(C07C47/542)

Electrochemical method of oxidising of alcohols to carbonyl compounds // 2393272
FIELD: chemistry.SUBSTANCE: method involves preparation of a reaction mixture at room temperature consisting of the alcohol to be oxidised, sodium bicarbonate, an organic solvent and a nitroxyl radical. Electrolysis is carried out on platinum electrodes with current of 1 A and temperature of 20-25C. Potassium iodide is added to the reaction mixture. The organic solvent used is dichloromethane and the nitroxyl radical used is 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl of formula: with ratio of alcohol to nitroxyl radical equal to 10:1.EFFECT: invention ensures high output of end products a within short period of time and less expenses on electricity using a high-technology method.2 ex
 
2551036.
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