Method of laundering

FIELD: textile industry.

SUBSTANCE: method includes stage of article washing with detergent solution, which contains organic polymer, having spinnability, with average molecular weight of 1500000 or more, and where 60 mol % or more of its component monomers contain sulfonic acid group, or form of its salt, or sulfuric acid group, or form of its salt, provided that polyethylene oxide is unavailable. Invention also describes the following: method of hand washing, including stage of hand washing of laundry item with specified detergent solution, or washing solution produced by dissolution of detergent solution with more than 1-1000-multiple amount of water; and versions of detergents. Suggested washing solution may be used for hand washing.

EFFECT: improved smoothness of articles in process of washing and hand care, reduced unfavorable factors of squeaking, rough texture and physical fatigue in process of hand washing.

19 cl, 2 tbl, 11 ex

 

The technical FIELD TO WHICH the INVENTION RELATES.

The present invention relates to a method for improving the smoothness to be washing products, the method of hand washing, cleaning composition, the cleaning composition for washing clothes and creamy the improver smoothness.

In addition, the present invention relates to a method of washing to be washed product c detergent composition, the cleaning composition for washing clothes or cream to improver smoothness mentioned above.

The LEVEL of TECHNOLOGY

Methods of washing in General can be divided into two types: hand wash and machine washable. In recent years, with the widespread use of washing machines is increasingly used to wash in the washing machine. However, from the viewpoint of ease of removal of polluting stains and economic benefits of hand washing still takes place.

Although hand wash provides flexible conditions of the washing depending on situations related to washing, such as the degree of removal of polluting stain and the type of products subject to washing, washing manually person is accompanied by physical and mental fatigue compared to washing in the washing machine. In particular, when "washing with friction," in which be washing products RUB between them, the mechanical force can preklady the diamonds directly to the places be washed, thereby realizing one of the most natural ways of hand washing. However, a long period of work onerous for erasing manually person.

In addition, since the surface is subjected to washing products, such as garments, is not microscopically smooth when items such service actually RUB against each other, there is a resistance (abrasion). This resistance is felt erasing person as adverse factors, such as "rough texture" and "creak", and increases physical effort that puts people, from the point of view of the exhaustion of physical strength during washing with friction. In addition, the local friction that occurs during washing with friction, leads to scratches or cuts on the hands of man, which in turn are involved in the deterioration of the fibers, the so-called "tissue damage" is subjected to washing products. Damage to the fibers not only shortens the life of service, but also serves as an accelerating factor for the adhesion of contaminants spots, thereby further increasing the cost of physical strength required for washing.

In addition, this resistance to abrasion during washing in a washing machine causes damage to the fibers arising under the action of mechanical forces, such as paramasivan is e, and loss of form.

On the other hand, usually technological developments are mainly taking into account aspects "remove contaminants adhering stains to be washed products", such as improving the detergency of detergent or preventing re-deposits on washed clothes, such as clothing, or taking into account the aspect of "carrying out finishing washed linen", such as giving a soft washed linen (see, for example, patent publication 1, 2, 3 and 4). If we take into account the above-mentioned adverse factors and costs of physical forces that occur during hand washing, that is, "mental and physical costs erasing person", technological developments focused on improvements in reducing these costs, up to the present time was not implemented.

The patent publication 1: JP-A-Hei 5-508889

The patent publication 2: JP-B-2620318

The patent publication 3: JP-A-Hei 7-216389

The patent publication 4: JP-2002-538289 A

Description of the INVENTION

PROBLEMS, WHICH are SOLVED by the INVENTIONS

Taking into account the above materials, the purpose of the present invention is to develop a method for improving the smoothness to be washing the product during hand washing carried out in the household; the development of a method of washing by Amigo washing products, which allows to reduce such adverse factors as "rough texture" and "creak" and physical fatigue, and to provide for the care of hands and preservation of the product during washing; the development of a detergent composition for implementing the method or the above-mentioned process; and the development of creamy improver smoothness.

Additionally, the purpose of the present invention is to obtain a detergent composition for washing clothes, which reduces the adverse factors, such as "rough texture", "creak" and physical fatigue, without deterioration of properties, preventing re-deposition; to prevent formation of scratches on the hands and to ensure the safety of underwear when washing items to be washed; in obtaining creamy conditioner smooth and secure method of washing with a detergent composition for washing Laundry or creamy improver smoothness mentioned above.

The WAY to SOLVE PROBLEMS

The present invention relates to

[1] the method for improving the smoothness to be washing the product during washing, which includes phase washed with wash solution in the washing solution is an organic polymer having predomantly;

[2] the method for improving the smoothness to be washing the product during hand washing, linking the stage hand washed with wash solution in terms when the washing solution is an organic polymer having predomantly;

[3] method hand wash, includes a stage hand washing to be washed product detergent solution, with predomantly containing organic polymer having predomantly, or detergent solution, obtained by diluting the cleaning solution more than 1 to 1,000-fold amount of water;

[4] the method according to the above item [3], in which the washing solution has a pH of 9.0 or more;

[5] the cleaning composition to improve the smoothness containing organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.% from washing composition;

[6] the cleaning composition according to the above item [5], in which the detergent composition contains

(a) an organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.%;

(b) a surfactant;

(c) an alkalizing agent; and

(d) the agent, absorbing metal ions;

[7] the cleaning composition according to the above item [5], in which the detergent composition contains

(a) a polyethylene oxide with average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.%;

(b-1) anionic surfactant in the amount of 10% or more;

(c) selecively agent; and

(d) the agent, absorbing metal ions,

and in which the detergent composition does not actually contain a simple Olkiluoto ether of polyoxyethylene (b-2);

[8] the cleaning composition according to any one of above items [5]-[7], in which the detergent composition is in powder form or granular form;

[9] the cleaning composition according to any one of above items [5]-[8], further containing an inorganic salt capable of releasing hydrogen peroxide in water, in which the inorganic salt is contained in an amount of 15 wt.% or less of the detergent composition;

[10] cleaning composition for washing clothes containing polymer with an average molecular weight of 500,000 or more, in which 60 mol.% or more components of the monomers contains sulfonation group or its salts, or sulfuric acid group or its salts;

[11] cleaning composition for washing Laundry according to the above item [10], in which the detergent composition for washing Laundry is in powder form or granular form;

[12] cleaning composition for washing Laundry according to the above item [10] or [11], in which the detergent composition contains

(a') a polymer with an average molecular weight of 500,000 or more, in which 60 mol.% or more of its constituent monomers contains sulfonation group or its salts, or sulfuric acid group or its salts;

(b) the surface is Resto-active substance;

(c) an alkalizing agent; and

(d) the agent, absorbing metal ions;

[13] cleaning composition for washing Laundry according to any one of above items [10]-[12], which make up the monomer is a derivative from one or more monomers selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid and its salts and styrelseledamot acid and its salts;

[14] the creamy improver smoothness containing organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.% from creamy improver smoothness;

[15] the creamy improver smoothness on the above item [14], in which the organic polymer is a polymer or copolymer derived from a monomer selected from the group consisting of acrylic acid, acrylamide, acrylamidophenylboronic acid, dimethylaminoethylmethacrylate acid, vinyl alcohol and mixtures thereof; polysaccharide with diabetes the main chain; or polypeptide;

[16] the creamy improver smoothness on the above item [14], in which the organic polymer is a polyethylene oxide, and which in fact does not contain a simple Olkiluoto ester polyoxyalkylene;

[17] the creamy improver smoothness containing polymer with the her molecular weight of 500,000 or more, in which 60 mol.% or more components of the monomers contains sulfonation group or its salts, or sulfuric acid group or its salts;

[18] the creamy improver smoothness on the above item [17], which make up the monomer is a derivative from one or more monomers selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid or its salts, and styrelseledamot acid or its salts;

[19] the method of washing to be washed product with a detergent composition for washing clothes, mentioned above in paragraph [10]; and

[20] the method of washing to be washed product with creamy improver smoothness specified above in paragraph [17].

The EFFECTS of the INVENTION

When applying the method of washing to be washed product, the cleaning composition or detergent composition for washing Laundry according to the present invention discovered this effect, which allows an ordinary washing, particularly hand washing in the home with a more pleasant experience. In particular, according to the present invention discovered several effects, such as improved sensation during hand washing, while reducing the physical costs and the possibility of implementing additional conservation linen and prevent abrasion.

BEST mode for carrying out IMAGE IS ETENIA

A typical component of a detergent, such as a surfactant or a low molecular weight polymer is introduced into the formulation as dispersant additives for removing polluting stains and carbon spots, such as sodium polyacrylate or polyethylene glycol, may have the effect of sliding under certain conditions, for example, in a very highly concentrated system (for example, in a liquid mixture with a concentration of 100 g/l relative to the concentration of the main components). However, when the concentration of the washing solution, which is typically used (for example, in a liquid mixture with a concentration of from 0.05 to 10.0 g/l relative to the concentration of the main components), such effects slip does not exist, or even if there is a slight effect, it is not sufficient to address the above mentioned shortcomings in the implementation of hand washing. For example, it is known that some compounds, such as polymers based on silicon compounds described in the aforementioned patent JP-A-Hei 5-508889, can reduce the friction between the fibers. However, the consumer may still not feel particularly significant changes in the wash with friction using a wash solution at commonly used concentrations. Therefore, with effects that are created only such basic components, when rochestie not there is a pleasant perception to the consumer. In addition, polymers based on silicon compounds are a type of lubricant covering the surface and having the ability to flow, to reduce friction on the surface of the fibers during drying, and when such polymers are used in the form of aqueous solution, i.e. washing solution, such polymers do not provide sufficient effects in preventing damage to the fibers that occur during washing with friction.

To hand wash at home was accompanied by a pleasant perception, it is necessary that the smoothness is subjected to washing products could be implemented in the washing solution at normal concentration.

As a result of intensive study of the requirements for the implementation of hand washing with far better perception of the authors of the present invention have found that a certain smoothness can be obtained, in particular, by adding to the cleaning solution of certain organic polymer friction subject to washing each other and implementation of hand washing, and through this to improve sensation during hand washing and at the same time reduce the cost of physical force, resulting in additionally includes storing linen and hand care.

The authors of the present invention have also discovered that such polymers from among the content of inorganic fillers polymers with specific functional groups, in particular, possess excellent properties from the point of view of preventing re-deposition of the cleansing composition.

In addition, the authors of the present invention found that the smoothness obtained by adding such an organic polymer cleaning solution, helps prevent damage to the sheets in the wash items in your washing machine and prevent the leads and the distortion of linen in the washing machine due to the fact that between products for washing and fibers occurs smoothness, through which is provided the effect of preservation underwear, such as preventing the loss of its shape.

These and other advantages of the present invention will become apparent from the following description.

1.Method for improving the smoothness

One of the important features of the process of improving smoothness during washing to be washed product (hereinafter referred to simply as a means of improving smoothness") of the present invention is that the method includes a stage washed with wash solution in the washing solution is an organic polymer having predmosti (hereinafter also referred to as "preday organic polymer"). For example, the method can be carried out using a washing solution obtained by prepending m the irradiation of the composition, containing predomi organic polymer to water for dissolving or by a separate add predamage organic polymer during washing to cleaning solution that does not contain predamage organic polymer. Smoothness subject to washing products can significantly improve with the help of the method containing the above-mentioned characteristic.

Used here, the term "detergent" refers to a liquid composition on the basis of water to effect the washing service, during which the detergent composition is dissolved or suspendered.

Used here, the phrase "improving smoothness" refers to reducing the friction between clothes or between the fibers, or the like, in the washing solution or in a state in which the clothes or fibers contain detergent during washing. In particular, during hand washing smoothness may manifest as the degree of resistance (abrasion), feel hands erasing person during washing with friction are subject to washing products. Therefore, to improve the smoothness of this perception or sensation of resistance (abrasion) is reduced in order to be washing products could be rubbing each other very easily.

In particular, improving smoothness" is such a case, as described below. They say that the smoothness is improved when applying the cleaning solution) if the cleaning solution has lower resistance (abrasion), feel hands when hand washing with friction from clothing or items of clothing, in other words, the smoothness is higher and the feeling creak is more insignificant in comparison with detergent solution, not containing organic polymer. Here as a washing solution, not containing organic polymer, it is possible to apply the cleaning solution, obtained, for example, by dissolving the composition obtained in example obtain I-1 according to the method described in the section "testing Method hand wash". As a method of washing with friction, it is possible to apply the method, also described in "testing Method hand wash".

In particular, the erase man according to the method of improving the smoothness of the present invention during the wash feels soft layer on the surface to be washing products, when a fingertip or the like touches the surface. This feeling appears due to added to the cleaning solution pradamano organic polymer. In this regard, it is assumed that the layer or part plays the role of the moving layer, thus considered, provided a sense of "smoothness" subject to washing touching products relative to each other. Since according to the present invention in the underlying washing the product during washing such a layer exists, and while the article is RCTs with friction occurs "smoothness", washing can be done with a pleasant perception.

Additionally, the effect of removing cuts and scratches on his hands arising from friction to be hand-washing items (so-called effect of reducing abrasion), and the effect of eliminating damage to the fibers is subjected to washing products (so-called effect of preserving linen from damage during washing).

Definition of predmosti

Used here, the term "predmosti" means the ability of an object to be a property of elongation, i.e. the so-called ability to form fibers, and a perfect example of predmosti includes, for example, the ability of fermented soybeans, etc. to form the thread (predmosti).

Predmosti represents the ability to form a structure that is similar to the continuous filaments, without damaging inclusions, when the liquid composition flows (or flows) with a low speed or when the liquid composition is pulled while holding the liquid composition from one end. An example of such phenomena include, for example, the ability of viscous mucus animals or plants, etc. to form the threads. In addition, predmosti known as one of the phenomena of elastic relaxation of the liquid composition and is completely independent of the surface tension or viscosity. The above-mentioned property predmosti can OBS is to give a polymer solution, even in the case of conventional polymer solution, provided that the concentration of polymer is, for example, to 100 g/l or more, as mentioned above. However, the above-described polymer solution has such a high viscosity that the polymer solution has significant drawbacks in terms of fluidity. In the present invention predmosti refers to predmosti, which may have a liquid composition based on water specific organic polymer at very dilute concentrations, at the same time while maintaining its high turnover.

Definition of predmosti organic polymer

Used here predomi organic polymer refers to an organic polymer, an aqueous solution which has predomantly of the present invention, as mentioned above. This predomi organic polymer is usually different from the organic polymer with high molecular weight, which has a so-called "thickening effect".

In the present invention predomi organic polymer is preferably an organic polymer, an aqueous solution with a concentration of 30.0 g/l or less has predomantly, more preferably, when predomantly has a water solution with a concentration of 10 g/l or less, and even more preferably, when predomantly water has the initial solution with a concentration of 5 g/l or less.

In the present invention the presence or absence of predmosti the organic polymer is determined according to the following method. An aqueous solution of the mixture was obtained by adding to an aqueous solution containing 0.07 wt.% dodecylbenzenesulfonate sodium and 0.07 wt.% anhydrous sodium carbonate, the organic polymer in such a concentration that the viscosity of an aqueous solution of the mixture was approximately 500 MPa·s, about 200 MPa·s, about 100 MPa·s or approximately 20 MPa·s according to the definition on the viscometer (B-type at 25°C (0°DH, 60 rpm). Predmosti obtained aqueous solution of the mixture was evaluated according to the method described in the next section, "a Method of evaluating predmosti". When submitted a decision that an aqueous solution of the mixture has predomantly in any of the solutions described above values of viscosity, organic polymer was considered predomin organic polymer.

A method of evaluating predmosti

In the present invention an aqueous solution, having the ability to form filaments (predomantly) with a light leaking from the tip (inner diameter: 1 mm) Pasteur pipettes (glass, for example, of glass ASAHITECHNO GLASS, IK-PAS-5P), defined as an aqueous solution having predomantly. Here the solution, from which are formed over long threads, defined as an aqueous solution with more than si is Inoi (or higher) predomantly. After thorough mixing, the solution is an aqueous solution used in the method of estimating at 25°C, and the process flow carried out by placing the tip of a Pasteur pipette at least 5 mm from the point at which the drains aqueous solution. For an aqueous solution with a strong predomantly predmosti can more easily confirm, if you carry out the procedure escaping with even greater heights. The procedure of leakage can be performed several times and confirm (predmosti). "Thread", formed during the procedure, leak, is a thread thinner than 1 mm in diameter. Published predmosti can also be defined with the help of equipment such as capillary rheometer Capillary Breakup Extensional Rheometer (CaBER1) manufactured by Thermo HAAKE.

A higher effect is relatively more predmosti, namely higher predmosti polymer, "smoothness" can be performed at even lower given concentration. When the cleaning solution has predomantly, you can get even higher "smoothness". Even when not, it was found that the cleaning solution has predomantly set "smoothness" can be obtained by adding to the cleaning solution of the polymer with the ability to give the aqueous solution predmosti.

Predomi organic polymer of the present invention is a soybean is inania, usually not used in the detergent composition. Predomi organic polymer comprises crosslinked polymers and unstitched polymers. Among predomi organic polymers preferred according to the present invention is seamless polymer with a higher predomantly.

Specific examples predamage organic polymer include a polymer or copolymer derived from one or more monomers selected from the group consisting of ethylene oxide, acrylic acid, acrylamide, 2-acrylamide-2-methylpropanesulfonic acid, dimethylaminoethylmethacrylate acid, vinyl alcohol, and amino acids such as glutamic acid and aspartic acid; polysaccharide with diabetes the main chain, such as starch, hydroxyethylcellulose (NES), carboxymethylcellulose (CMC), hypromellose (HPMC) and hyaluronic acid. Among them, preferred is a polymer or copolymer derived from one or more monomers selected from the group consisting of ethylene oxide, acrylic acid, acrylamide, 2-acrylamide-2-methylpropanesulfonic acid, dimethylaminoethylmethacrylate acid, vinyl alcohol, amino acids such as glutamic acid and aspartic acid; and the polysaccharide with diabetes the main chain, such as starch, hydroxyethylcellulose (NES) or hydroxypropylmethylcellulose the oz (HPMC). More preferred are polymer based on acrylic acid or its salts, acrylamide polymer, the polymer based on 2-acrylamide-2-methylpropanesulfonic acid or a salt thereof, a copolymer of acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid or a salt thereof, polyethylene oxide, and hypromellose. From the point of view of the economic benefits and the like, preferable are polymer based on acrylic acid or its salts, acrylamide polymer, the polymer based on 2-acrylamide-2-methylpropanesulfonic acid or a salt thereof, a copolymer of acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid or its salts and polyethylene oxide.

Here as predamage polymer of the present invention a high smoothness has a polyethylene oxide. However, the polyethylene oxide loses its ability to impart smoothness when specific interaction, in the case of joint presence in the washing solution, with a simple alkilany ether of polyoxyethylene, which is a nonionic surfactant. Therefore, a method for improving the smoothness of the present invention, when predomi organic polymer is a polyethylene oxide, the cleaning solution does not, in fact simple alkilany ether of polyoxyethylene. Preferably, the cleaning solution has essentially the Eski not had a simple Olkiluoto ester polyoxyalkylene and simple alkylperoxo ether of polyoxyethylene. Used here, the expression "actually does not contain" means that the compound is contained in the washing solution at a concentration of 100 mg/l or less. Preferably, the connection is contained in a concentration of 70 mg/l or less, more preferably 50 mg/l or less, more preferably 30 mg/l or less, and most preferably not contained in the washing solution. Also the weight ratio of the specified connection to the polyethylene oxide is 12x or less, more preferably 10-fold or less, more preferably 5 times or less, more preferably 1-fold or less, and most preferably, the connection specified is not contained in the washing solution.

In addition, crosslinked acrylic polymer (Aqupec production company Sumitomo Seika Co., Ltd., Carbopol production company BF Goodrich and the like), in which the present invention is estimated as an organic polymer that does not have predomantly, and which is often used as a thickening agent for liquid detergent or the like, is a polymer predmosti which is blocked in the thickening system where the aqueous solution has thixotropic properties.

From the point of view of the individual add predamage organic polymer and other components of the detergent predomi organic polymer mo who should be present by itself or together with another connection, forming at getting creamy improver smoothness. In addition, as a creamy improver smoothness can be applied predomi organic polymer by itself or you can use two or more kinds of organic polymers. In addition, such predomi organic polymers can be added by including predamage organic polymer in the detergent composition.

From the point of view of ensuring smoothness in the way of improving the smoothness of the present invention, the number predamage organic polymer, which is present in the washing solution is preferably from 2 mg/l or more, more preferably from 5 mg/l or more, even more preferably from 10 mg/l or more, even more preferably from 20 mg/l or more, and still more preferably from 50 mg/l or more. The timing for adding predamage organic polymer cleaning solution is not specifically limited and includes the addition of just before hand washing, hand washing, before soaking, when washing with soaking, etc. in Addition, the method of adding predamage organic polymer includes a method comprising a stage of addition of the polymer as it is; the method comprising the stage of adding the solution obtained p is the prior dissolution of the polymer in the solvent, such as water; the method comprising a stage of mixing of the polymer with other compounds for the formation of structure in the form of powder, liquid, gel or the like and adding the composition; the method comprising the stages of pelletizing polymer; the method comprising the stage of incorporation of the polymer in the detergent composition in any of the forms in the form of liquid, gel, paste, powder, granules or in the form of additional molded product such as a tablet or in form of a viscous mass, etc. Detergent composition containing predomi organic polymer, can be added to water to dissolve, to get the cleaning solution, or predomi organic polymer can be added to the prior cleaning solution according to the above-mentioned method. In any case, the amount of detergent composition in the washing solution is not specifically limited.

When the detergent composition containing predomi organic polymer, can be added to water for dissolution to obtain a cleaning solution, a method of obtaining a detergent composition containing predomi organic polymer is not specifically limited. The detergent composition can be obtained in accordance with the methods described in the publications Tokkyocho Koho: Shuchi Kanyo Gijutsu Shu (Clothes Powder Detergent: Japanese Patent Office), 10(1998)-25(7159), and JP-B-3123757, which are known as General methods of obtaining detergent formulations. Alternative my the third composition can be obtained by obtaining the components of detergent, different from pradalago organic polymer according to the above-mentioned methods, and further mixing the obtained detergent composition with predomin organic polymer. During mixing predomi organic polymer can be separately pelletized and mix or pellet together with other compounds to obtain a granulated powder and then mixed, or can be obtained in liquid or gel form and then mix. During mixing of the components, different from pradalago organic polymer contained in the detergent composition, and shape of the detergent composition is not specifically limited.

A method for improving the smoothness of the present invention in the environment to perform washing, species subject to washing products, the amount subject to washing products, the quantity of washing solution and optionally the size of the container in the case of the washing container and the like is not specifically limited. For example, when using washbowl more than a vanity sink, the greater the number of washing solution and lower the relation of things to aqueous solution (weight ratio: subject washing product/wash solution) allow you to more easily identify smoothness. In terms of the size of the basin is preferably a shell with a diameter of 5 cm or more, more preferably 30 cm or more, more preferably 40 cm or more and more preferably 50 cm or more. The relation of things to aqueous solution is preferably 1/3 or less, more preferably 1/5 or less, more preferably 1/7 or less and even more preferably 1/10 or less. In addition, the higher temperature corresponds to a better solubility of many predomi organic polymers. Also the temperature of the washing solution is preferably 10°C or higher, more preferably 20°C or higher, even more preferably 25°C or higher and more preferably 30°C or higher. In addition, the method of hand washing is not specifically limited provided that it represents a method of washing to be washed product manually.

2.Method hand wash

In addition, the present invention relates to a method of hand washing. The preferred method of hand washing according to the present invention (hereinafter referred to as "method of hand washing according to the present invention") is a method in which a method for improving the smoothness of the present invention, which includes a stage hand washing to be washed product detergent solution, with predomantly and used in the present invention, as described below. P and the implementation of the above-mentioned method of hand washing can be obtained an excellent effect of improving smoothness. According to the method of hand washing is the effect that allows you to improve your feeling for that hand washing was carried out with a pleasant perception. Additionally it is called an effect of preventing abrasion, the effect of eliminating cuts, scratches, etc. on hand resulting from friction to be hand-washed items, and so-called effect of preserving linen from damage during washing, the effect of eliminating damage to the fibers, etc. is subjected to washing products.

The cleaning solution in the way of hand washing according to the present invention relates (i) to a cleaning solution that has predomantly during hand washing, containing predomi organic polymer, or (ii) to a cleaning solution obtained by diluting the above-mentioned washing solution (i) more than 1 to 1,000-fold amount of water.

Despite the fact that the cleaning solution, obtained by diluting the cleaning solution with predomantly, more than 1-1000-fold amount of water, in some cases already has predomantly during hand washing can be implemented by the above-mentioned effect of improving the smoothness of the present invention, since predomi organic polymer according to the present invention, which has a lubricating ability, is also present in the liquid layer between the subjects of the clothes in the washing solution. Therefore, the cleaning solution having predomantly, the present invention is actually completely different from the aqueous solution with just increased viscosity or its diluted solution. The presence or absence of predmosti washing solution has been evaluated in accordance with the method described above in the section "a Method of evaluating predmosti".

The cleaning solution with predomantly, can be obtained, for example, added to the cleaning solution predamage organic polymer as the component parts of detergent or separately from the detergent components.

In the present invention, higher molecular weight predamage organic polymer or a higher content predamage organic polymer in the washing solution corresponds to a higher effect of improving smoothness, so the washing is carried out with a more pleasant experience.

The cleaning solution with predomantly, the present invention can be applied when washing after dilution of the washing solution (i), as mentioned above. From the point of view of the effect of improving the smoothness of the concentration after dilution is preferably 1/1000 or more from the lower limit of the concentration at which the solution still has predomantly, more preferably 1/500 or more, even more preferably 1/200 or the more, even more preferably 1/100 or more, even more preferably 1/50 or more and more preferably 1/20 or more. In addition, in order to obtain a higher effect of improving smoothness, it is preferable that the cleaning solution with predomantly, according to the present invention was used at a concentration at which predmosti manifests itself sufficient. From the point of view of the properties of the operation of the washing solution and the economic benefits the concentration of the washing solution is preferably 500-fold amount or less from the lower limit of the concentration at which the solution still has predomantly, more preferably 100-fold amount or less, more preferably 50-fold amount or less, more preferably 20-fold amount or less, even more preferably 10-fold amount or less, more preferably 5-fold amount or less, even more preferably 2-fold amount or less and even more preferably 1-fold amount or less.

From the viewpoint of obtaining a high effect of improving the smoothness concentration predamage organic polymer in the washing solution is preferably 2 mg/l or more, more preferably 5 mg/l or more, more preferably 10 mg/l or more, more preferably 20 m is/l or more and more preferably 50 mg/l or more. In addition, the concentration predamage organic polymer in the washing solution is preferably 5000 mg/l or less, more preferably 2500 mg/l or less, more preferably 1000 mg/l or less, more preferably 500 mg/l or less and even more preferably 250 mg/l or less from the viewpoint of the properties operated as a solution.

From the viewpoint of detergency pH of the washing solution preferably is 9.0 or more, more preferably 9.5 or more, and still more preferably 10.0 or more. Here the pH of the washing solution is determined in the washing solution with a water hardness of 0°DH at 25°C, not containing items of clothing. From the point of view of stability, prevent damage to the hands and the like, the upper limit of the pH is preferably of 11.0 or less.

Applied here, the cleaning solution refers to the solution to effect the washing, in which the detergent composition is dissolved, suspendered, etc. is Here contained in the detergent composition components, different from the organic polymer, the shape of the detergent composition and method for producing detergent composition is not specifically limited and may be the same as that used in the above-mentioned method of improving smoothness.

In addition, when the method of hand washing according to the present invention in the environment for the implementation of the manual with the Irka, species subject to washing products, the amount subject to washing products, the amount of water, temperature or size of the container, if the washing is carried out in a container, etc. are not specifically limited and is similar to that described in the above-mentioned method for improving the smoothness of the present invention. The effects can manifest in any possible environment. Preferred washing conditions may be similar to those described in the above-mentioned method of improving smoothness.

3.Detergent composition

In addition, the present invention relates to a cleaning composition. Detergent composition of the present invention can be divided into the following two options for implementing the invention:

Variant implementation of the invention 1. Detergent composition containing an organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.% from washing composition.

Variant implementation of the invention 2. Detergent composition for washing clothes containing polymer with an average molecular weight of 500,000 or more, in which 60 mol.% or more of its constituent monomers contains sulfonation group or its salts, or sulfuric acid group or a salt thereof.

Variant implementation of the invention 1

One of the important characteristics of the cleansing composition according to the variant of implementation of the ia of the invention 1 is what detergent composition contains an organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.% from the cleaning composition. Because the detergent composition has the above characteristic, some of the effects are manifested in the fact that when the detergent composition is used for hand washing in the home, the feeling when hand washing is improved, both physical costs are reduced and additionally you can save the linen in the wash and reduce abrasion.

Also, when the detergent composition is used for washing in the washing machine, showing some of the effects of conservation underwear in the wash, in which the smoothness helps prevent damage to clothing and provides smoothness between garments to prevent the leads on the clothes for washing in the washing machine, thus preventing loss of form.

In addition, the present invention relates to a cleaning composition for improving smoothness (hereinafter referred to as the detergent composition of the present invention).

Among the above, preferred detergent composition according to the variant embodiment of the invention 1 contains:

(a) an organic polymer with an average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.%;

(b) over OSTO-active substance;

(c) an alkalizing agent; and

(d) the agent, absorbing metal ions,

from the point of view of satisfying the requirements as detergency, and impart smoothness.

In addition, for these reasons, a method for improving the smoothness when predomi organic polymer is a polyethylene oxide, it is preferable that the detergent composition contains:

(a) a polyethylene oxide with average molecular weight of more than 1,500,000 or more, with predomantly, in excess of 0.1 wt.%;

(b-1) anionic surfactant in the amount of 10% or more;

(c) an alkalizing agent; and

(d) the agent, absorbing metal ions,

where the detergent composition does not actually contain a simple Olkiluoto ether of polyoxyethylene (b-2).

Used here, the phrase "does not actually contain a simple Olkiluoto ether of polyoxyethylene" means that the compound is contained in an amount of from 0% or more to less than 2%.

Variant implementation of the invention 2

In addition, the detergent composition according to the variant embodiment of the invention 2 relates to a detergent composition for washing clothes (hereinafter referred to as "detergent composition according to the variant embodiment of the invention 2"). One of the important characteristics of the cleansing composition according to the variant embodiment of the invention 2 is that the detergent composition contains a polymer with an average mol the molecular weight of 500,000 or more, in which 60 mol.% or more of its constituent monomers contains sulfonation group or its salts, or sulfuric acid group or its salt (hereinafter referred to as "polymer containing sulfonation group and/or a sulfuric acid group). Because the detergent composition has the above characteristic, some of the effects are manifested in the fact that when the detergent composition is used for hand washing in the home, the feeling when hand washing is improved, both physical costs are reduced and additionally you can save the linen in the wash and hand care without deterioration of the properties associated with preventing re-deposition.

In addition, when the detergent composition is used in the wash in a washing machine, some of the effects are manifested in the fact that the smoothness helps prevent damage to clothing and smoothness between garments or fibers to prevent the leads and deformation clothes when washing linen in the washing machine, thus preventing the loss of her form.

Preferred detergent composition according to the variant embodiment of the invention 2 contains

(a') a polymer with an average molecular weight of 500,000 or more, in which 60 mol.% or more of its constituent monomers contains sulfonation group or a salt thereof, or that nokiatool group or its salts;

(b) a surfactant;

(c) an alkalizing agent; and

(d) the agent, absorbing metal ions,

from the point of view of satisfying the requirements associated with both washing ability, and to give smoothness.

Detergent composition of the present invention, shown in the embodiment of invention 1 or 2, may take any form such as powder, granule, liquid or paste, or an alternative detergent composition can be formed into aggregates, tablets, viscous mass or more using the advanced method. Preferably, if the detergent composition contains an alkalizing agent and an agent that absorbs metal ions, together with surface-active substance from the viewpoint of detergency. In addition, from the viewpoint of the solubility of the detergent composition preferably the primary tool quickly dissolved during the dissolution. Given these viewpoints, it is preferable that the detergent composition was in the form of powder or granules. In addition, predomi organic polymer or a polymer containing sulfonation group and/or a sulfuric acid group of the present invention, for the most part has the form of powder or granules. Therefore, the formation of the composition is facilitated by making the cleansing composition in the form of powder or granules, in order to further extent the ü freedom of the polymer, included in the recipe.

The method of obtaining the cleaning composition of the present invention is not specifically limited. The detergent composition can be obtained in accordance with methods described in the publication Tokkyocho Koho: Shuchi Kanyo Gijutsu Shu (Clothes Powder Detergent: Japanese Patent Office), 10(1998)-25(7159), and JP-B-3123757, which are known as General methods of obtaining detergent formulations. Alternative detergent composition can be obtained by obtaining the components of detergent that is different from pradalago organic polymer or polymer containing sulfonation group and/or a sulfuric acid group, in accordance with the above-mentioned methods, followed by mixing the obtained detergent composition with predomin organic polymer or a polymer containing sulfonation group and/or a sulfuric acid group.

In addition, the detergent composition of the present invention, indicated in the embodiment of invention 1 or 2, can accordingly be used for a method of improving the smoothness of the present invention and method of hand washing according to the present invention mentioned above.

When the detergent composition of the present invention, shown in the embodiment of invention 1 or 2, is used for a method of improving the smoothness of the present invention and method of hand washing according to the present invention, the cleaning composition can be submitted is ü a composition, used in commonly used method in the concentration in which the detergent is typically used when hand washing or washing in the washing machine. The concentration of the detergent composition according to the variant embodiment of the invention 1 in the washing solution in the case of hand washing is preferably 0.05 g/l or more, more preferably 0.1 g/l or more, more preferably 0.5 g/l or more, more preferably 1 g/l or more, more preferably 2 g/l or more and more preferably 3 g/l or more from the viewpoint of improving smoothness of the washing solution. On the other hand, the concentration of the detergent composition in the washing solution is preferably 20 g/l or less, more preferably 15 g/l or less and more preferably 10 g/l or less from the point of view of slavemaster (water) and the properties of the operation of the washing solution. Even more preferable to apply detergent composition at a concentration of from 0.5 to 10 g/L. in Addition, preferably used the method includes a method of washing with friction, in which the cleaning solution is obtained by directly spraying the proper amount of detergent composition of the present invention, the part to be washing clothes being washed with friction and contact of the clothes with water. Also preferred is the combined use of detergent from the tava according to the present invention with the detergent composition, different from the detergent composition of the present invention, or a composition for the preservation of linen in the wash that does not contain detergent components, such as perfume.

Each of the components that are applicable in the present invention, will be described next.

4.Predomi organic polymer and a polymer containing sulfonation group and/or a sulfuric acid group

In the detergent composition of the present invention, the effect of improving the smoothness of the present invention can be obtained by applying predamage organic polymer described a method for improving the smoothness of the present invention. As predamage organic polymer is preferably used water-soluble organic polymer with an average molecular weight of more than 1,500,000 or more. At higher average molecular weight predamage organic polymer fewer organic polymer to implement a given "smoothness". Provided that the organic polymer is predomi organic polymer with an average molecular weight of more than 1,500,000 or more, it is possible to give a liquid mixture sufficient smoothness, even in the case of mixtures with low concentrations of dissolved substances, as in the case of the washing solution. Predomi organic polymer preferably has an average mo is coolaroo mass 2000000 or more, more preferably 2500000 or more and more preferably 3000000 or more from the point of view of the implementation of sufficient smoothness, even at more dilute concentrations. On the other hand, from the viewpoint of solubility predomi organic polymer preferably has an average molecular weight of 100000000 or less, more preferably 30000000 or less and even more preferably 20000000 or less.

The polymer containing sulfonation group and/or a sulfuric acid group, according to the present invention may be a vinyl polymer, polycondensation polymer or polymer-based polyether.

When the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention is a vinyl polymer, a vinyl monomer component containing sulfonation group and/or its salts, or sulfuric acid group and/or its salts, which represents a Monomeric unit, and includes, for example, a link that is derived from such a monomer such as 2-(meth)acryloyloxyhexyloxy acid, 2-(meth)acryloylmorpholine acid, 2-(meth)acrylamide-2-alkyl(number of carbon atoms: from 1 to 4)propanesulfonic acid, vinylsulfonic acid, arylsulfonate acid, styrelseledamot acid or viniterra the acid. Among the above, from the viewpoint of high ability for polymerization, so it was easy to obtain a polymer with a high molecular weight, it is preferable to link derived from 2-(meth)acryloyloxyhexyloxy acid, 2-(meth)acryloylmorpholine acid, 2-(meth)acrylamide-2-alkyl(number of carbon atoms: 1 to 4)propanesulfonic acid or styrelseledamot acid, more preferred is a link derived from 2-acrylamide-2-methylpropanesulfonic acid or styrelseledamot acid, and more preferred is derived from 2-acrylamide-2-methylpropanesulfonic acid.

These monomer components can be used as a link in the form of acid or sulfonation group and/or a sulfuric acid group at the level of the partially or completely neutralized to obtain the link in salt form.

The counterion for the formation of a link in the form of a salt sulfonation group or a sulfuric acid group includes metal ions, ammonium ion, ion of alkylamine or alkenylamine, each of which contains the total number of carbon atoms from 1 to 22, pyridinium ion, which contains alkyl or alkenylphenol group with the number of carbon atoms from 1 to 22, and ion alkanolamine with the total number of carbon atoms from 1 to 22. Preferred are alkaline ions m is the metal, such as sodium ion and potassium ion, or ammonium ion, and more preferred are the sodium ion and the potassium ion.

In the polymer containing sulfonation group and/or a sulfuric acid group of the present invention, the above-mentioned constituent monomers can be used alone or as a mixture of two or more kinds. When using two or more kinds of components of the polymer monomers, the arrangement of such parts of the polymer of the monomers is not specifically limited, and it is possible to use a random order, chess order and block order.

In the case where the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention is a vinyl polymer, a method of obtaining a vinyl polymer is not specifically limited, and you can choose the known method. For example, a vinyl monomer containing sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts), can be homopolymerization, or vinyl monomer can be copolymerized with other monomers not containing sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts), in such ratio that the molar ratio of vinyl monomer containing su is honokalani group (and/or the form of its salt) and/or sulfuric acid group, and/or its salts), constituent monomers is 60 mol.% or more. Alternatively, sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts) can be entered in any known polymer in the ratio of 60 mol.% or more of its constituent monomers.

In the case when the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention is a vinyl polymer, as a form of polymerization to obtain a vinyl polymer can be used homopolymerization or copolymerization of a monomer containing sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts). As the polymerization method can be applied block polymerization or polymerization deposition. To obtain a polymer having an even greater ability to provide smoothness, or to facilitate control of the polymerization, it is preferable as the polymerization method for obtaining a vinyl polymer to apply the polymerization in aqueous solution or suspension polymerization with reversible phase.

In the case where the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention is a vinyl polymer, upon receipt of the vinyl polymer, the polymerization method may, before the presentation any way, such as polymerization by a radical mechanism, anionic polymerization and cationic polymerization. In the case when the vinyl polymer is produced by polymerization by a radical mechanism, as a polymerization initiator for the radical mechanism can be applied peroxide initiator such as potassium persulfate, ammonium persulfate, sodium persulfate, tert-butylhydroperoxide or hydrogen peroxide, or azoinitiator, such as 2,2'-azobis-(2-amidinopropane)dihydrochloride. Alternatively, the polymerization initiator for the radical mechanism can be used as a redox initiator with a reducing agent such as sodium sulfite, hydrosulfite sodium, sulfate, ferrous iron or L-ascorbic acid. The monomer can be irradiated with ultraviolet light, electron beams or γ-rays, in order to initiate the polymerization. Here the number of such initiators used in the polymerization is preferably from 0.0001 to 5 mol.%, more preferably from 0.001 to 1.5 mol.% and even more preferably from 0.01 to 0.5 mol.% from the above-mentioned vinyl monomer.

In addition, in the case where the vinyl polymer obtained by anionic polymerization, as the polymerization initiator can be used aromatic complex of an alkali metal, such as naphthas is latry; alkaline metal such as lithium, sodium or potassium; or you can apply organolithium compound (compound ascilite), such as n-utility, tert-utility, motility or fluorenylmethyl, or you can apply magyarkanizsa compound, preferably a compound of the Grignard reagent, such as phenylmagnesium or butylacrylamide or magnetoresitance connection, such as dibenzylamine, dibutylamine or benzylpyridine. Applied here, the amount of these polymerization initiators is preferably from 0.0001 to 5 mol.%, more preferably from 0.001 to 1.5 mol.% and even more preferably from 0.01 to 0.5 mol.% from the above-mentioned vinyl monomer.

On the other hand, in the case where the vinyl polymer obtained by cationic polymerization, as the polymerization initiator can be applied acid of Branstad, such as triperoxonane acid, trichloroacetic acid, sulfuric acid, methanesulfonate acid or triftormetilfullerenov acid, or you can apply a mixture of acids of Bronsted/Lewis acid, such as water/boron TRIFLUORIDE, water/trichloride boron, water/aluminium chloride, water/aluminum bromide, water/tin tetrachloride, trichloroacetic acid/tin tetrachloride, hydrogen chloride/trichloride boron or hydrogen chloride/trichloride aluminum. Alternative WMS is about to apply organic cation, such as a cation of trityl or the cation of trapelia, or a mixture capable of generating ion oxocarbon, such as acetylchloride/hexafluoroantimonate silver or acetylchloride/silver perchlorate. Here, the specified number of the used polymerization initiators is preferably from 0.0001 to 5 mol.%, more preferably from 0.001 to 1.5 mol.% and even more preferably from 0.01 to 0.5 mol.% from the above-mentioned vinyl monomer.

In addition, the vinyl polymer is produced in the form of a copolymer formed between monomer containing sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts), and other copolymerizable monomers. In this case constituting the monomer that is different from a constituent monomer containing sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts), not specially limited, provided that the polymer containing sulfonation group and/or a sulfuric acid group can maintain its solubility.

The above-mentioned copolymerizing monomer can be described as follows.

Copolymerizing monomer includes (meth)acrylic acid [where (meth)acrylic acid refers to acrylic acid, methacrylic acid or mixtures thereof] and its salts; Tirolerhof acids and their salts; mo is the Windows-based maleic acid [maleic anhydride, maleic acid, complex monoether maleic acid, monoamide maleic acid or a mixture of two or more kinds of them] and its salts; taconova acid and its salts, etc. Can be used one or more kinds selected from the above. Among these preferred are (meth)acrylic acid and its salts and Tirolerhof acids and their salts, and from the viewpoint of ease of copolymerization is preferable (meth)acrylic acid and its salts. Here is the counterion for the formation of salts can represent the above-mentioned counterion.

In the copolymerization can also participate constituting the vinyl monomer containing phosphorotioate group (or its salt) or postnational group (or its salt). Constituting the vinyl monomer containing phosphorotioate group or postnational group includes, for example, (meth)acryloyloxy(the number of carbon atoms: 1 to 4)phosphate, vinylphosphonic acid, etc. Here is the counterion for the formation of salts can represent the above-mentioned counterion.

Optionally subjected to copolymerization of the following monomers.

1) Unsubstituted or substituted (meth)acrylamide in which the hydrogen atom on the nitrogen atom may be substituted saturated or unsaturated alkyl group containing from 1 to 4 atoms in the of Lerida, or aranceles group. For example, preferred are (meth)acrylamide, N-methyl(meth)acrylamide, N,N-dimethyl(meth)acrylamide, N-ethyl(meth)acrylamide, N-tert-butyl(meth)acrylamide, (meth)acryloylmorpholine, 2-(N,N-dimethylamino)ethyl(meth)acrylamide, 3-(N,N-dimethylamino)propyl(meth)acrylamide, 2-hydroxyethyl(meth)acrylamide, N-methylol(meth)acrylamide, N-butoxymethyl(meth)acrylamide, etc.

2) (Meth)acrylates. For example, preferred are methyl(meth)acrylate, ethyl(meth)acrylate, 2-hydroxyethyl(meth)acrylate, 2-(N,N-dimethylamino)ethyl(meth)acrylate, 2-methoxyethyl(meth)acrylate, mono(meth)acrylates of polyethylene glycol, etc.

In addition, the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention may be a crosslinked polymer, provided that the degree of crosslinking is preferably regulated so as to avoid gelatinization of the polymer. In particular, the amount of crosslinking agent used during the polymerization of the polymer, is preferably from 0 to 0.001 mol.% from its constituent monomers.

A crosslinking agent includes, for example, (meth)acrylate compounds of polyhydric alcohols, such as di(meth)acrylate of ethylene glycol, di(meth)acrylate of diethylene glycol, di(meth)acrylate of polyethylene glycol, di(meth)acrylate of propylene glycol, di(meth)acrylate of dipropyleneglycol, di(meth)acrylic is t polypropylenglycol, di(meth)acrylate 1,2-butyleneglycol, di(meth)acrylate 1,3-butyleneglycol, di(meth)acrylate neopentyl glycol, di(meth)acrylate glycerol, three(meth)acrylate glycerol, three(meth)acrylate of trimethylolpropane and Tetra(meth)acrylate of pentaerythritol; acrylamide compounds such as N-methylacrylamide, N-vinylamine, N,N'-Methylenebis(meth)acrylamide and bisacrylamide acid; divinelvie compounds such as divinylbenzene, simple divinely ether, diphenylethylenediamine; polyallyl compounds such as diallylphthalate, diallylmalonate, diallylamine, triallylamine, salt triallylamine, simple allyl ether of pentaerythritol, simple allyl ether of sucrose, containing at least two link simple allyl ether in its molecule; esters of (meth)acrylic acid and unsaturated alcohols such as vinyl(meth)acrylate, allyl(meth)acrylate and 2-hydroxy-3-acryloyloxy(meth)acrylate; and the like

Among these crosslinking agents, preferred are di(meth)acrylate of ethylene glycol, di(meth)acrylate of polyethylene glycol, polystyrene, simple trailerby ether of pentaerythritol and simple tatrallyay ether of pentaerythritol.

In addition copolymerization with the above-mentioned stitched monomer, the crosslinking can be accomplished through reaction with epoxysilane, such as 1,2-epoxybutane, 1,2-epoxy is Xan, 1,2-epoxyoctane or 1,2-epoxydecane. Alternatively, you can implement any of the methods of stitching, such as cross-linking through the formation of covalent bonds, according to such methods, as clossiana during the polymerization, the reaction of crosslinking with each other or the irradiation of x-rays; cross-linking through the formation of ionic bonds involving metal ions or the like; stitching through hydrogen bonds; the stitching due to the semi-crystalline structure; or stitching due to the spiral (helical) structure.

In addition, in the case where the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention is not vinyl polymer, not the vinyl polymer may be polycondensation polymer, such as a complex polyester, polyamide, polyurethane or polyimide, or a polymer-based polyether. Alternative sulfonation group (and/or the form of its salt) and/or sulfuric acid group and/or its salts) can be entered in the famous polycondensation polymer or polymer-based polyether in relation to 60 mol.% or more of its constituent monomers.

It is believed that the polymer containing sulfonation group and/or a sulfuric acid group, has in the washing solution low affinity to solid cha is the tics, such as pollution, or soot, and particles of conventional pollutants spots subjected to treatment with detergents. For this reason, even when the washing solution contains any particles of dirt and soot, in the case when the washing solution is a polymer with high molecular weight in a concentration capable of smoothness, the polymer does not cause aggregation, due to the simultaneous adsorption of many particles, so that the polymer may not serve as a binder between the fibers and particles, resulting in can not occur the phenomenon of re-deposition of contaminants stains on the clothes in the wash. In particular, when predomi organic polymer in the present invention is a polymer containing sulfonation group and/or a sulfuric acid group, more preferably a higher molar ratio such sulfonation monomer and the acid monomers the monomers constituting the polymer.

The ratio of the constituent monomers containing sulfonation group (and/or the form of its salt) or a sulfuric acid group and/or its salts), preferably 60 mol.% or more, more preferably 66 mol.% or more, more preferably 85 mol.% or more and more preferably 95 mol.% or more of all components of the suits.

As the polymer containing sulfonation group and/or a sulfuric acid group, in the present invention preferably employ a molecule with an average molecular weight of 500,000 or more. At higher average molecular weight defined "smoothness" can be implemented with fewer. Provided that the polymer has an average molecular weight of 500,000 or more, the polymer can provide sufficient smoothness of the service. From the point of view of the implementation of sufficient "smoothness" even when diluted concentration during washing the polymer preferably should have an average molecular weight of 1000000 or more, more preferably more than 1,500,000 or more, even more preferably 2000000 or more, even more preferably 2500000 or more, even more preferably 3000000 or more, even more preferably 4500000 or more, even more preferably 5000000 or more and more preferably 6000000 or more. On the other hand, from the viewpoint of solubility of the polymer should preferably have an average molecular weight of 30000000 or less and more preferably 20000000 or less.

In addition, the properties of the polymer containing sulfonation group and/or a sulfuric acid group, a preferred property for the manifestation of "smoothness" is "predmosti". The higher predmosti polymer, the smaller the amount of polymer, included in the recipe, you need to implement the "smoothness". In the present invention, "high predmosti" means that predomantly has a water solution with a lower concentration or an aqueous solution of low viscosity. In the present invention, preferred is a polymer with a higher molecular weight and lower ability to crosslinking of the linear polymer, the higher predomantly, through which is excellent "smoothness".

Determination of the average molecular weight

The average molecular weight of the organic polymer used in the present invention, can be determined by measurement method gel chromatography (GPC) under the following conditions. As a standard sample used polyethylene oxide (PEO) of the usual value of molecular weight. In addition, in the present invention, the average molecular weight refers not to srednetsenovoj molecular mass or mass-average molecular weight, as to the value of PEO with molecular weight fraction, which is detected on the curve of GPC elution is characterized by very high intensity (hereinafter referred to as "molecular weight corresponding to the peak"). In other words, the phrase "organic polymer with an average molecular m is soy 1500000 or more" refers to an organic polymer with a molecular weight, the corresponding peak equal to 1500000 or more in terms of a given molecular weight PEO.

The conditions determining the GPC method

Used column is a column PW/GMPWXL/GMPWXL (production company Tosoh Corporation), eluent used is a 0,2M phosphate buffer (KH2PO4, Na2HPO4, pH 7)/CH3CN=9/1 (weight ratio), the column temperature is 40°C, flow rate 1.0 ml/min and the concentration of the sample is from 1 to 100 µg/ml Used detector is the analyzer RALLS (analyzer light scattering 90°). In addition, the average molecular weight can be set using the diffractometer RID (differential diffractometer). The GPC analysis using RID carried out under conditions of, for example, when applicable column represents GMPWXL+GMPWXL, eluent represents 0,2M phosphate buffer/CH3CN=9/1 (weight ratio), the column temperature is 40°C, flow rate 0.5 ml/min, and the concentration of 0.05 mg/ml

In addition, the present invention relates to an improver for the implementation of the effect of improving the smoothness of the present invention (hereinafter referred to as "creamy improver smoothness of the present invention"), as improver contains the above-mentioned predomi organic polymer or the polymer, with the holding sulfonation group and/or a sulfuric acid group.

Form a creamy improver smoothness of the present invention is not specifically limited and can be applied to any form in the form of powder, granules, liquid, dense suspensions and pastes. Creamy improver smoothness can also be subjected to additional molding units, granules, tablets or other Such methods of molding can be performed by known methods.

Creamy improver smoothness according to the present invention can remarkably increase the ability of the service to the smoothing adding creamy improver smoothness to the water or by dissolving improver in water or other aqueous composition. Therefore, if creamy improver smoothness of the present invention is added to a conventional cleaning composition, a conventional detergent composition can be improved by getting the detergent composition of the present invention.

When creamy improver smoothness of the present invention is added to a conventional cleaning composition with getting the cleaning composition of the present invention, a method of adding a creamy improver smoothness of the present invention is not specifically limited. To use creamy improver smoothness to stably obtain a sufficient effect, the way you add must ensure homogeneous dispersed through the W creamy improver smoothness according to the present invention in the detergent composition at a practical level, preferably in the stages of receipt of the cleansing composition. A typical way to obtain the powdered detergent creamy improver smoothness according to the present invention can be added after the stage of mixing (stage add a component of a detergent, for example, fluorescent substances, enzymes, perfume, antifoam, bleach activator, bleach or the like to the resulting detergent granules or the like). Alternatively, creamy conditioner smoothness can be added at the stage of surface modification or stage of granulation. If possible, it is convenient to use the method of adding creamy improver smoothness at the stage of formation of a thick suspension.

To the polymer was directly mixed with the detergent composition in the form of powder or granules, it is preferable that the polymer containing sulfonation group and/or a sulfuric acid group, was in the form of powder or granules. The characteristics of the polymer particles is not specifically limited. From the viewpoint of the solubility of the polymer particles, the average size of the polymer particles is preferably 3 mm or less, more preferably 1 mm or less and more preferably 500 μm or less. In addition, the polymer particles have an average particle size of preferably 10 μm or more, more PR is doctitle 50 μm or more and more preferably 100 μm or more from the viewpoint of the ability to dispersion when adding detergent composition in water and prevent the formation of a viscous mass (status, where between the granules is sticking with partial hydration unit of the granules, so that it is impossible dispersing granules even under the action of mechanical forces). Although the method of obtaining polymer particles containing sulfonation group and/or a sulfuric acid group is not specifically limited, preferable from the standpoint of obtaining a powdery or granular polymer with the above-mentioned particle size is the suspension polymerization with reversible phase.

In addition, in order predomi organic polymer or a polymer containing sulfonation group and/or a sulfuric acid group, inhibited the formation of a viscous mass, it is possible to apply the polymer in the form of a mixture with other basic components that are obtained by granulation. Mentioned here the other main component can be any of the other major components to ensure sufficient dispersion or dissolution predamage organic polymer or polymer containing sulfonation group and/or a sulfuric acid group, according to the present invention. For example, you can apply sodium sulfate, sodium carbonate, zeolite, polyethylene glycol, alkylsulfate or the like, in the right quantity.

From the viewpoint of improving smoothness when hand washing the contents of Prada the th organic polymer or polymer containing sulfonation group and/or a sulfuric acid group, preferably equal to the amount exceeding 0.1 wt.%, more preferably, equal to the excess of 0.2 wt.%, more preferably, equal to the excess of 0.25 wt.%, more preferably 0.3 wt.% or more, more preferably 0.5 wt.% or more, even more preferably 1 wt.% or more, and particularly preferably 3 wt.% or more of the detergent composition. In addition, the content of the polymer is preferably 30 wt.% or less, more preferably 20 wt.% or less and more preferably 10 wt.% or less from the point of view of slavemaster (water) and properties of the powder.

In addition, when the manual method of washing Laundry can be done in conditions when there is only a small number of products subject to the wash, or a small amount of water. Therefore, as compared with the case where washing is carried out in the washing machine, the amount applied for once the cleaning composition is more easily reduced. In particular, in the powdered detergent composition obtained after mixing the composition containing predomi organic polymer or the composition containing the polymer with sulfonation group and/or a sulfuric acid group, in the powdered state, the content predamage organic polymer Il the polymer, containing sulfonation group and/or a sulfuric acid group used separate washing, preferably equal to the amount exceeding 0.1 wt.%, more preferably, equal to the excess of 0.2 wt.%, more preferably, equal to the excess of 0.25 wt.%, more preferably 0.3 wt.% or more, more preferably 0.5 wt.% or more, more preferably 0.7 wt.% or more, and particularly preferably 1 wt.% or more of the detergent composition, from the viewpoint of homogeneous mixing predamage organic polymer or polymer containing sulfonation group and/or a sulfuric acid group, with a detergent composition. In addition, the content of the polymer is preferably 20 wt.% or less, more preferably 10 wt.% or less and more preferably 5 wt.% or less from the viewpoint of the balance of the composition.

In addition, when applying predamage organic polymer of the present invention when predomi organic polymer is applied in the form of a mixture with other components, obtained by granulating the ability of the polymer to dispergirujutsja in the composition is excellent due to the reduction of the effective content predamage organic polymer in single grains from the point of view of stabilization of the number of used predamage of the organic polymer.

5.Other components of the detergent

(b) Surfactant

As surface-active substances, applicable in the present invention, it is possible to apply any of the well-known surface-active substances. From the point of view of enhancing detergency preferably, a surfactant as a main component contained anionic surfactant or nonionic surfactant.

In particular, as anionic surfactants are preferred salt of linear alkylbenzenesulfonic acid, the alkyl part of which contains from 10 to 18 carbon atoms, salt complex Olkiluoto ether sulfuric acid salt of sulfuric acid and simple Olkiluoto ester polyoxyalkylene, salt complex methyl ester of alpha-sulfazine acid, surfactant N-allumination type, carboxylate simple alkylboron or alkenilovyh ether, surfactant amino acid type, a salt of an alkali metal, such as complex alkilany or alkenilovyh phosphate ester or its salt; and yet in the recipe, you can enable salt of fatty acid obtained from animal fat or coconut oil. Among the above, preferred are alkylbenzoic ONAT, salt complex Olkiluoto ether sulfuric acid and salt of sulfuric acid simple Olkiluoto ester polyoxyalkylene, and in particular, it is preferable Las sodium. Anionic surfactant has the effect of additional strengthening of the "predmeti" organic polymer described in the present invention, and enhance the effect of imparting smoothness using organic polymer. From this point of view, the content of the anionic surfactant is preferably 5 wt.% or more, more preferably 10 wt.% or more, more preferably 12 wt.% or more, even more preferably 15 wt.% or more, more preferably 18 wt.% or more and more preferably 20 wt.% or more of the detergent composition. In addition, from the point of view of the characteristics of the powder, the content of the anionic surfactant is preferably 40 wt.% or less, more preferably 35 wt.% or less, even more preferably 30 wt.% or less and even more preferably 26% by weight or less of the detergent composition.

In addition, as a nonionic surfactant is preferred simple alkilany ether polyoxyalkylene [preferably oxyethylene and/or oxypropylene]. You can also apply a simple alkylphenolate the ether of polyoxyethylene, alkanolamine higher fatty acid or its adduct with alkalization, esters of sucrose and fatty acids, Alkylglucoside or complex glycerin monoether fatty acids. Nonionic surfactant is especially suitable for detergency for oily stains, such as polluting stains sebum, because of their excellent resistance to hard water. From the viewpoint of foaming ability and slavemaster (water) nonionic surfactant used in the amount of 15 wt.% or less.

In addition, for these reasons, a method for improving the smoothness when predomi organic polymer is a polyethylene oxide, it is preferable that the number of simple Olkiluoto ether of polyoxyethylene in the formulation was such that the composition does not actually contain simple Olkiluoto ether of polyoxyethylene. Used here, the phrase "did not actually contain simple Olkiluoto ether of polyoxyethylene" means that the compound contains less than 2%, more preferably less than 1.5%, more preferably less than 1%, more preferably less than 0.5% and most preferably not contained. Even more preferably, if the number of ordinary Olkiluoto ester polyoxyalkylene and simple alkylperoxo ether of polyoxyethylene in the recipe Ave is doctitle is less than 2%, more preferably less than 1.5%, more preferably less than 1%, more preferably less than 0.5% and most preferably not contained.

The recipe detergent composition of the present invention can additionally include the right amount of surfactant such as an amphoteric surfactant type betaine, a surfactant based on a complex ester of phosphoric acid, soap or cationic surfactant.

(c) Alkalizing agent

As an alkalizing agent, applicable in the present invention, for the preparation of the formulation is preferably applied traditionally known alkalizing agent. It is preferable to include alkalizing agent in the cleaning composition from the viewpoint of detergency. Examples of alkalizing agent include alkali metal salts, including carbonates of alkali metals such as sodium carbonate, referred to under the General title as dense soda ash and light soda; amorphous alkali metal silicates such as sodium silicate JIS No. 1, 2 or 3; crystalline alkali metal silicates; and the like, Salt of an alkali metal has the effect of additional strengthening of the "smoothness" by using the organic polymer described in the present invention. From this point of view, the content is if the alkali metal is preferably 1 wt.% or more, more preferably 5 wt.% or more, more preferably 7 wt.% or more, more preferably 10 wt.% or more, more preferably 12 wt.% or more, even more preferably 15 wt.% or more and more preferably 20 wt.% or more of the detergent composition. In addition, the content of the alkalizing agent is preferably 40% or less and more preferably 30% or less of the detergent composition, from the viewpoint of the balance of the composition.

(d) the Agent, absorbing metal ions

Very effective to include in the recipe agent, absorbing metal ions, as an additive to the cleaning composition to absorb the components, increasing the hardness of water, water for washing. In addition, the agent, absorbing metal ions, has the effect of additional strengthening of the "smoothness" using the polymer described in the present invention. In particular, it is more efficient to include in the recipe agent, absorbing metal ions with the absorptive capacity of 100 mg caso3/g or more in relation to calcium ions. Agent absorbing metal ions, includes a crystalline aluminosilicate, crystalline sodium silicate, polymer based on acrylic acid, a copolymer of acrylic acid/maleic acid, sodium tripolyphosphate, ethylenediaminetetraacetic acid and metallicities the Yu acid. Here, in the present invention, the sodium carbonate and amorphous sodium silicate is not included in the number of agents that absorb metal ions. The content agent absorbing metal ions, is preferably 1 wt.% or more, more preferably 5 wt.% or more, more preferably 10 wt.% or more and more preferably 20 wt.% or more of the detergent composition, from the viewpoint of detergency. In addition, the content agent absorbing metal ions, preferably 50 wt.% or less, more preferably 40 wt.% or less and more preferably 35 wt.% or less of the detergent composition, from the viewpoint of the balance of the composition.

(e) an Inorganic salt, releasing hydrogen peroxide

In addition, the content of inorganic salt, which is capable of releasing hydrogen peroxide in water (hereinafter referred to simply as "inorganic salt, releasing hydrogen peroxide") is preferably 15 wt.% or less, more preferably 10 wt.% or less, even more preferably 5 wt.% or less and even more preferably 2.5 wt.% or less of the detergent composition, from the viewpoint of reducing the so-called "skin irritation".

Inorganic salt, releasing hydrogen peroxide, is not specifically limited. Inorganic salt, releasing peraki the ü hydrogen, includes, for example, percarbonate, perborate, perphosphate, prsilikat etc.

(f) Other polymer

In addition, well-known in order to increase the ability to dispersion spots, consisting of a particulate detergent composition of the present invention or a cleaning solution that is applicable in the present invention may contain in addition to the organic polymer having predomantly, organic polymer with a molecular weight of less than 500,000 and preferably with a molecular weight of from 1000 to 100,000, including carboxylated polymer, polyethylene glycol, carboxymethylcellulose or the like

Carboxylated polymer

Besides the function of absorption of metal ions carboxylate polymer performs the function of dispersion spots, consisting of solid particles in the vessel for washing. Carboxylated polymer is preferably a homopolymer or copolymer of acrylic acid, methacrylic acid, basis of itaconic acid or the like as a copolymer suitable are copolymers obtained by copolymerization of the above-mentioned monomer with maleic acid, and preferred are copolymers with a molecular weight of from 5000 to 20000.

The polyethylene glycol

The function of the glycol is in the dispersion of spots consisting of solid particles in the vessel for washing. Predpochtitel the NYM is a polyethylene glycol with a molecular weight of from 1000 to 20000.

Carboxymethylcellulose

Function carboxymethylcellulose is the dispersion of spots consisting of solid particles in the vessel for washing. From the point of view of ability to dispersion preferably carboxymethylcellulose had a molecular weight of from several thousand to several hundred thousand, and the degree of esterification was from 0.2 to 1.0.

(g) Other additives

Detergent composition of the present invention may contain the desired amount of enzyme, perfumes, fluorescent substance, dye or the like

6.Method of washing

The present invention relates to a method of washing. One of the hallmarks of the method of washing according to the present invention is that the method includes a stage of washing to be washed product with a detergent composition of the present invention, a detergent composition containing predomi organic polymer or a polymer containing sulfonation group and/or a sulfuric acid group of the present invention, or with a detergent composition containing a creamy conditioner smoothness according to the present invention. Because the method of washing contains the above-mentioned characteristic, between the subject washing products receive smoothness, through which the effect of eliminating damage to the fibers, etc. have to be washing products (so-called the th effect of preserving linen in the wash from damage). In the case of hand washing due to improvement in sensation effect is manifested in the fact that you can hand wash with a pleasant perception. Additionally the effect of eliminating cuts, scratches, etc. of the hands due to friction to be washing products and hands together (the so-called effect of reducing abrasion). Consequently, it is possible to realize an effect of improving the smoothness of the present invention.

In the present invention, higher molecular weight predamage organic polymer or polymer containing sulfonation group and/or a sulfuric acid group of the present invention, or a higher polymer content in the detergent solution containing the polymer corresponds to the improved smoothness, as well as more improved predmosti washing solution. Therefore, washing is carried out with a more pleasant experience.

The cleaning solution in the method of washing according to the present invention can represent the same solution, as mentioned above. In addition, in the method of washing according to the present invention environment for implementation washing, species subject to washing products, the amount subject to washing products, water content, and optionally the size of the container in the case where washing is carried out in the container, etc. are not specifically limited Effects can be obtained in any environment.

EXAMPLES

The following additional examples are described and shown embodiments of the present invention. Examples are given solely for the purpose of illustration and should not be construed as limiting the present invention.

Determination of molecular weight

The molecular weight used in each of these examples of organic polymers was determined according to the above method. Here the detector is applied RALLS.

Sample 1: polyacrylate sodium brand "ARON A-20P" manufactured by TOAGOSEI CO., LTD.

Sample 2: sodium salt of a copolymer acrylamidophenylboronic acid/acrylic acid brand "ARON A-50P" manufactured by TOAGOSEI CO., LTD.

Sample 3: polyethyleneoxide brand "PEO 8Z" manufactured by Sumitomo Seika Chemicals Company, Limited.

Sample 4: polyethyleneoxide "PEO 3Z" manufactured by Sumitomo Seika Chemicals Company, Limited.

Results definitions

Sample 1 (peak): average molecular weight: 5000000

Sample 2 (peak): average molecular weight: 5500000

Sample 3 (peak): average molecular weight: £ 2,800,000 are exempted

Sample 4 (peak): average molecular weight: 1200000

Furthermore, the method of assessment of hand washing carried out in the examples will be described next.

Evaluation method for hand washing

Conditions for the exercise of hand washing

8.2 l p is DIPROPYLENE the washtub (production company YAZAKI) with a diameter of 30 cm and a depth of 13 cm was downloaded 2 l of hard water (molar ratio Ca/Mg: 7/3, corresponding to the content of 8.9 mg caso3/liter) at a controlled temperature of 25°C and was added to water and 15 g of detergent composition; the water was continuously stirred by hand with a degree of intensity, so as not to spill water from the tank for washing. After 30 seconds from the start of mixing the cleaning solution that is in the tank for washing, immersed in men's t-shirt with 100% cotton content (white, made by Gunze, size L) so that all men's t-shirt was quite immersed. Five minutes later sections on the chest mens t-shirts has got two hands and rubbed areas on the chest mens t-shirts together. The plots were rubbing each other, taking a man's shirt from the washing solution. After friction together from 3 to 5 times during each time subjected to friction areas during immersed in the cleaning solution. Ease friction during friction plots each other was evaluated in terms of smoothness on a scale from 1 to 5. When this assessment was performed only with cooked above the water, so as not to provide smoothness in a negative light, uneven mens t-shirts, preventing smoothness (smoothness) in areas exposed to friction together, Ter slightly to the rubbing together of the parts was not air bubbles. In this case, the smoothness was assigned a score of 1. X is racteristic each indicator is given below.

Figure 1: very low smoothness and a sense creak, and therefore to cope with the holding hand washing is very difficult.

Figure 2: very low smoothness and a sense creak, and therefore perform hand washing is not easy.

Figure 3: smoothness on the average level and the ability to perform hand washing without creak.

Figure 4: high smoothness, ability to perform hand washing more easily, without a creak.

Figure 5: very high smoothness, ability to perform hand washing is very easy, without a creak.

In addition, in the above-mentioned test to provide a measure for the average value of the received results of the assessment made by 6 experts. It was also evaluated the effect of improving smoothness by pairwise comparison with the detergent composition obtained in example obtain I-1.

In addition, during the evaluation of hand washing was evaluated predmosti washing solution obtained by the aforementioned method according to the aforementioned [method of evaluating predmosti], by dissolving 15 g of detergent composition in 86 ml of water.

Test damage underwear in the wash

Obtaining a pre-processed garments

After the establishment of the water level for washing in a fully automated security is a pressing machine (Toshiba, "AW-D802VP") 45 l in the washing machine was loaded 10 samples of cotton men's t-shirts (approximately 2.2 kg). Additionally, the washing machine was added powdered detergent compact type ("ATTACK", Kao Corporation) in accordance with the standard dosage and perform the wash cycle for 8 minutes, centrifuge the centrifuge for 3 minutes, rinse twice in stagnant water and spin in a centrifuge for 3 minutes, and then men's t-shirt was dried in a drying machine. The specified wash cycle was repeated 5 times, while receiving pre-treated clothing.

Test damage underwear in the wash

Four sample men's t-shirts, obtained by pre-processing service, as described above, were sewn on the sewing machine in the area of the plot on the chest in accordance with the test tissue MA (Machine Action) method Testfabrics, Inc. Applied here, the test tissue MA is a test tissue, described in the publication Frants Szaras; "The mechanical action in washing machines. MA-test pieces instruction and application" (1982).

After the establishment of the water level for washing in a fully automatic washing machine (Toshiba, "AW-D802VP") 45 l in the washing machine loaded 4 pattern cotton men's t-shirts are stitched according to the aforementioned test tissue MA, and 6 samples of cotton men's t-shirts without flashing with the according to the above-mentioned test tissue MA, only 10 samples (approximately 2.2 kg). In the washing machine, added detergent composition in the amount of 67.5 g, spent soaking for 30 minutes and then made a wash cycle for 8 minutes, centrifuge the centrifuge for 3 minutes, rinse twice in stagnant water and spin in a centrifuge for 6 minutes, and then without drying were tested tissues MA on men's shirts. Counted the number of worn threads.

Method of assessment when testing the damage of linen in the wash

The evaluation was performed by obtaining the average number of worn threads on 4 samples for testing tissue MA.

Getting detergent formulations

Example obtain I-1

Mixed together in water in the amount of 325 kg 200 kg 50 wt.% an aqueous solution of dodecylbenzenesulfonate sodium, 75 kg 40 wt.% an aqueous solution of sodium silicate No. 2, 50 kg of sodium carbonate, 212,5 kg of sodium sulfate, 5 kg of polyethylene glycol, 2.5 kg of fluorescent substances CBS and 100 kg of zeolite to obtain a homogeneous dense suspensions. Then, the resulting thick suspension was spray dried, thus obtaining detergent composition.

An example of comparison I-1

The smoothness of the detergent composition obtained in example obtain I-1, are shown in table 1. Detergent composition had the smoothness index 2. An aqueous solution obtained by dissolving detergent composition, also n is possessed predomantly.

An example of obtaining I-2

Mixed together in water in the amount of 325 kg, 240 kg of 50 wt.% an aqueous solution of dodecylbenzenesulfonate sodium, 6 kg of ethoxylate alcohol (number of carbon atoms: 12, EO: average added 8 mol), 75 kg 40 wt.% an aqueous solution of sodium silicate No. 2, 50 kg of sodium carbonate, 186,5 kg of sodium sulfate, 5 kg of polyethylene glycol, 2.5 kg of fluorescent substances CBS and 100 kg of zeolite to obtain a homogeneous dense suspensions. Then, the resulting thick suspension was spray dried, thus obtaining detergent composition.

An example of comparison of I-2

The smoothness of the detergent composition obtained in example obtain I-2, are shown in table 1. Detergent composition had the smoothness index 2. Compared with the level of smoothness for example obtain I-1 detergent composition had the same level of smoothness. An aqueous solution obtained by dissolving detergent composition, had no predomantly.

An example of obtaining I-3

Mixed together in water in the amount of 465 kg, 48 kg, 50 wt.% (aqueous solution) dodecylbenzenesulfonate sodium, 135 kg 40 wt.% an aqueous solution of sodium polyacrylate, 120 kg of sodium carbonate, 60 kg of sodium sulfate, 9 kg of sodium sulfite, 3 kg of fluorescent substances CBS and 300 kg of zeolite to obtain a homogeneous dense suspensions. Then, the resulting thick suspension was spray dried, thus obtaining the main faction.

The shift of the p solution, containing 15 weight parts of the ethoxylate alcohol (number of carbon atoms: 12, EO: average added 6 mol), 15 weight parts of Las sodium, 1 weight part of polyethylene glycol and 3 weight parts of water, was mixed with 100 weight parts of the main fraction with stirring, while receiving detergent composition.

An example of comparison of I-3

The smoothness of the detergent composition obtained in example obtain I-3, are shown in table 1. Such a detergent composition had the smoothness index 2. Compared with the level of smoothness for example obtain I-1 detergent composition had the same level of smoothness. An aqueous solution obtained by dissolving detergent composition, had no predomantly.

An example of obtaining I-4

Mixed together in water in the amount of 325 kg, 220 kg of 50 wt.% an aqueous solution of dodecylbenzenesulfonate sodium, 18 kg of ethoxylate alcohol (number of carbon atoms: 12, EO: average added 6 mol), 75 kg 40 wt.% an aqueous solution of sodium silicate No. 2, 60 kg of sodium carbonate, 197,5 kg of sodium sulfate, 2.5 kg of fluorescent substances CBS and 93 kg of zeolite, thus obtaining a homogeneous dense suspension. Then, the resulting thick suspension was spray dried, thus obtaining detergent composition.

An example of comparison of I-4

The smoothness of the detergent composition obtained in example obtain I-4, are shown in table 1. Detergent composition was coated the figure smoothness 2. Compared with the level of smoothness for example obtain I-1 detergent composition had the same level of smoothness. An aqueous solution obtained by dissolving detergent composition, had no predomantly.

An example of comparison of I-5

Detergent composition obtained in example obtain I-4, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 50 g of polyethylene oxide with average molecular weight of £ 2,800,000 are exempted ("PEO-8Z" manufactured by Sumitomo Seika Chemical Co., Ltd., with predomantly), 2 g of the fluorescent substance ("Tinopal CBS-X" manufactured by Ciba Geigy AG) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 2. Compared with the level of smoothness for example obtain I-1 detergent composition had the same level of smoothness.

Example I-1

Detergent composition obtained in example obtain I-1, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 12 g of sodium polyacrylate with an average molecular weight 5000000 ("ARON A-20P" production is odstv company TOAGOSEI CO., LTD., with predomantly), 2 g of the fluorescent substance DM ("Tinopal DMA" manufactured by Ciba Geigy AG) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, and surface applied men's t-shirts you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 4. When compared to the detergent composition according to example obtain I-1 almost all experts believed that the smoothness undoubtedly improved.

Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-2

Detergent composition obtained in example obtain I-1, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l) and then was added 20 g of sodium polyacrylate with an average molecular weight 5000000 ("ARON A-20P" manufactured by TOAGOSEI CO., LTD., with predomantly), 200 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 84 g of granules containing percarbonate sodium (bleach granule described in paragraph 0019 of the patent JP-2000-256699 A), 4 g of the Zell the basics (Cellzyme granules, production company Novozymes) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts undoubtedly you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 5. When compared to the detergent composition according to example obtain I-1 all members of the group of six experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-3

Detergent composition obtained in example obtain I-3, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto were added 200 g of sodium polyacrylate with an average molecular weight 3000000 (predomantly), 160 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 8 g of protease granules (Kannase granules, the production company Novozymes), 4 g of the fluorescent substance ("Tinopal CBS-X" manufactured by Ciba Geigy AG) and 16 g of odorants. The components were mixed at an inclination of 30 and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 4. When compared to the detergent composition according to example obtain I-1 almost all experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-4

Detergent composition obtained in example obtain I-3, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 60 g of a copolymer of sodium acrylate/acrylamidoglycolate sodium (AA/AMPS) with an average molecular weight 5000000 ("ARON A-50P" manufactured by TOAGOSEI CO., LTD., with predomantly), 120 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 4 g of cellulase in granules (Cellzyme granules, the production company Novozymes), 8 g of protease granules (Kannase granules, the production company Novozymes) and 16 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving the washing with the becoming, containing organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts could certainly feel the sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 5. When compared to the detergent composition according to example obtain I-1 all members of the group of six experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-5

Detergent composition obtained in example obtain I-1, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 48 g of polyethylene oxide (PEO) with an average molecular weight £ 2,800,000 are exempted ("PEO-8Z" manufactured by Sumitomo Seika Chemical Co., Ltd., with predomantly), 60 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 48 g of granules containing percarbonate sodium (bleach granules described in paragraph 0019 patent JP 2000-256699 A), 20 g of granules lauroylsarcosinate sodium granules bleaching activator described in paragraph 0018 patent JP 2000-256699 A), 8 g of cellulase in granules (Cellzyme granules production company Novozymes) and 6 g Fluor is szarowska substances ("Tinopal CBS-X" manufactured by Ciba Geigy AG). The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts undoubtedly you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 5. When compared to the detergent composition according to example obtain I-1 all members of the group of six experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-6

Detergent composition obtained in example obtain I-1, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 6.0 g of polyethylene oxide with average molecular weight of 4500000 ("PEO-18Z" manufactured by Sumitomo Seika Chemical Co., Ltd., with predomantly), 2 g of the fluorescent substance ("Tinopal CBS-X" manufactured by Ciba Geigy AG) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular what assay. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts undoubtedly you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent composition shown in table 1. Detergent composition had the smoothness index 5. When compared to the detergent composition according to example obtain I-1 all members of the group of six experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Example I-7

Detergent composition obtained in example obtain I-2, in the amount of 4.0 kg were added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 280 g of polyacrylamide with an average molecular weight 5000000 (predomantly), 80 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.) and 16 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition containing an organic polymer with high molecular weight. Water for washing, solvent such detergent composition was a viscous, so that the surface of used men's t-shirts undoubtedly you could feel it sliding layer containing the polymer. The smoothness of the obtained detergent of softwarevideo in table 1. Detergent composition had the smoothness index 4. When compared to the detergent composition according to example obtain I-1 almost all experts believed that the smoothness undoubtedly improved. Also, an aqueous solution obtained by dissolving 15 g of detergent composition in 86 ml of water, had predomantly.

Here, when hand washing was carried out according to examples I-1 to I-7, the formation of cracks on the hands and fiber damage not occurred.

The above-mentioned test in respect of damage to the sheets when washing was carried out with the use of detergent compositions obtained in example obtain I-1 example I-6. The number of worn threads (average for 4 samples of garments for testing MA) for each detergent composition was 86 and 70, respectively.

Obtaining polymer containing a sulphonate group and/or containing a sulfate group

The synthesis example II-1

An example of the synthesis of polymer 1

A homopolymer of 2-acrylamide-2-methyl propane sulfate sodium

A solution obtained by dissolving 50,3 g of 2-acrylamide-2-methyl propane sulfate sodium, 32,4 g of sodium hydroxide, and 3.95 g of 2,2'-azobis-(2-methylpropionamidine)dihydrochloride (V-50" manufactured by Wako Pure Chemical Industries, Ltd.) in 135 g of water held by the ion exchange processing was heated to a temperature of 50°C in nitrogen atmosphere and the mixture was stirred for 1 the Asa. Then the temperature was raised to 70°C and the mixture was stirred for an additional 8 hours. The resulting mixture was diluted with 360 g of water, held ion-exchange processing, and then added to this 2700 g of ethanol to precipitate the solid polymer. The precipitated polymer was dried under reduced pressure, thus obtaining 55,0 g colorless solid polymer (yield: 98.8 per cent). The obtained polymer was subjected to determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak was 2000000 (refer to polyethylene glycol (PEO), column: GMPWXL+GMPWXL, manifesting solvent: 0,2M phosphate buffer/CH3CN=9/1 (weight ratio), concentration: 0.05 mg/ml, flow rate: 0.5 ml/min, 40°C, detector: RALLS, in the future, similar to the determination of the average molecular weight in the same conditions).

The synthesis example II-2

Example of synthesis of polymer 2

A homopolymer of 2-acrylamide-2-methyl propane sulfate sodium

The solution obtained by dissolution of 20.0 g of 2-acrylamide-2-methyl propane sulfate sodium, 3,86 g of sodium hydroxide and to 0.055 g of ammonium persulfate in 50 g of water held by the ion exchange processing was dispersible in a solution obtained by dissolving 1,00 g complex sugar ester (S-770" Mitsubishi Chemical Foods K.K.) in 185 g of n-hexane. The dispersion was heated to a temperature of 60°C in nitrogen atmosphere and n is remedial the mixture for 3 hours. The water content was reduced by removing only the aqueous phase of the azeotropic boiling under reflux solution up until the water content of the polymer reaches 30 wt.%, and gave the opportunity to the reaction mixture to cool in the air. The obtained solid product is a granular structure was dried under reduced pressure, thus obtaining 22,0 g of colorless polymer granular structure (yield: 99.1 per cent). The obtained polymer was subjected to determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak was 3000000. The average particle size of the polymer was 230 μm.

Here, the average particle size of the polymer were determined using sieves, as prescribed in JIS Z 8801. Used ten consecutive sieves, the cell size of each of the sieves was 2000 μm, 1400 μm, 1000 μm, 710 μm, 500 μm, 355 μm, 250 μm, 180 μm, 125 μm and 106 μm, and a receiving tray; as sieves, and the receiving tray was attached to a rotating and shaking device for shaking (production company HEIKO SEISAKUSHO). 100 g of the sample was subjected to vibration for 10 minutes to sort particles by size (shaking: 156 times/min, rotation: 290 times/min). Then determined the weight of the granules remaining on the receiving tray and on each of the sieves. If the cell of the first sieve, in which the total weight ratio, under the read for fine particles, is 50% or more, designated as "a" μm cell sieve larger than "a" μm, at one stage be denoted as "b" μm, the total weight ratio in the output bin μm-sieve denoted as "c"%, and the ratio of weight to mass on µm-sieve denoted as d%, the average particle size can be calculated according to the following formula:

(average particle size) = 10Andwhere

where A corresponds to the formula:

A = (50-(c-d)/(logb-loga) × logb))/(d)/(logb-loga)).

The synthesis example II-3

Example of synthesis of polymer 3

A homopolymer of 2-acrylamide-2-methyl propane sulfate sodium

To a solution obtained by dissolving 6,00 g complex sugar ester (S-770" Mitsubishi Chemical Foods K.K.) in 950 g of n-hexane and boiling the solution under reflux in a nitrogen atmosphere, is added dropwise over 1 hour was added to the solution obtained by dissolving and dispersing 665 g of 2-acrylamide-2-methyl propane sulfate sodium and 0.80 g of 2,2'-azobis-(2-methylpropionamidine)dihydrochloride (V-50" manufactured by Wako Pure Chemical Industries, Ltd.) in 590 g of water held ion-exchange processing, and the mixture was stirred for an additional 30 minutes. The resulting mixture was subjected to azeotropic dehydration and drying in the same manner as in synthesis example II-2, while receiving 664 g of colorless polymer granular structure (yield: 99.8 per cent). The resulting polymer, for example, the Ali determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak was 6200000. The average particle size of the polymer was 250 μm. In addition, in an aqueous solution of a polymer concentration of 0.4 wt.% was found predmosti.

The synthesis example II-4

Example of synthesis of polymer 4

The copolymer of 2-acrylamide-2-methyl propane sulfate sodium/sodium acrylate = 95:5 (molar ratio)

To a solution obtained by dissolving 6,00 g complex sugar ester (S-770" Mitsubishi Chemical Foods K.K.) in 800 g of cyclohexane and heating the solution to a temperature of 70°C in an atmosphere of nitrogen for over 1 hour was added dropwise a solution obtained by dissolving and dispersing 600 g of 2-acrylamide-2-methylpropanesulfonic acid, 160 g of sodium hydroxide, 10 g of acrylic acid and of 2.40 g of 2,2'-azobis-(2-methylpropionamidine)dihydrochloride (V-50" manufactured by Wako Pure Chemical Industries Co., Ltd.) in 510 g of water held ion-exchange processing, and the mixture was stirred for an additional 30 minutes. The resulting mixture was subjected to azeotropic dehydration and drying in the same manner as in synthesis example II-2, while receiving 672 g of colorless polymer granular structure (99,4%). The obtained polymer was subjected to determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak, with Talala 4500000. The average particle size of the polymer was 150 μm. In addition, in an aqueous solution of a polymer concentration of 0.5 wt.% was found predmosti.

The synthesis example II-5

Example of synthesis of polymer 5

The copolymer of 2-acrylamide-2-methyl propane sulfate sodium/sodium acrylate = 95:5 (molar ratio)

To a solution obtained by dissolving 6,00 g complex sugar ester (S-770" Mitsubishi Chemical Foods K.K.) in 800 g of n-hexane and boiling the solution under reflux in nitrogen atmosphere for more than 1 hour was added dropwise a solution obtained by dissolving and dispersing 600 g of 2-acrylamide-2-methylpropanesulfonic acid, 160 g of sodium hydroxide, 10 g of acrylic acid and 0.80 g of 2,2'-azobis-(2-methylpropionamidine)dihydrochloride (V-50" manufactured by Wako Pure Chemical Industries Co., Ltd.) in 510 g of water held ion-exchange processing, while maintaining the temperature of the mixture to 10°C or less, and the mixture was stirred for an additional 30 minutes. The resulting mixture was subjected to azeotropic dehydration and drying in the same manner as in synthesis example II-2, while receiving 674 g of colorless polymer granular structure (99,7%). The obtained polymer was subjected to determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak was 7800000. The average particle size poly the EPA was 220 μm. In addition, in an aqueous polymer solution with a concentration of 0.3 wt.% was found predmosti.

The synthesis example II-6

Example of synthesis of polymer 6

Cross-linked polymer based on 2-acrylamide-2-methyl propane sulfate sodium

To a solution obtained by dissolving 2.00 g of complex sugar ester (S-770" Mitsubishi Chemical Foods K.K.) in 950 g of n-hexane and boiling the solution under reflux in nitrogen atmosphere for more than 1 hour was added dropwise a solution obtained by dissolving and dispersing 440 g of 2-acrylamide-2-methyl propane sulfate sodium, to 0.011 g of polyethylene glycol dimethacrylate (NK ESTER 23G" manufactured by Shin-Nakamura Chemical Co., Ltd.) and 0.50 g of 2,2'-azobis-(2-methylpropionamidine)dihydrochloride (V-50" manufactured by Wako Pure Chemical Industries, Ltd.) in 390 g of water held ion-exchange processing, and the mixture was stirred for an additional 30 minutes. The resulting mixture was subjected to azeotropic dehydration and drying in the same manner as in synthesis example II-2, while receiving 438 g of colorless polymer granular structure (yield: 99.5%pure). The obtained polymer was subjected to determination of molecular weight by GPC method. The resulting molecular weight corresponding to the peak, was $ 5000000. The average size of polymer particles was 200 μm. In addition, in an aqueous solution of the polymer with concentrat what she 0.5 wt.% was found predmosti.

Getting detergent formulations

An example of retrieving II-1

Water in the amount of 325 kg 200 kg 50 wt.% an aqueous solution of dodecylbenzenesulfonate sodium, 125 kg 40 wt.% an aqueous solution of sodium silicate No. 2, 50 kg of sodium carbonate, 50 kg of sodium tripolyphosphate, 150 kg of sodium sulfate, 5 kg of polyethylene glycol, 6.25 kg 40 wt.% an aqueous solution of a copolymer of acrylic acid/maleic acid, 2.5 kg of fluorescent substances CBS and 100 kg of zeolite were mixed together, thus obtaining a homogeneous dense suspension. Then, the resulting thick suspension was spray dried, thus obtaining detergent composition. Characteristics of the resulting detergent composition was evaluated according to the following methods.

Evaluation method for hand washing

The test was performed in the same manner as described above, and to obtain the indicator has gotten the average value of the results of the evaluation made by 6 experts. Here used 2 litres of hard water with equivalent content of 89 mg CaCO3/l (molar ratio Ca/Mg: 7/3). Evaluation of the effect of improving the smoothness was carried out with application of the detergent composition obtained in example obtain II-1 as the object to compare with pairwise comparison.

The method of damage assessment linen in the wash

The test was performed in the same manner as described above, and the average value of the received 4 samples service to test the Oia MA.

The method of estimating properties to prevent re-deposition of carbon spots

The detergent composition in an amount of 5.0 g was dissolved in 1000 ml of water (CaCl2: to 55.42 mg/l MgCl2•6H2O: 43,51 mg/l)applied at 40°C. Then, thereto was added 0.25 g of carbon black selected Nippon Yukagaku Kyokai (production company Asahi Carbon K.K., preferably carbon black Asahi carbon black for washing). For a homogeneous distribution of the carbon black and the mixture was subjected to ultrasonic treatment at 26±1.5 kHz for 5 minutes. Then the dispersion was transferred to a standard Cup connected to the test apparatus detergency type mixer (Terg-O-Tometer) at 20°C. Five samples of cotton calico 6 cm × 6 cm (chintz #2023, standard product, selected Nippon Yukagaku Kyokai supplied by Sentaku Depending Kyokai) was introduced into the test apparatus detergency and which when the rotation speed of 100±5 rpm for 10 minutes. Then cotton chintz, which was removed from the test apparatus detergency, lightly pressed by hand so that the water content was 200 wt.% or less. Cotton was placed in 1000 ml of water (CaCl2: to 55.42 mg/l MgCl2•6H2O: 43,51 mg/l)applied at 40°C, and rinsed for 3 minutes in a device for testing detergency type mixer (rotational speed: 100±5 rpm). The rinsing procedure was carried out in which a total of 2 times. Then extracted from the device chintz was air-dried and treated the surface of the iron.

Then determined the reflectance of the obtained tissue at 550 nm (spectrophotometer production company Nihon Denshoku Kogyo K.K.). The percentage of preventing re-deposition were obtained using the following formula and evaluated in accordance with the following evaluation criteria.

Evaluation criteria:

Evaluation A: the Percentage of preventing re-deposition of 60% or more; and

Evaluation X:% prevent re-deposition of less than 60%.

The method of estimating properties to prevent re-deposition of contaminants spots

The detergent composition in an amount of 5.0 g was dissolved in 1000 ml of water (CaCl2: to 55.42 mg/l MgCl2•6H2O: 43,51 mg/l)applied at 40°C. Then, thereto was added 2.5 g of contaminants (red clay Kanuma for a garden with a particle size passing through a cell sieve 200 mesh [purchased from the company K.K. Kokukoen (10, Yoshimasa-cho, Izumi-shi, Osaka)]) and the mixture was dispersively to a homogeneous state. Then the dispersion was transferred to a standard Cup connected to the test apparatus detergency type mixer (Terg-O-Tometer). Five samples of cotton calico 6 cm × 6 cm (chintz #2023, standard product, selected Nippon Yukagaku Kyokai supplied by Sentaku Depending Kyokai) was made in the device DL the test detergency and which when the rotation speed of 100±5 rpm for 10 minutes. Then extracted from the device cotton chintz lightly pressed by hand so that the water content was 200 wt.% or less. Cotton was placed in 1000 ml of water (SAS2: to 55.42 mg/l MgCl2•6H2O: 43,51 mg/l)applied at 40°C, and rinsed for 3 minutes in a device for testing detergency type mixer (rotational speed: 100±5 rpm). The rinsing procedure was performed a total of 2 times. Then extracted from the device chintz was air-dried and treated the surface of the iron. Then determined the reflectance of the obtained tissue at 460 nm (spectrophotometer production company Nihon Denshoku Kogyo K.K.). The percentage of preventing re-deposition were obtained using the following formula and evaluated in accordance with the following evaluation criteria.

Evaluation criteria:

Evaluation A: the Percentage of preventing re-deposition of 66% or more; and

Evaluation X:% prevent re-deposition of less than 66%.

An example of comparison II-1

The smoothness of the cleansing composition and the property of the detergent composition obtained in example obtain II-1, to prevent re-deposition are shown in table 2. Detergent composition gave the smoothness index equal to 2, with smoothness at the same level, compared with the smoothness of the sample receiving II-1. Detergent composition so the e had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

An example of retrieving II-2

Water in the amount of 325 kg, 240 kg of 50 wt.% an aqueous solution of dodecylbenzenesulfonate sodium, 6 kg of ethoxylate alcohol (number of carbon atoms: 12, EO: average added 8 mol), 75 kg 40 wt.% an aqueous solution of sodium silicate No. 2, 50 kg of sodium carbonate, 186,5 kg of sodium sulfate, 5 kg of polyethylene glycol, 2.5 kg of fluorescent substances CBS and 100 kg of zeolite were mixed together, thus obtaining a homogeneous dense suspension. Then, the resulting thick suspension was spray dried, thus obtaining detergent composition.

An example of comparison II-2

Smoothness and properties of the detergent composition obtained in example obtain II-2, to prevent re-deposition are shown in table 2. Detergent composition gave the smoothness index equal to 2, with smoothness at the same level, compared with the smoothness of the sample receiving II-1. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

An example of retrieving II-3

Water in the amount of 465 kg, 48 kg, 50% aqueous solution of dodecylbenzenesulfonate sodium, 135 kg 40 wt.% an aqueous solution of sodium polyacrylate, 120 kg of sodium carbonate, 60 kg of sodium sulfate, 9 kg of sodium sulfite, 3 kg of fluorescent substances CBS and 300 kg of zeolite were mixed together, getting the ri this dense homogeneous suspension. Then, the resulting thick suspension was spray dried, thus obtaining the main faction.

The solution mixture containing 15 parts by weight of the ethoxylate alcohol (number of carbon atoms: 12, EO: average added 6 mol), 15 weight parts of Las sodium, 1 weight part of polyethylene glycol and 3 weight parts of water, was mixed with 100 weight parts of the main fraction with stirring, while receiving detergent composition.

An example of comparison II-3

Smoothness and properties of the detergent composition obtained in example obtain II-3, to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 2, with smoothness at the same level, compared with the smoothness of the sample receiving II-1. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

Example II-1

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-2, was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 720 g of polymer 1 in synthesis example II-1, 2 g fluorescent substance DM ("Tinopal DMA" manufactured by Ciba Geigy AG) and 12 g of odorants. The components were mixed at an inclination of 30° and with whom oresti rotation of 20 rpm for 3 minutes, thus the detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 4, so that when compared with the smoothness of the sample receiving I-1, almost all the experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

Example II-2

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-3, was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 360 g of polymer 2 obtained in synthesis example II-2, 200 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 84 g of granules containing percarbonate sodium (bleach granules described in paragraph 0019 of the patent JP-2000-256699 A), 4 g of cellulase (Cellzyme granules, the production company Novozymes) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index, R is wny 4, so compared with the smoothness of the sample receiving II-1, almost all the experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

Example II-3

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-1 was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 120 g of polymer 3 obtained in synthesis example II-3, 160 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 8 g of protease (granules Kannase granules production company Novozymes), 4 g of the fluorescent substance ("Tinopal CBS-X" manufactured by Ciba Geigy AG) and 16 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 5, so that when compared with the smoothness of the sample receiving II-1 all members of the group of six experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon is about spot assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

Example II-4

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-2, was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 320 g of polymer 4 obtained in synthesis example II-4, 48 g of granules containing percarbonate sodium (bleach granules described in paragraph 0019 patent JP 2000-256699 A), 20 g of granules lauroylsarcosinate sodium granules bleaching activator described in paragraph 0018 patent JP 2000-256699 A), 120 g of carboxymethyl cellulose ("F10MC" manufactured by NIPPON PAPER CHEMICALS CO., LTD.), 4 g of cellulase (granules Cellzyme granules production company Novozymes), 8 g of protease (Kannase granules production company Novozymes) and 16 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 5, so that when compared with the smoothness of the sample receiving II-1 all members of the group of six experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot with a rating A.

Example II-5

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-1 was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l), and then thereto was added 60 g of polymer 5 obtained in synthesis example II-5, 8 g of cellulase (granules Cellzyme granules production company Novozymes), 6 g of fluorescent substances ("Tinopal CBS-X" manufactured by Ciba Geigy AG) and 12 g of odorants. The components were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, while receiving detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 5, so that when compared with the smoothness of the sample receiving II-1 all members of the group of six experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

Example II-6

The detergent composition in an amount of 4.0 kg, obtained according to the example of a II-1 was added to the mixer with pop-up drum (production company KYC Machine Industry CO., LTD., capacity 40 l) and then was added 160 g of polymer 6 obtained in synthesis example II-6, and 12 g of odorants. The components of the coefficients were mixed at an inclination of 30° and the rotation speed of 20 rpm for 3 minutes, thus the detergent composition. Smoothness and properties of the resulting detergent composition to prevent re-deposition are shown in table 2. Received detergent composition gave the smoothness index equal to 5, so that when compared with the smoothness of the sample receiving II-1 all members of the group of six experts believed that the smoothness undoubtedly improved. The detergent composition also had the ability to prevent re-deposition of carbon spots with the assessment O and the ability to prevent re-deposition of contaminants spot assessment O.

When the washing was carried out using each of the detergent compositions obtained in examples II-1 to II-6, it was evident the distinction as the reduction of unpleasant factors, such as "rough texture" or "creak", and you could feel a significant decrease in physical costs compared to physical costs in the comparison examples II-1 to II-3. In addition, when the washing was carried out using each of the detergent compositions obtained in examples II-1 to II-6 does not result in formation of cracks on the hands, and when the Laundry was not any loss of ability to keep in shape, etc.

The above-mentioned test of the damage to the sheets when washing was carried out with the use of detergent compositions obtained in example obtain II-1 example II-5. The number of worn threads (average value of 4 on which the specimens clothing items for testing MA) for each of the detergent formulations was 88 and 72, respectively.

Table 2
Prsr II-1Prsr II-2Prsr II-3Approx. II-1Approx. II-2Approx. II-3Approx. II-4Approx. II-5Approx. II-6
The components of the detergent composition (weight parts)
The main detergent composition
An example of retrieving II-1100,000,0 100,0100,0
An example of retrieving II-2100,0100,0100,0
An example of retrieving II-3100,0100,0
Other components
Carboxymethylcellulose (CMC)5,04,03,0
Cellulase0,10,10,2
Protease0,20,2
Percarbonate sodium granules2,11,2
Lauroylsarcosine sodium granules0,5
Fluorescent substance 0,050,10,15
Perfume0,30,30,40,40,30,3
Polymer
Synthetic polymer 1 AMPS (molmasse 2000000)18,0
Synthetic polymer 2 AMPS (molmasse 3000000) 9,0
Synthetic polymer 3 AMPS (molmasse 6200000)3,0
Synthetic polymer 4 AMPS/AA (molmasse 4500000)8,0
Synthetic polymer 5 AMPS/AA (molmasse 7800000)1,5
Synthetic polymer 6 sewn (molmasse 5000000) 4,0
The smoothness index222445555
The ability to prevent re-deposition
The ability to prevent re-deposition of carbon spotAboutAboutAboutAboutAboutAboutAboutAboutAbout
The ability to prevent re-deposition of contaminants spotAboutAboutAbout AboutAboutAboutAboutAboutAbout
Note: molmasse denotes the average molecular weight.

In the table denote the AMPS match 2-acrylamide-2-methylpropanesulfonate sodium, and designation AA corresponds to the sodium acrylate.

Industrial applicability

Detergent composition of the present invention, in particular, can appropriately be used for hand washing.

Thus, when describing the present invention it will be obvious that it can be varied in many ways. Such variations should not be regarded as a departure from the essence and scope of the invention, and all such modifications as expected, obvious to a person skilled in this field, should be included in the scope of the following claims.

1. Method for improving the smoothness during washing to be washed products, including phase washed with wash solution in the washing solution is an organic polymer having predomantly, provided that the polyethylene oxide is missing, where the specified polymer has an average molecular weight of more than 1,500,000 or more, and where 60 mol.% or more of its constituent monomers sod is rat sulfone acid group, or the form of its salts, or sulfuric acid group or a salt thereof.

2. Method for improving the smoothness during hand washing to be washed product, comprising a stage hand washed with wash solution for hand washing in conditions where the organic polymer having predomantly and an average molecular weight of 2500000 or more, provided that no polyethylene oxide and polyacrylamide, and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or a salt thereof, is present in the washing solution in an amount of 5 mg/l or more.

3. Method of washing, which includes a stage hand washing to be washed product detergent solution, with predomantly containing organic polymer having predomantly and an average molecular weight of 2500000 or more (provided that no polyethylene oxide and polyacrylamide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or its salts, or alkaline cleaning solution obtained by diluting the specified cleaning solution more than 1 to 1,000-fold amount of water, in conditions when the organic polymer is present in the wash in the washing solution in an amount of 5 mg/l or more.

4. The method according to claim 3, is that the cleaning solution has a pH of 9.0 or more.

5. Detergent composition to improve the smoothness is subjected to washing with wash solution product containing organic polymer with an average molecular weight 2500000 or more with predmosti (provided that no polyethylene oxide and polyacrylamide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or its salt in an amount exceeding 0.1 wt.% from the detergent composition, and the organic polymer is present in the washing solution during the washing in an amount of 5 mg/l or more.

6. Detergent composition according to claim 5, where the detergent composition contains
(a) an organic polymer with an average molecular weight 2500000 or more (provided that no polyethylene oxide and polyacrylamide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or a salt thereof, with predomantly, in excess of 0.1 wt.%;
(b) a surfactant;
(c) an alkalizing agent; and
(d) the agent, absorbing metal ions.

7. Detergent composition according to claim 5 or 6, where the detergent composition is in powdered or granulated form.

8. Detergent composition according to any one of pp.5 and 6, optionally containing inorganic salt capable of releasing hydrogen peroxide in water, is where the inorganic salt is contained in an amount of 15 wt.% or less of the detergent composition.

9. Powdery or granular detergent composition for washing clothes containing polymer having predomantly, with an average molecular weight of more than 1,500,000 or more, in which 60 mol.% or more of its constituent Monomeric units contain sulfone acid group or its salts, or sulfuric acid group or a salt thereof.

10. Powdery or granular detergent composition for washing according to claim 9, in which the detergent composition contains
(a') having predomantly polymer with an average molecular weight of more than 1,500,000 or more, in which 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or its salts;
(b) a surfactant;
(c) an alkalizing agent; and
(d) the agent, absorbing metal ions.

11. Powdery or granular detergent composition for washing Laundry according to claim 9 or 10, in which a constituent monomer of the chain is a derived from one or more monomers selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid and its salts and styrelseledamot acid and its salts.

12. Creamy improver smoothness to improve the smoothness is subjected to washing with wash solution product containing organic polymer having predomantly, with an average molecular weight 2500000 or b is more (in the absence of polyethylene oxide and polyacrylamide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or its salt in an amount exceeding 0.1 wt.% from creamy improver smoothness, in which the organic polymer is present in the washing solution during the washing in an amount of 5 mg/l or more.

13. Creamy improver smoothness to improve the smoothness is subjected to washing with wash solution product containing the polymer having predomantly, with an average molecular weight of more than 1,500,000 or more, in which 60 mol.% or more of its constituent Monomeric units contain sulfone acid group or its salts, or sulfuric acid group or a salt thereof.

14. Creamy improver smoothness in item 13, in which the sulfonic acid group or its salt is a link derived from one or more monomers selected from the group consisting of 2-acrylamide-2-methylpropanesulfonic acid and its salts and styrelseledamot acid and its salts.

15. Method of washing to be washed product with poroshkoobraznym or granular detergent composition for washing Laundry according to claim 9.

16. Method of washing to be washed product with creamy improver smoothness on item 13.

17. Method for improving the smoothness during hand washing to be washed product, VK is uchumi in itself a stage hand washed with wash solution for manual washing conditions, when an organic polymer having predomantly and an average molecular weight of 2000000 or more (in the absence of polyethylene oxide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or a salt thereof, is present in the washing solution (20 mg/l or more.

18. Method of washing, which includes a stage hand washing to be washed product detergent solution, with predomantly containing organic polymer having predomantly and having an average molecular weight 2000000 or more (provided that no polyethylene oxide), and 60 mol.% or more of its constituent monomers contain sulfone acid group or its salts, or sulfuric acid group or its salts, or alkaline cleaning solution obtained by diluting the cleaning solution more than 1 to 1,000-fold amount of water, in conditions when the organic polymer is present in the wash in the washing solution (20 mg/l or more.

19. The method according to p, in which the washing solution has a pH of 9.0 or more.



 

Same patents:

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FIELD: chemistry.

SUBSTANCE: invention refers to sodium percarbonate particles. According to the invention the coated sodium percarbonate particles possessing the inner shell layer including as basic component at least one inorganic hydrate-forming salt and outer shell layer including alkali metal thiosulphate, alkali-earth metal thiosulphate and/or ammonium thiosulphate are described. The method of such sodium percarbonate particles preparation and application of these particles as bleaching agent in detergents and cleansers are also the subjects of an invention.

EFFECT: increasing of stability of sodium percarbonate particles in detergents and cleansers during storage.

23 cl, 4 dwg, 4 tbl

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10 cl, 2 tbl, 5 ex

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22 cl, 1 ex

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EFFECT: improved detergent efficiency and stability of the claimed composition.

14 cl, 3 tbl, 12 ex

FIELD: chemistry.

SUBSTANCE: invention pertains to compositions of granulated synthetic detergents, meant for manual and machine washing (in any type of machine) and soaking all types of textiles, including coloured and other household needs. The detergent contains the following components in the given % mass: anionic surface active agent sodium alkylbenzenesulfonate 9-12; non-ionic surfactant 2-5; sodium tripolyphosphate 15-30; dispergator 0.3-1.2; carboxymethyl cellulose 0.3-0.7; sodium silicate 3-6; modified polyalkylene glycol 0.2-0.6; enzyme 0.3-0.8; sodium carbonate 6-12; photo-bleaching agent 0.003-0.020; optical brightener 0.05-0.20; fragrance component 0.1-0.3; sodium sulphate and water up to 100. The non-ionic surfactant preferably contains oxyethylated monoalkylphenols based on propylene trimers or oxyethylated fatty alcohols. The dispergator used is sodium polyacrylate or sodium salt of a copolymer of maleic or acrylic acid or a sodium salt of a copolymer of acrylic, methacrylic and maleic acid. Alternatives of the synthetic detergent are also described.

EFFECT: increased effectiveness of the detergent, bleaching effect after washing, wider assortment of high quality granulated synthetic detergents.

7 cl, 1 tbl

FIELD: household chemistry, in particular compositions for bleaching of white and random dyeing textile made of natural, artificial, synthetic and mixed fibers.

SUBSTANCE: claimed composition contains (mass %): hydrogen peroxide 7-11; oxanole 0.5-1.0; oxyethylidenediphosphonic acid 0.1-0.3; optical bleaching agent, namely mixture of benzoxyzaryl derivative 0.1-0.2 and stilbenesulfo acid 0.1-0.2; and balance: water.

EFFECT: non-layered composition during storage; decreased chemical failure of materials.

2 tbl, 12 ex

FIELD: organic chemistry, chemical technology.

SUBSTANCE: invention relates to a whitening composition comprising: (a) monomeric ligand or catalyst with transient metal of ligand of the formula (I): wherein R represents hydrogen atom; R1 and R2 are chosen independently from (C1-C4)-alkyl, pyridine-2-yl-methyl and (C2-C4)-alkylmethyl; X represents -C=O; R3 and R4 are similar and represent -(CH2)nC(O)O-(C1-C4)-alkyl; n = 0-4, and (b) equilibrating carriers and additional components. This composition is useful for catalytic whitening substrates with atmosphere oxygen. Also, invention describes a method for whitening the substrate involving applying step of the whitening composition on substrate in aqueous medium.

EFFECT: valuable properties of substances, improved whitening method.

11 cl, 2 tbl

FIELD: chemistry.

SUBSTANCE: detergent composition for hand washing linen contains a polymer in which 90 wt % or more of monomer units consists ethylene oxide. The polymer has average molecular weight ranging from 1500000 or more to 4500000 or less and is contained in amount ranging from over 0.03 wt % to 5 wt % of the detergent composition. The composition also contains 10-40 wt % alkyl benzene sulphonate and 7-40 wt % alkalising agent.

EFFECT: improved smoothness when washing with mechanical friction.

11 cl, 1 tbl, 6 ex

FIELD: cosmetology.

SUBSTANCE: invention relates to cosmetology and is represented by a cleansing compound consisting from approximately 2.6% to approximately 3% (weight) of an aqueous emulsion of an acrylate copolymer, from approximately 7.7% to approximately 10.2% (weight) of an anionic surfactant and from approximately 1.4% to approximately 1.7% (weight) of an amphoteric surfactant, an effective quantity of balls of shea butter and seeds, the diametre of each ball varying within the range from 100 to 1200 micron; and additional ingredients required to bring the compound composition to 100%.

EFFECT: invention enables improvement of cleansing properties, is characterised by high translucency and improved stability.

15 cl, 3 ex, 1 dwg

FIELD: medicine.

SUBSTANCE: first, waterproof layer of absorbing tissue is placed on victim's body surface under blood-stained section of clothes, then the section is continuously flushed and rubbed with a sponge soaked in aqueous flushing fluid with pH over 7.0 and hypoosmolarity under 140 milliosmol per litre of water at +26 to +42°C till the stain changes colour from red to yellow. Afterwards the tissue is replaced with a new one, stained clothe sector is soaked for up to 2 seconds in bleach fluid with pH over 7.0, and is soaked twice in 2 seconds by sponge with flushing fluid. Further the tissue is removed, wet fabric is dried by drying tissues and warm dry air flow.

EFFECT: enhanced efficiency, safety and expediency of stain removal.

1 ex

FIELD: chemistry.

SUBSTANCE: detergent contains, wt %: sodium alkylbenzolsulphonate 5-10, synthanol ALM-7 1-2, polyethylene glycol 1-2, trisodphium phosphate 4-16, caustic soda 1-2, and water - the rest.

EFFECT: higher detergent power in solid surface cleaning.

2 tbl, 3 ex

FIELD: chemistry.

SUBSTANCE: detergent contains the components as follows, wt %: anionic surface active agent (SAG) - alkylbenzol sodium sulphonate 10-16; nonionic SAG - oxyethylated fatty alcohols or oxyethylated alkylphenol 2-5; sodium tripolyphosphate 15-25; organophosphonate compound - sodium salt 1-hydroxyethylidene of phosphonic acid or sodium diethylentriaminopentaxys-(methylene phosphonate) 0.2-0.6; polycarboxylate 0.5-1.5; carboxymethyl cellulose 0.3-0.6; modified polyalkylene glycol 0.2-0.6; optical bleaching agent 0.05-0.3; soda ash 3-6; liquid glass 3.5-6.0; enzyme 0.4-0.7; defoaming agent 0.05-1.5; aromatiser 0.15-0.3; sodium sulphate and water to 100.

EFFECT: higher efficiency of bleaching detergent, all type decontamination with additional softening of fabric and without irritation of hand skin during manual washing, lower temperature modes of washing, reduced damage effect on metal parts of washing machines.

10 cl, 2 tbl, 5 ex

FIELD: chemistry.

SUBSTANCE: composition, which contains one or several surface active substances (5-95 wt.%), 40 wt.% or more of all surface active substances being non-ionic, and one or several water-swellable polymers, which absorb water in amount exceeding their own weight (5-95 wt.%), is suggested. Weight ratio of surface active substances to water-swellable polymers is within 1:0.4 to 0.4:1. Water-swellable polymer is selected from the following compounds: polyacrylic acids, polyacrylates, cross-linked acrylates, guar gum and derivatives thereof, starch acrylic grafted copolymers, hydrolysates of starch acrylic grafted copolymers, cross-linked polyoxyethylene, cross-linked carboxymethyl cellulose, partially cross-linked water-swellable polymers, such as polyethylenoxide and polyacrylamide, isobutylene/maleic acid copolymers.

EFFECT: concentrates composition can be converted to an easy-to-use product by adding water prior to use.

15 cl, 2 tbl, 2 ex

FIELD: chemistry of polymers.

SUBSTANCE: invention describes a composition for using as a conditioner and comprising water and at least one cationic polygalactomannan or derivative of cationic polygalactomannan. A lower limit of average molecular mass of these cationic substances is 5000 Da and the upper limit is 200000 Da, transparency value of 10% aqueous solution is above 80% at wavelength 600 nm. The protein content is less 1.0% as measured for polysaccharide mass and the content of aldehyde groups is at least 0.01 ml-eqiv./g. Residue for modification of cationic derivative of polygalactomannan is chosen from group comprising alkyl, hydroxyalkyl, alkylhydroxyalkyl and carboxymethyl wherein alkyl comprises in chain from 1 to 22 carbon atoms, Hydroxyalkyl is chosen from group comprising hydroxyethyl, hydroxypropyl and hydroxybutyl, and cation residue is chosen from compounds of quaternary ammonium but with exception of hydroxypropyl trimethyl ammonium chloride. Proposed compositions are used for preparing a clear final product, for example, for personal hygiene agent and household chemistry agent.

EFFECT: improved preparing method, improved and valuable properties of composition.

55 cl, 11 tbl, 14 ex

FIELD: household chemical goods.

SUBSTANCE: invention relates to solid molded detergent compositions for cleaning hard surfaces, washing of textiles, or for personal hygiene. Cleaning agent contains 5 to 95% active detergent, 0 to 90% inorganic substance particles or other common ingredients, and at least 5% water. Outside surface of cleaning agent is covered by at least one polymer film formed by radiation hardening of polymer composition capable of being hardened under irradiation.

EFFECT: improved strength characteristics and imparted preservation of shape and integrity of cleaner lumps on prolonged contact with water.

22 cl, 6 tbl, 6 ex

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