 7, characterized in that said non-ionic surfactant contains from about 9 to about 18 carbon atoms.

9. A composition according to claim 8, characterized in that said non-ionic surfactant contains from about 10 to about 14 carbon atoms.

10. A composition according to claim 1, characterized in that said composition contains less than about 2% by weight not alkoxysilanes branched alcohol.

11. A composition according to claim 1, characterized in that said nonionic surfactant has an average degree of alkoxysilane from about 3 to about 20.

12. A composition according to claim 11, characterized in that said nonionic surfactant has an average degree of alkoxysilane from about 7 to about 12.

13. A composition according to claim 1, characterized in that said nonionic surfactant is ethoxylated and/or propoxycarbonyl.

14. A composition according to claim 13, characterized in that said nonionic surfactant is ethoxylated.

15. A composition according to claim 1, characterized in that said branched non-ionic surfactant is selected from:
and. Formula I:

where in formula:
R1is a C5-C16 linear or branched;
R2represents a C1-C8 linear or branched;
R3represents H or C1-C4 alkyl;
b denotes a number from about 1 to about 40;
b. Formula II:

where in formula II:
R1is a C6-C16 linear or branched, preferably linear, alkyl chain;
R2represents a C1-C8 linear or branched, preferably linear, alkyl chain;
R3represents H or C1-C4 alkyl;
b denotes a number from about 1 to about 40; and
(C) mixtures thereof.

16. A composition according to claim 15, characterized in that the branched non-ionic surfactant selected from the group consisting of: Formula I, Formula II, and mixtures thereof, and R1in Formula I and Formula II independently represents a linear alkyl chain.

17. A composition according to claim 15, characterized in that the branched non-ionic surfactant selected from the group consisting of: Formula I, Formula II, and mixtures thereof, and R2in Formula I and Formula II independently represents a linear alkyl chain.

18. A composition according to claim 15, characterized in that the branched non-ionic surfactant selected from the group consisting of: Formula I, Formula II and their mixture�th, and R3in Formula I and Formula II are independently represents H or methyl.

19. A composition according to claim 15, characterized in that the branched non-ionic surfactant selected from the group consisting of: Formula I, Formula II, and mixtures thereof, and b in Formula I and Formula II are independently means a number from about 5 to about 20.

20. Method of manual dishwashing method using a composition according to claim 1, wherein the method comprises a stage on which is injected into contact a specified composition in undiluted form with the dishes.



 

Same patents:

FIELD: personal use articles.

SUBSTANCE: present invention relates to the field of laundry washing. Described is a method for washing a batch of white laundry in a washing machine, preferably - a professional one, where a batch of laundry is subjected to at least three washing stages: at the first stage a detergent is added; at the second one a bleacher is added, at the third one a whitening additive containing a bleacher absorbent is added. Additionally described is application of the bleacher absorbent in the process of washing.

EFFECT: stains removal, odour and whiteness improvement.

7 cl, 6 tbl, 3 ex

FIELD: personal use articles.

SUBSTANCE: group of invention relates to a toilet seat cleaning unit. Proposed is a toilet seat cleaning unit, a fragrance, at least one non-ionic surfactant as well as at least one alkylbemene sulphonate and at least one olefin sulphonate; the unit may be moulded in a rounding machine or press to produce a body symmetrical relative to the rotation axis, in particular - a ball, and is applied in a system composed of at least one cleaning unit and at least one dosing device.

EFFECT: unit swelling reduction.

21 cl, 7 dwg, 1 tbl

FIELD: chemistry.

SUBSTANCE: invention relates to a novel acyclic aldehyde having 16 carbon atoms, containing at least three branches and selected from a group consisting of: 3-ethyl-7,11-dimethyldodecanal, 2,3,7,11-tetramethyl-dodecanal, 7,11,-dimethyl-3-vinyldodeca-6,10-dienal and 4,8,12-dimethyltrideca-4,7,11-trienal, to a composition of substances suitable for use as starting material for producing surfactants and containing at least one of the disclosed acyclic aldehydes, to a composition of detergent alcohols, suitable for producing a composition of surfactants and containing at least one acyclic alcohol converted from the disclosed acyclic aldehyde, and to a surfactant composition suitable for use in a detergent or cleaning composition and containing one or more surfactant derivatives of isomers of the acyclic detergent alcohol converted from the disclosed acyclic aldehyde. The invention also relates to versions of a cleaning composition and to versions of a method of producing an alcohol mixture for a composition of detergent alcohols.

EFFECT: improved properties of compounds.

19 cl, 10 tbl, 24 ex

FIELD: chemistry.

SUBSTANCE: described is a universal detergent and a disinfecting foam preparation, which contains potassium hydroxide, a disinfecting component - catamin AB and water and additionally: sodium hydroxide, alkylpolyglycoside and alkyldimethylamine oxide as non-ionogenic SAS, salt of ethylenediaminotetraacetic acid, glycol A with the following component ratio, wt % (counted per pure substances): sodium hydroxide 5-15, potassium hydroxide 2-8, salt of ethylenediaminotetraacetic acid 1.5-5, mixture of non-ionogenic SAS including: alkylpolyglycoside 2-4 and alkyldimethylamine oxide 2-6, disinfecting component catamin AB 2.5-6, glycol A 0.5-2, water - the remaining part.

EFFECT: increased detergent and disinfecting ability of the preparation due to an increase of the foam formation.

4 cl, 3 ex

FIELD: chemistry.

SUBSTANCE: claimed invention relates to liquid detergent for manual dish-washing, which contains: (a) from 0.2% to 3% of the total composition weight, of chelating agent, selected from the group, consisting of glutamic-N,N-diacetic acid, its salts and derivatives, diethylenetriaminepentamethylphosphonic acid; diethylene triaminepentaacetic acid, methylglycenediacetic acid and their mixtures, (b) from 12% to 45% of the total composition weight, of surface-active substance, selected from the group, consisting of anionic, non-ionic, cationic, amphoteric, zwitterionic, semi-polar non-ionic surface-active substances and their mixtures, and said composition contains from 5% to 30% of the total composition weight, of anionic surface-active substances, selected from the group, consisting of sulphate and sulphonate surface-active substances; and from 3% to 20% of the total composition weight, of non-ionic surface-active substances, where said non-ionic surface-active substance includes branched surface-active substance, where weight ratio of the total content of surface-active substance to content of non-ionic surface-active substance constitutes from 2 to 10, and where average degree of branching of alkyl chain of surface-active substances constitutes, at least, 10% of the total weight of surface-active substances. Claimed invention also relates to method of dinnerware purification.

EFFECT: obtaining detergent composition, providing improved purification and improved lustre.

11 cl, 21 ex

FIELD: chemistry.

SUBSTANCE: claimed washing liquids for heating systems contain either solution of 1-3% citric acid, 0.03-0.05 wt % of hydrochloric acid and 0.05-0.5 wt % of chitosan, modified with isobutyric acid, containing methylpyrazole group (chitosan methyl pyrazolyl isobutyrate - CMPI), or 1-3 wt % of citric acid, 0.1-0.15 wt % of sulfuric acid and 0.05-0.05 wt % of chitosan, modified with isobutyric acid, containing methylpyrazole group (chitosan methyl pyrazolyl isobutyrate - CMPI), water - the remaining part.

EFFECT: effective purification of pipelines, prolongation of service term of heating systems and protection of steel pipelines against corrosion.

2 cl

FIELD: chemistry.

SUBSTANCE: described is a detergent which contains: an alkali metal hydroxide, sodium metasilicate, dye and water, and additionally oxyethylene diphosphonic acid, a tetrasodium salt of oxyethylene diphosphonic acid, a salt of ethylenediaminotetraacetic acid, citric acid, sodium silicate, a sodium salt of a copolymer of acrylic acid and maleic acid, alkylated polyglycoside with length of the alkyl chain of C6-C12, a mixture of anionic surfactants, with the following ratio of components, wt %: alkali metal hydroxide 4-12%, oxyethylene diphosphonic acid 0-8%, tetrasodium salt of oxyethylene diphosphonic acid 0-8%, salt of ethylenediaminotetraacetic acid 1-3%, citric acid 2-10%, sodium silicate 0,5-3%, sodium salt of a copolymer of acrylic acid and maleic acid 0-1%, alkylated polyglycoside with length of the alkyl chain of C6-C12, with respect to pure substance 1-6%, mixture of anionic surfactants, which includes a compound of the type RO-(CHR'CHR'-O)nSO3Na, where R is a linear or branched saturated or unsaturated alkyl substitute with backbone chain length of C10-C18, R'=H, CH3, n ranges from 0 to 4 and a compound of the type R"C6H4SO3X, where R" is a linear or branched saturated or unsaturated alkyl substitute with backbone chain length of C6-C12, X-Na, K, H with respect to pure substance 2-10%, dye 0.05-0.5%, water - the balance.

EFFECT: improved quality of contactless washing due to higher foaming capacity.

6 cl, 3 ex

FIELD: chemistry.

SUBSTANCE: industrial detergent contains the following in wt %: surfactant 1.5-1.8, antifoaming agent 0.1-0.2, demulsifying agent 0.4-4.0, corrosion inhibitor 0.001-0.002, alkali 7.0-7.5, active component - the balance. In the disclosed industrial detergent, the surfactant used is a mixture of nonionic surfactants - synthanol and OP-10; the corrosion inhibitor is sodium benzoate; the active component is a mixture of alkali metal salts - sodium carbonate, sodium phosphate and ammonium sulphate.

EFFECT: high detergent power, corrosion resistance and good quality of the zinc coating when cleaning rolled metal products in belts before zinc plating.

2 tbl

FIELD: chemistry.

SUBSTANCE: invention relates to industrial detergents for cleaning and deoiling surfaces from organic contaminants, including petroleum products, lubricants, oils and other liquid hydrocarbons, and can be used in cleaning different metal and non-metal surfaces in petrochemical industry, mechanical engineering, instrument making, transportation, agricultural systems, as well as in inter-operation washing of assemblies and units in any industry. Said detergent composition contains the following, wt %: sodium tripolyphosphate 18-26, trisodium phosphate 19-23, calcined soda 16-21, oxalic acid 4-8, technical borax 4-6, sodium sulphate 9-11, diproxamine 157 8-9, carboxymethyl cellulose 2, synthanol 7-8, alkyl sulphate 1-2, allantoin 1-2, glycerine 0.1, pine rosin 0.01-2, ammonia spirit1-2, HydroChem 110 1-2, HydroChem 140 1-2, casein glue 0.01-2, edible aromatising additives 0.1-0.5.

EFFECT: higher detergent and emulsifying power, low toxicity, wider field of use, use of the universal detergent composition GENS in liquid, gel and powdered form.

FIELD: chemistry.

SUBSTANCE: invention relates to an aqueous detergent composition containing the following components in wt %: a) 0.1-15% of at least an alkyl ester carboxylate of formula R-O-(CH2CH2O)m-CH2-COOX (I) b) 0.1-15% of at least one amine oxide of formula c) 0.1 -40% of at least one alkyl ester sulphate type anionic surfactant with a carbon chain containing 10-18 carbon atoms, d) water - up to 100%.

EFFECT: detergent composition with improved foaming and cleaning efficiency.

13 cl, 2 tbl, 1 ex

FIELD: chemistry.

SUBSTANCE: described is a composition for cleaning the surface of soft and porous semiprecious stones, which contains: a) a water-soluble alkali and alkali-earth metal salt in total amount of 3.4-3.6 wt %, selected from salts present in seawater; b) one of α-amino acids in total amount of 0.5-2.0 wt %, selected from 18 amino acids present in pearl; c) a nonionic surfactant in total amount of 0.5-1.0 wt %; d) a preservative in total amount of 0.1-0.25 wt %; e) water - the balance. The disclosed composition has potential for use in the jewellery industry, in museum restoration workshops, in antique and jewellery stores and in preparing jewellery exhibitions.

EFFECT: giving an article lustre without destroying the surface structure.

2 cl, 2 tbl, 26 ex

FIELD: chemistry.

SUBSTANCE: invention relates to field of detergent compositions, in particular highly active compositions of liquid detergents, intended in addition to other applications, for cleaning in laundries and/or household conditions. described are compositions of bicontinuous detergent microemulsions, which contain surface active system, water solution and oil or solvent, and additionally described are sprayer, device for preliminary stain removal and method of microemulsion preparation.

EFFECT: provision of fast dissolution of solid fatty material (dissolution of oil/fatty stains).

12 cl, 9 tbl, 5 ex

FIELD: chemistry.

SUBSTANCE: invention refers to detergents and aims at degreasing cold-rolled metal in rapid metal working units before applying various types of coatings. What is described is a detergent for the metal surface cleaning containing sodium hydroxide, sodium carbonate, a composition of non-ionic oxyethylated products free from alkylphenol ethoxylates, a mixture of polyoxyethylated esters of monoethanolamides of synthetic fatty acids of a C10-C16 fraction, additionally contains trisodium salt of nitrilotriacetic acid and an antifoaming agent in the following proportions, g/l: sodium hydroxide - 4.07-20.35, sodium carbonate - 5.50-27.50, a composition of non-ionic oxyethylated products free from alkylphenol ethoxylates - 0.05-0.25, a mixture of polyoxyethylated esters of monoethanolamides of synthetic fatty acids of a C10-C16 fraction - 0.05-0.25, trisodium salt of nitrilotriacetic acid - 0.30-1.50, antifoaming agent - 0.03-0.15, water the rest to 1 l.

EFFECT: high degree of the metal surface cleaning, low consumption of the agent, and reduced production costs.

1 tbl, 3 ex

FIELD: chemistry.

SUBSTANCE: invention relates to technological processes, where detergents are applied for washing and defatting of equipment of food industry factories, products of ferrous metals and their alloys, polymer and fluoropolymer materials at enterprises of machine-building industry, chemical, petrochemical and mining industry. Described is washing and defatting substance, which contains (counted per dry residue), wt %: sodium hydroxide 20.0-25.0, sodium metasilicate pentahydrate 27.0-29.0, sodium carbonate 17.0-19.0, sodium citrate dihydrate 5.0-7.0, sodium sulphate 11.0-18.0, anionic SAS 2.0-6.0, non-ionogenic SAS 1.0-5.0, trichloroethylene 0.1-4.0, 1,1-difluoro-1,2,2-trichloroethane (chladone) 0.1-3.0.

EFFECT: increase of washing ability of claimed substance, reduction of its corrosion aggressiveness and load on the environment ecology.

3 cl, 2 tbl, 9 ex

FIELD: chemistry.

SUBSTANCE: washing and disinfecting preparation contains the following components, wt %: a non-ionogenic surface-active substance (SAS) - 1.5-5.0; alkyldimethylbenzylammonium chloride and/or didecyldimethylammonium chloride - 3.5-5.5; potassium hydroxide - 5.0-10.0; potassium methasilicate - 2.0-4.5; sodium gluconate - 5-10; triethanolamine - 0.5-1.5 and water - to 100.

EFFECT: extension of a spectrum of removable soiling, high washing ability and reduction of a negative ecological influence on the environment.

2 tbl

FIELD: chemistry.

SUBSTANCE: invention relates to technological processes with the application of washing preparations, in particular in the metallurgical industry for cleaning of hard-rolled metal-roll in rolls on units of continuous processing from oils, rolling emulsols, lubricants, carbonaceous pollutions. Described is a liquid alkaline washing preparation, which contains sodium hydroxide, trisubstituted sodium phosphate, complexon (aqueous disodium salt of ethylenediaminetetraacetic acid or aqueous trisodium salt of hydroxyethylidendiphosphonic acid), a washing surface-active agent Berol DGR 81, additionally contains potassium hydroxide, a washing surface-active agent Berol LFG 61, a mixture of polyoxyethylated ethers of monoethanelamides of synthetic fatty acids of fraction C7-C17, propylene glycol and an antifoaming additive Biomol DF -63 with the following component ratio, g/l: sodium hydroxide 2.05-3.4, potassium hydroxide 1.5-2.5 sodium phosphate trisubstituted 0.08-0.13, aqueous complexon-disodium salt of ethylenediaminetetraacetic acid, aqueous or aqueous trisodium salt of hydroxyethylidendiphosphoric acid 0.16-0.28, washing surface-active agent Berol DGR 81 - optimised mixture of nonionic SAS of alcohol ethoxylates and alkylglucosides 0.12-0.2, washing surface-active agent Berol LFG 61 - optimised mixture of nonionic SAS of alcohol ethoxylates and alkylglucosides 0.58-0.97, mixture of polyoxyethylated ethers of monoethanolamides of synthetic fatty acids of fraction C7-C17 0.035-0.09, propylene glycol 0.21-0.36, antifoaming additive Biomol DF -63 0.17-0.29, water - the remaining part to 1 l, and the weight ratio of the mixture of the surface-active substances to propylene glycol and to the antifoaming additive constitutes : (4.3:1.24:1).

EFFECT: high washing ability both in the chemical and in electrochemical method of degreasing, low foaming.

2 tbl

FIELD: chemistry.

SUBSTANCE: described is a sanitary-hygienic cleaning agent containing the following components, wt %: hydrogen chloride (with respect to 36% hydrochloric acid 15.5-22) 5.58-7.92, nonionic surfactant 0.5-1.6, polyelectrolyte 2.0-6.0, hexamethylenetetramine 0-4.0, acid corrosion inhibitor 0.03-0.1, water - the balance. The acid corrosion inhibitor used is a reaction product of polyethylene polyamines with benzyl chloride in molar ratio 1:3, respectively, or a reaction product of polyethylene polyamines with oleic acid and benzyl chloride in molar ratio 1:1:3, respectively.

EFFECT: high efficiency of removing rust and hardness salt deposits from toilet bowls, faience sinks and ceramic tile surfaces, faster treatment and longer shelf life of the cleaning agent.

3 cl, 4 ex

FIELD: chemistry.

SUBSTANCE: described is a concentrated liquid detergent composition which contains: (A) anionic surfactant, (B) amphoteric surfactant, (C) 5-15 wt % monoatomic or diatomic alcohol, (D) 8-18 wt % nonionic surfactant with NOB value of 0.8-1.1 and molecular weight of 500 or less, and (E) 45 wt % or less water, where the sum of (A) and (B) ranges from 40 to 60 wt %; where the ratio (C):(D) in the mixture ranges from 3.5:1 to 1:2.5; and where viscosity at 30°C is 300 mPa·s or higher, when the composition is diluted to concentration of (A) and (B) of 15 wt %.

EFFECT: obtaining a concentrated detergent while maintaining the respective viscosity by diluting with water, low power consumption.

7 cl, 7 tbl, 5 ex, 1 dwg

FIELD: chemistry.

SUBSTANCE: described is a cleaning agent, containing, wt %: propylene glycol 5-15; nonionic surfactant (e.g. Sintanol ALM-2, Sintanol ALM-3 or similar) 0.5-2.0; fragrance (e.g. Watermelon CFB23845 or similar) 0.1-0.5; isopropanol or ethanol - the balance up to 100.

EFFECT: removing tobacco tar from smooth, rough and hairy surfaces without damaging the structure and colour of the cleaned objects.

2 tbl, 3 ex

FIELD: chemistry.

SUBSTANCE: detergent is phosphate-free and has high detergent power and low foaming. The detergent for treating food processing equipment contains an alkali metal hydroxide, a mixture of nonionic surfactants and water. The detergent further contains a sodium salt of aldonic acid in form of sodium gluconate, low-foam nonionic surfactant in form of C8-C10 alkyl polyglycoside and triethanolamine, and the mixture of nonionic surfactants is added in form of a mixture of ethoxylated fatty alcohols with hydrocarbon radical chain length of C12-C14 with ethoxylation degree of 6 and 10, with the following ratio of components, wt %: alkali metal hydroxide 20-30, sodium gluconate 1-3, low-foam nonionic surfactant - C8-C10 alkyl polyglycoside 0.1-1, triethanolamine 0.1-1, mixture of nonionic surfactants -10, water - the balance.

EFFECT: producing phosphate-free low-foam detergent, high detergent power.

2 tbl

FIELD: chemistry.

SUBSTANCE: described is a concentrated liquid detergent composition which contains: (A) anionic surfactant, (B) amphoteric surfactant, (C) 5-15 wt % monoatomic or diatomic alcohol, (D) 8-18 wt % nonionic surfactant with NOB value of 0.8-1.1 and molecular weight of 500 or less, and (E) 45 wt % or less water, where the sum of (A) and (B) ranges from 40 to 60 wt %; where the ratio (C):(D) in the mixture ranges from 3.5:1 to 1:2.5; and where viscosity at 30°C is 300 mPa·s or higher, when the composition is diluted to concentration of (A) and (B) of 15 wt %.

EFFECT: obtaining a concentrated detergent while maintaining the respective viscosity by diluting with water, low power consumption.

7 cl, 7 tbl, 5 ex, 1 dwg

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