Compounds having and cho groups bound to carbon atoms of six-membered aromatic rings (C07C47/52)

C   Chemistry; metallurgy(318790)
C07   Organic chemistry(61593)
C07C47        Compounds having ; cho groups(815)
C07C47/52                     Compounds having ; cho groups bound to carbon atoms of six-membered aromatic rings(13)
ixtures, used in oxidation of alkylaromatic compounds // 2540276
FIELD: chemistry.SUBSTANCE: invention relates to a mixture for oxidation of an alkylaromatic compound, containing: an alkylaromatic compound, a solvent, a brome source and a catalyst, with the solvent containing carboxylic acid, containing from 1 to 7 carbon atoms, as well as a ionic liquid, selected from the group, consisting of an imidazole ionic liquid, pyridine ionic liquid, phosphonium ionic liquid, tetraalkylammonium ionic liquid and their combinations, and, optionally, water; with the solvent being characterised by a ratio of the ionic liquid to carboxylic acid, being in the range from 1:10 to 10:1 by weight; and the catalyst contains, at least, one of the group: cobalt, titanium, manganese, chrome, copper, nickel, vanadium, iron, molybdenum, tin, cerium and zirconium.EFFECT: application of the method makes it possible to regulate the amount of admixtures in the solid product of oxidation.9 cl, 1 tbl, 9 ex
ethod of oxidising alkyl aromatic compounds // 2524947
FIELD: chemistry.SUBSTANCE: invention relates to a method and a mixture for oxidising an alkyl aromatic compound. The mixture contains: an alkyl aromatic compound, a solvent, a bromine source, a catalyst and ammonium acetate; wherein the solvent includes a carboxylic acid having 1-7 carbon atoms and optionally water, and the catalyst substantially consists of at least one metal selected from cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium and zirconium, present in form of acetates or hydrates thereof.EFFECT: present invention enables to obtain products of higher purity which enables to eliminate or minimise purification costs.10 cl, 1 tbl, 3 ex

Furifosmin, organometallic complexes based on them, methods for their production and catalysts // 2198891
The invention relates to new furifosmin formula Iwhere n denotes an integer of 1 or 2; R1denotes a hydrophilic group selected from the following groups: -SO2M, -SO3M, -CO2M, -PO3M, where M represents inorganic or organic cationic residue selected from a proton, cations, alkaline or alkaline earth metals, ammonium cations -- N(R)4where R denotes hydrogen or C1-C14alkyl, and the other cations are based on metals, salts with acids: fullsleeve, fullcarbon, fullsleeve or furylphosphonous soluble in water; m denotes an integer of 1; R2denotes a hydrophilic group,- SO2M, -SO3M, -CO2M, RHO3M, where M denotes hydrogen or an alkaline metal salt with the acid fullsleeve, fullcarbon, fullsleeve or fullfactorial soluble in water, R denotes an integer from 0 to 2